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High temperature corrosion behavior on molten nitrate salt-based nanofluids for CSP plants

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  • Fernández, Angel G.
  • Muñoz-Sánchez, Belen
  • Nieto-Maestre, Javier
  • García-Romero, Ana

Abstract

Recently, a number of theoretical and experimental studies have been performed to understand the effect of nanoparticles on thermal properties and heat transfer performance but there is a lack regarding their corrosion properties. In this work, an extended corrosion characterization (at central tower plant storage temperature (565 °C)) has been carried out in two different grades of solar salt (industrial and refined purity) doped with the addition of 1 wt% Al2O3 nanoparticles or 1 wt% SiO2 nanoparticles. Corrosion rates were determined in commercial stainless steel commonly used in CSP technology (347SS) by gravimetric tests, measuring the weight gain during 1000 h, identifying the corrosion products by Scanning Electron Microscopy (SEM) and X-Ray Diffraction (XRD). The lowest corrosion rate (0.007 mm/year) was obtained in the refined solar salt with the addition of 1 wt% Al2O3 nanoparticles. A protective layer was formed in the steel-salt interphase, identified through XRD as Al2O3.

Suggested Citation

  • Fernández, Angel G. & Muñoz-Sánchez, Belen & Nieto-Maestre, Javier & García-Romero, Ana, 2019. "High temperature corrosion behavior on molten nitrate salt-based nanofluids for CSP plants," Renewable Energy, Elsevier, vol. 130(C), pages 902-909.
    • Handle: RePEc:eee:renene:v:130:y:2019:i:c:p:902-909
    DOI: 10.1016/j.renene.2018.07.018
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    References listed on IDEAS

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    1. Nieto-Maestre, Javier & Muñoz-Sánchez, Belén & Fernández, Angel G. & Faik, Abdessamad & Grosu, Yaroslav & García-Romero, Ana, 2020. "Compatibility of container materials for Concentrated Solar Power with a solar salt and alumina based nanofluid: A study under dynamic conditions," Renewable Energy, Elsevier, vol. 146(C), pages 384-396.
    2. Wang, Qiliang & Pei, Gang & Yang, Hongxing, 2021. "Techno-economic assessment of performance-enhanced parabolic trough receiver in concentrated solar power plants," Renewable Energy, Elsevier, vol. 167(C), pages 629-643.
    3. Skrbek, Kryštof & Bartůněk, Vilém & Sedmidubský, David, 2022. "Molten salt-based nanocomposites for thermal energy storage: Materials, preparation techniques and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 164(C).
    4. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).
    5. Gustavo García-Martin & María I. Lasanta & María T. de Miguel & Andre Illana Sánchez & Francisco J. Pérez-Trujillo, 2021. "Corrosion Behavior of VM12-SHC Steel in Contact with Solar Salt and Ternary Molten Salt in Accelerated Fluid Conditions," Energies, MDPI, vol. 14(18), pages 1-16, September.
    6. Luisa F. Cabeza & Emiliano Borri & Cristina Prieto, 2022. "Bibliometric Map on Corrosion in Concentrating Solar Power Plants," Energies, MDPI, vol. 15(7), pages 1-16, April.
    7. Yuan, Fan & Li, Ming-Jia & Qiu, Yu & Ma, Zhao & Li, Meng-Jie, 2019. "Specific heat capacity improvement of molten salt for solar energy applications using charged single-walled carbon nanotubes," Applied Energy, Elsevier, vol. 250(C), pages 1481-1490.

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