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Fuel additives from glycerol etherification with light olefins: State of the art

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  • Izquierdo, J.F.
  • Montiel, M.
  • Palés, I.
  • Outón, P.R.
  • Galán, M.
  • Jutglar, L.
  • Villarrubia, M.
  • Izquierdo, M.
  • Hermo, M.P.
  • Ariza, X.

Abstract

The production of biofuel has increased considerably over the last years. Glycerol, a by-product of biodiesel synthesis, accounts for 10wt% of the total product and has a limited range of applications. Etherification reaction of glycerol with light olefins (isobutene, isoamylenes) in liquid phase and catalyzed by acidic macroporous ion-exchange resins could be an attractive solution (i) to address the excess of glycerol, and (ii) to increase the diesel volume using light olefins, obtaining a product of good properties, higher value and especially useful as an additive in diesel and also in biodiesel.

Suggested Citation

  • Izquierdo, J.F. & Montiel, M. & Palés, I. & Outón, P.R. & Galán, M. & Jutglar, L. & Villarrubia, M. & Izquierdo, M. & Hermo, M.P. & Ariza, X., 2012. "Fuel additives from glycerol etherification with light olefins: State of the art," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(9), pages 6717-6724.
    • Handle: RePEc:eee:rensus:v:16:y:2012:i:9:p:6717-6724
    DOI: 10.1016/j.rser.2012.08.005
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    References listed on IDEAS

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    1. Rahmat, Norhasyimi & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2010. "Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 987-1000, April.
    2. Janaun, Jidon & Ellis, Naoko, 2010. "Perspectives on biodiesel as a sustainable fuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(4), pages 1312-1320, May.
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    2. Jia, Guangxin & He, Beibei & Ma, Wenlin & Sun, Yifan, 2019. "Thermodynamic analysis based on simultaneous chemical and phase equilibrium for dehydration of glycerol with methanol," Energy, Elsevier, vol. 188(C).
    3. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    4. Rafael Estevez & Laura Aguado-Deblas & Diego Luna & Felipa M. Bautista, 2019. "An Overview of the Production of Oxygenated Fuel Additives by Glycerol Etherification, Either with Isobutene or tert -Butyl Alcohol, over Heterogeneous Catalysts," Energies, MDPI, vol. 12(12), pages 1-20, June.
    5. Aghbashlo, Mortaza & Tabatabaei, Meisam & Rastegari, Hajar & Ghaziaskar, Hassan S. & Roodbar Shojaei, Taha, 2018. "On the exergetic optimization of solketalacetin synthesis as a green fuel additive through ketalization of glycerol-derived monoacetin with acetone," Renewable Energy, Elsevier, vol. 126(C), pages 242-253.
    6. Galadima, Ahmad & Muraza, Oki, 2014. "Biodiesel production from algae by using heterogeneous catalysts: A critical review," Energy, Elsevier, vol. 78(C), pages 72-83.
    7. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Hezaveh, Hadi, 2014. "Glycerol for renewable acrolein production by catalytic dehydration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 28-59.
    8. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).

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