IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i14p4202-d592943.html
   My bibliography  Save this article

Catalytic Hydroisomerisation of Fischer–Tropsch Waxes to Lubricating Oil and Investigation of the Correlation between Its Physical Properties and the Chemical Composition of the Corresponding Fuel Fractions

Author

Listed:
  • Philipp Neuner

    (Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany)

  • David Graf

    (Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany)

  • Heiko Mild

    (Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany)

  • Reinhard Rauch

    (Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany)

Abstract

Due to environmental concerns, the role of renewable sources for petroleum-based products has become an invaluable research topic. One possibility of achieving this goal is the Fischer–Tropsch synthesis (FTS) based on sustainable raw materials. Those materials include, but are not limited to, synthesis gas from biomass gasification or hydrogen through electrolysis powered by renewable electricity. In recent years, the utilisation of CO 2 as carbon source for FTS was one main R&D topic. This is one of the reasons for its increase in value and the removal of its label as being just exhaust gas. With the heavy product fraction of FTS, referred to as Fischer–Tropsch waxes (FTW), being rather limited in their application, catalytic upgrading can help to increase the economic viability of such a process by converting the waxes to high value transportation fuels and lubricating oils. In this paper, the dewaxing of FTW via hydroisomerisation and hydrocracking was investigated. A three phase fixed bed reactor was used in combination with a zeolitic catalyst with an AEL (SAPO-11) structure and 0.3 wt% platinum (Pt). The desired products were high quality white oils with low cloud points. These products were successfully produced in a one-step catalytic dewaxing process. Within this work, a direct correlation between the physical properties of the white oils and the chemical composition of the simultaneously produced fuel fractions could be established.

