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Spherical Sb Core/Nb 2 O 5 -C Double-Shell Structured Composite as an Anode Material for Li Secondary Batteries

Author

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  • Hyungeun Seo

    (School of Materials Science and Engineering, Kookmin University, Seoul 02707, Korea)

  • Kyungbae Kim

    (School of Materials Science and Engineering, Kookmin University, Seoul 02707, Korea)

  • Jae-Hun Kim

    (School of Materials Science and Engineering, Kookmin University, Seoul 02707, Korea)

Abstract

Antimony (Sb)-based materials are considered to be attractive for use in Li secondary battery anodes because of their high capacity. However, their huge volume change during Li insertion-extraction cycling limits their cycle performance. The Sb-active material can be combined with intercalation-based active materials to address these issues. In this study, spherical Sb core/Nb 2 O 5 shell structured composite materials were synthesized through a simple solvothermal process and a carbon coating was simultaneously added during heat treatment using a naphthalene precursor. The resulting double-shelled materials were characterized with X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and electron microscopy. The electrochemical test results showed that a reversible capacity of more than 450 mAh g −1 was retained after 100 cycles. This improved performance is ascribed to the double-shelled structure. The large volume change of the nano-sized Sb core material was alleviated by the double-shelled structure, which consisted of crystalline orthorhombic Nb 2 O 5 and amorphous carbon. The shell materials also aided rapid charge transport.

Suggested Citation

  • Hyungeun Seo & Kyungbae Kim & Jae-Hun Kim, 2020. "Spherical Sb Core/Nb 2 O 5 -C Double-Shell Structured Composite as an Anode Material for Li Secondary Batteries," Energies, MDPI, vol. 13(8), pages 1-10, April.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:8:p:1999-:d:347071
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    References listed on IDEAS

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    1. Lysander De Sutter & Gert Berckmans & Mario Marinaro & Jelle Smekens & Yousef Firouz & Margret Wohlfahrt-Mehrens & Joeri Van Mierlo & Noshin Omar, 2018. "Comprehensive Aging Analysis of Volumetric Constrained Lithium-Ion Pouch Cells with High Concentration Silicon-Alloy Anodes," Energies, MDPI, vol. 11(11), pages 1-21, October.
    2. Holger C. Hesse & Michael Schimpe & Daniel Kucevic & Andreas Jossen, 2017. "Lithium-Ion Battery Storage for the Grid—A Review of Stationary Battery Storage System Design Tailored for Applications in Modern Power Grids," Energies, MDPI, vol. 10(12), pages 1-42, December.
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