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Metal Hydride Beds-Phase Change Materials: Dual Mode Thermal Energy Storage for Medium-High Temperature Industrial Waste Heat Recovery

Author

Listed:
  • Serge Nyallang Nyamsi

    (South African Institute for Advanced Materials Chemistry, University of the Western Cape, Private Bag X17, Bellville 7535, South Africa)

  • Ivan Tolj

    (Faculty of Electrical Engineering, Mechanical Engineering and Naval Architecture, University of Split, Rudjera Boskovica 32, Split 21000, Croatia)

  • Mykhaylo Lototskyy

    (South African Institute for Advanced Materials Chemistry, University of the Western Cape, Private Bag X17, Bellville 7535, South Africa)

Abstract

Heat storage systems based on two-tank thermochemical heat storage are gaining momentum for their utilization in solar power plants or industrial waste heat recovery since they can efficiently store heat for future usage. However, their performance is generally limited by reactor configuration, design, and optimization on the one hand and most importantly on the selection of appropriate thermochemical materials. Metal hydrides, although at the early stage of research and development (in heat storage applications), can offer several advantages over other thermochemical materials (salt hydrates, metal hydroxides, oxide, and carbonates) such as high energy storage density and power density. This study presents a system that combines latent heat and thermochemical heat storage based on two-tank metal hydrides. The systems consist of two metal hydrides tanks coupled and equipped with a phase change material (PCM) jacket. During the heat charging process, the high-temperature metal hydride (HTMH) desorbs hydrogen, which is stored in the low-temperature metal hydride (LTMH). In the meantime, the heat generated from hydrogen absorption in the LTMH tank is stored as latent heat in a phase change material (PCM) jacket surrounding the LTMH tank, to be reused during the heat discharging. A 2D axis-symmetric mathematical model was developed to investigate the heat and mass transfer phenomena inside the beds and the PCM jacket. The effects of the thermo-physical properties of the PCM and the PCM jacket size on the performance indicators (energy density, power output, and energy recovery efficiency) of the heat storage system are analyzed and discussed. The results showed that the PCM melting point, the latent heat of fusion, the density and the thermal conductivity had significant impacts on these performance indicators.

Suggested Citation

  • Serge Nyallang Nyamsi & Ivan Tolj & Mykhaylo Lototskyy, 2019. "Metal Hydride Beds-Phase Change Materials: Dual Mode Thermal Energy Storage for Medium-High Temperature Industrial Waste Heat Recovery," Energies, MDPI, vol. 12(20), pages 1-27, October.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:20:p:3949-:d:277586
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    Cited by:

    1. Serge Nyallang Nyamsi & Mykhaylo Lototskyy & Ivan Tolj, 2020. "Optimal Design of Combined Two-Tank Latent and Metal Hydrides-Based Thermochemical Heat Storage Systems for High-Temperature Waste Heat Recovery," Energies, MDPI, vol. 13(16), pages 1-18, August.
    2. Bhogilla, Satya Sekhar, 2021. "Numerical simulation of metal hydride based thermal energy storage system for concentrating solar power plants," Renewable Energy, Elsevier, vol. 172(C), pages 1013-1020.
    3. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
    4. Sunku Prasad, J. & Muthukumar, P., 2022. "Design and performance analysis of an annular metal hydride reactor for large-scale hydrogen storage applications," Renewable Energy, Elsevier, vol. 181(C), pages 1155-1166.
    5. Serge Nyallang Nyamsi & Ivan Tolj, 2021. "The Impact of Active and Passive Thermal Management on the Energy Storage Efficiency of Metal Hydride Pairs Based Heat Storage," Energies, MDPI, vol. 14(11), pages 1-24, May.
    6. Julián Puszkiel & José M. Bellosta von Colbe & Julian Jepsen & Sergey V. Mitrokhin & Elshad Movlaev & Victor Verbetsky & Thomas Klassen, 2020. "Designing an AB 2 -Type Alloy (TiZr-CrMnMo) for the Hybrid Hydrogen Storage Concept," Energies, MDPI, vol. 13(11), pages 1-26, June.
    7. Serge Nyallang Nyamsi & Ivan Tolj & Michał Jan Gęca, 2022. "Dehydrogenation of Metal Hydride Reactor-Phase Change Materials Coupled with Light-Duty Fuel Cell Vehicles," Energies, MDPI, vol. 15(9), pages 1-18, April.
    8. Lijun Gao & Yunze Li & Huijuan Xu & Xin Zhang & Man Yuan & Xianwen Ning, 2019. "Numerical Investigation on Heat-Transfer and Hydromechanical Performance inside Contaminant-Insensitive Sublimators under a Vacuum Environment for Spacecraft Applications," Energies, MDPI, vol. 12(23), pages 1-21, November.

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