Suggested Citation

  • Philipp Neuner & David Graf & Heiko Mild & Reinhard Rauch, 2021. "Catalytic Hydroisomerisation of Fischer–Tropsch Waxes to Lubricating Oil and Investigation of the Correlation between Its Physical Properties and the Chemical Composition of the Corresponding Fuel Fra," Energies, MDPI, vol. 14(14), pages 1-14, July.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:14:p:4202-:d:592943
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/14/4202/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/14/4202/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Dwivedi, Gaurav & Sharma, M.P., 2014. "Impact of cold flow properties of biodiesel on engine performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 650-656.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. David D. J. Antia, 2023. "Conversion of Waste Synthesis Gas to Desalination Catalyst at Ambient Temperatures," Waste, MDPI, vol. 1(2), pages 1-29, May.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Can, Özer & Baklacioglu, Tolga & Özturk, Erkan & Turan, Onder, 2022. "Artificial neural networks modeling of combustion parameters for a diesel engine fueled with biodiesel fuel," Energy, Elsevier, vol. 247(C).
    2. Ni, Zihao & Zhai, Yuling & Li, Fashe & Wang, Hua & Yang, Kai & Wang, Bican & Chen, Yu, 2020. "Reaction kinetics analysis of branched-chain alkyl esters of palmitic acid and cold flow properties," Renewable Energy, Elsevier, vol. 147(P1), pages 719-729.
    3. Laura Aguado-Deblas & Jesús Hidalgo-Carrillo & Felipa M. Bautista & Diego Luna & Carlos Luna & Juan Calero & Alejandro Posadillo & Antonio A. Romero & Rafael Estevez, 2020. "Diethyl Ether as an Oxygenated Additive for Fossil Diesel/Vegetable Oil Blends: Evaluation of Performance and Emission Quality of Triple Blends on a Diesel Engine," Energies, MDPI, vol. 13(7), pages 1-16, March.
    4. Leng, Lijian & Li, Hui & Yuan, Xingzhong & Zhou, Wenguang & Huang, Huajun, 2018. "Bio-oil upgrading by emulsification/microemulsification: A review," Energy, Elsevier, vol. 161(C), pages 214-232.
    5. Carlos S. Osorio-González & Natali Gómez-Falcon & Fabiola Sandoval-Salas & Rahul Saini & Satinder K. Brar & Antonio Avalos Ramírez, 2020. "Production of Biodiesel from Castor Oil: A Review," Energies, MDPI, vol. 13(10), pages 1-22, May.
    6. Patel, Alok & Arora, Neha & Mehtani, Juhi & Pruthi, Vikas & Pruthi, Parul A., 2017. "Assessment of fuel properties on the basis of fatty acid profiles of oleaginous yeast for potential biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 604-616.
    7. Deviren, Halis, 2024. "Enhancing diesel engine efficiency and emission performance through oxygenated and non-oxygenated additives: A comparative study of alcohol and cycloalkane impacts on diesel-biodiesel blends," Energy, Elsevier, vol. 307(C).
    8. Varun, & Singh, Paramvir & Tiwari, Samaresh Kumar & Singh, Rituparn & Kumar, Naresh, 2017. "Modification in combustion chamber geometry of CI engines for suitability of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1016-1033.
    9. Sorate, Kamalesh A. & Bhale, Purnanand V., 2015. "Biodiesel properties and automotive system compatibility issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 777-798.
    10. Leesing, Ratanaporn & Siwina, Siraprapha & Ngernyen, Yuvarat & Fiala, Khanittha, 2022. "Innovative approach for co-production of single cell oil (SCO), novel carbon-based solid acid catalyst and SCO-based biodiesel from fallen Dipterocarpus alatus leaves," Renewable Energy, Elsevier, vol. 185(C), pages 47-60.
    11. Nguyen, Dinh Duc & Moghaddam, Hesam & Pirouzfar, Vahid & Fayyazbakhsh, Ahmad & Su, Chia-Hung, 2021. "Improving the gasoline properties by blending butanol-Al2O3 to optimize the engine performance and reduce air pollution," Energy, Elsevier, vol. 218(C).
    12. Laura Aguado-Deblas & Rafael Estevez & Jesús Hidalgo-Carrillo & Felipa M. Bautista & Carlos Luna & Juan Calero & Alejandro Posadillo & Antonio A. Romero & Diego Luna, 2020. "Outlook for Direct Use of Sunflower and Castor Oils as Biofuels in Compression Ignition Diesel Engines, Being Part of Diesel/Ethyl Acetate/Straight Vegetable Oil Triple Blends," Energies, MDPI, vol. 13(18), pages 1-14, September.
    13. Adrian Clenci & Rodica Niculescu & Amélie Danlos & Victor Iorga-Simăn & Alina Trică, 2016. "Impact of Biodiesel Blends and Di-Ethyl-Ether on the Cold Starting Performance of a Compression Ignition Engine," Energies, MDPI, vol. 9(4), pages 1-19, April.
    14. Cavalheiro, Leandro Fontoura & Misutsu, Marcelo Yukio & Rial, Rafael Cardoso & Viana, Luíz Henrique & Oliveira, Lincoln Carlos Silva, 2020. "Characterization of residues and evaluation of the physico chemical properties of soybean biodiesel and biodiesel: Diesel blends in different storage conditions," Renewable Energy, Elsevier, vol. 151(C), pages 454-462.
    15. Kim, Jun Young & Kim, Dongjae & Li, Zezhong John & Dariva, Claudio & Cao, Yankai & Ellis, Naoko, 2023. "Predicting and optimizing syngas production from fluidized bed biomass gasifiers: A machine learning approach," Energy, Elsevier, vol. 263(PC).
    16. Verma, Puneet & Sharma, M.P. & Dwivedi, Gaurav, 2016. "Impact of alcohol on biodiesel production and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 319-333.
    17. Renas Hasan Saeed Saeed & Youssef Kassem & Hüseyin Çamur, 2019. "Effect of Biodiesel Mixture Derived from Waste Frying-Corn, Frying-Canola-Corn and Canola-Corn Cooking Oils with Various ?Ages on Physicochemical Properties," Energies, MDPI, vol. 12(19), pages 1-26, September.
    18. Srikanth, H.V. & Venkatesh, J. & Godiganur, Sharanappa & Manne, Bhaskar, 2019. "Acetone and Diethyl ether: Improve cold flow properties of Dairy Washed Milkscum biodiesel," Renewable Energy, Elsevier, vol. 130(C), pages 446-451.
    19. T. M. Yunus Khan, 2020. "A Review of Performance-Enhancing Innovative Modifications in Biodiesel Engines," Energies, MDPI, vol. 13(17), pages 1-22, August.
    20. Mujtaba, M.A. & Masjuki, H.H. & Kalam, M.A. & Ong, Hwai Chyuan & Gul, M. & Farooq, M. & Soudagar, Manzoore Elahi M. & Ahmed, Waqar & Harith, M.H. & Yusoff, M.N.A.M., 2020. "Ultrasound-assisted process optimization and tribological characteristics of biodiesel from palm-sesame oil via response surface methodology and extreme learning machine - Cuckoo search," Renewable Energy, Elsevier, vol. 158(C), pages 202-214.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:14:p:4202-:d:592943. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.