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Small-Scaled Production of Blue Hydrogen with Reduced Carbon Footprint

Author

Listed:
  • Yuriy Zagashvili

    (“HTR” LLC, 190000 Saint Petersburg, Russia
    “GSG” LLC, 190000 Saint Petersburg, Russia)

  • Aleksey Kuzmin

    (“HTR” LLC, 190000 Saint Petersburg, Russia
    “GSG” LLC, 190000 Saint Petersburg, Russia
    Department of Rocket and Space Technology, Baltic State Technical University “VOENMEH”, 190005 Saint Petersburg, Russia)

  • George Buslaev

    (Department of Oil and Gas, Saint Petersburg Mining University, 199106 Saint Petersburg, Russia)

  • Valentin Morenov

    (Department of Oil and Gas, Saint Petersburg Mining University, 199106 Saint Petersburg, Russia)

Abstract

This article reviews a method of hydrogen production based on partial non-catalytic oxidation of natural gas in an original synthesis gas generator. The working principles of the unit are similar to those of liquid-propellant rocket engines. This paper presents a description of the operation and technical characteristics of the synthesis gas generator. Its application in the creation of small-scaled plants with a capacity of up to 5–7 thousand m 3 /h of hydrogen is justified. Hydrogen production in the developed installation requires a two-stage method and includes a technological unit for producing a hydrogen-containing gas. Typical balance compositions of hydrogen-containing gas at the synthesis gas generator’s outlet are given. To increase the hydrogen concentration, it is proposed to carry out a two-stage steam catalytic conversion of carbon monoxide contained in the hydrogen-containing gas at the synthesis gas generator’s outlet using a single Cu–Zn–cement-containing composition. Based on thermodynamic calculations, quasi-optimal modes of natural gas partial oxidation with oxygen are formulated and the results of material balance calculation for the installation are presented. In order to produce “blue” hydrogen, the scheme of carbon dioxide separation and liquefaction is developed. The conclusion section of the paper contains the test results of a pilot demonstration unit and the recommendations for improving the technology and preventing soot formation.

Suggested Citation

  • Yuriy Zagashvili & Aleksey Kuzmin & George Buslaev & Valentin Morenov, 2021. "Small-Scaled Production of Blue Hydrogen with Reduced Carbon Footprint," Energies, MDPI, vol. 14(16), pages 1-11, August.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:16:p:5194-:d:619474
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    References listed on IDEAS

    as
    1. Kato, Takeyoshi & Kubota, Mitsuhiro & Kobayashi, Noriyuki & Suzuoki, Yasuo, 2005. "Effective utilization of by-product oxygen from electrolysis hydrogen production," Energy, Elsevier, vol. 30(14), pages 2580-2595.
    2. Mohammad Ostadi & Kristofer Gunnar Paso & Sandra Rodriguez-Fabia & Lars Erik Øi & Flavio Manenti & Magne Hillestad, 2020. "Process Integration of Green Hydrogen: Decarbonization of Chemical Industries," Energies, MDPI, vol. 13(18), pages 1-16, September.
    3. Chen, Wei-Hsin & Chen, Chia-Yang, 2020. "Water gas shift reaction for hydrogen production and carbon dioxide capture: A review," Applied Energy, Elsevier, vol. 258(C).
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    Cited by:

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    2. Gayatri Udaysinh Ingale & Hyun-Min Kwon & Soohwa Jeong & Dongho Park & Whidong Kim & Byeingryeol Bang & Young-Il Lim & Sung Won Kim & Youn-Bae Kang & Jungsoo Mun & Sunwoo Jun & Uendo Lee, 2022. "Assessment of Greenhouse Gas Emissions from Hydrogen Production Processes: Turquoise Hydrogen vs. Steam Methane Reforming," Energies, MDPI, vol. 15(22), pages 1-20, November.

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