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Hydrate Stability and Methane Recovery from Gas Hydrate through CH 4 –CO 2 Replacement in Different Mass Transfer Scenarios

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  • Jyoti Shanker Pandey

    (Center for Energy Resource Engineering (CERE), Department of Chemical Engineering, Technical University of Denmark, Lyngby 2800, Denmark)

  • Nicolas von Solms

    (Center for Energy Resource Engineering (CERE), Department of Chemical Engineering, Technical University of Denmark, Lyngby 2800, Denmark)

Abstract

CH 4 –CO 2 replacement is a carbon-negative, safer gas production technique to produce methane gas from natural gas hydrate reservoirs by injecting pure CO 2 or other gas mixtures containing CO 2 . Laboratory-scale experiments show that this technique produces low methane volume and has a slow replacement rate due to the mass transfer barrier created due to impermeable CO 2 hydrate layer formation, thus making the process commercially unattractive. This mass-transfer barrier can be reduced through pressure reduction techniques and chemical techniques; however, very few studies have focused on depressurization-assisted and chemical-assisted CH 4 –CO 2 replacement to lower mass-transfer barriers and there are many unknowns. In this work, we qualitatively and quantitatively investigated the effect of the pressure reduction and presence of a hydrate promoter on mixed hydrate stability, CH 4 recovery, and risk of water production during CH 4 –CO 2 exchange. Exchange experiments were carried out using the 500 ppm sodium dodecyl sulfate (SDS) solution inside a high-pressure stirred reactor. Our results indicated that mixed hydrate stability and methane recovery depends on the degree of pressure reduction, type, and composition of injected gas. Final selection between CO 2 and CO 2 + N 2 gas depends on the tradeoff between mixed hydrate stability pressure and methane recovery. Hydrate morphology studies suggest that production of water during the CH 4 –CO 2 exchange is a stochastic phenomenon that is dependent on many parameters.

Suggested Citation

  • Jyoti Shanker Pandey & Nicolas von Solms, 2019. "Hydrate Stability and Methane Recovery from Gas Hydrate through CH 4 –CO 2 Replacement in Different Mass Transfer Scenarios," Energies, MDPI, vol. 12(12), pages 1-20, June.
  • Handle: RePEc:gam:jeners:v:12:y:2019:i:12:p:2309-:d:240431
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    References listed on IDEAS

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    Cited by:

    1. Gajanan, K. & Ranjith, P.G. & Yang, S.Q. & Xu, T., 2024. "Advances in research and developments on natural gas hydrate extraction with gas exchange," Renewable and Sustainable Energy Reviews, Elsevier, vol. 190(PB).
    2. Ouyang, Qian & Pandey, Jyoti Shanker & von Solms, Nicolas, 2022. "Insights into multistep depressurization of CH4/CO2 mixed hydrates in unconsolidated sediments," Energy, Elsevier, vol. 260(C).
    3. Tsypkin, G.G., 2021. "Analytical study of CO2–CH4 exchange in hydrate at high rates of carbon dioxide injection into a reservoir saturated with methane hydrate and gaseous methane," Energy, Elsevier, vol. 233(C).
    4. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    5. Zhang, Kai & Lau, Hon Chung, 2022. "Sequestering CO2 as CO2 hydrate in an offshore saline aquifer by reservoir pressure management," Energy, Elsevier, vol. 239(PC).
    6. Marat K. Khasanov & Guzal R. Rafikova & Nail G. Musakaev, 2020. "Mathematical Model of Carbon Dioxide Injection into a Porous Reservoir Saturated with Methane and Its Gas Hydrate," Energies, MDPI, vol. 13(2), pages 1-17, January.
    7. Oleg Bazaluk & Kateryna Sai & Vasyl Lozynskyi & Mykhailo Petlovanyi & Pavlo Saik, 2021. "Research into Dissociation Zones of Gas Hydrate Deposits with a Heterogeneous Structure in the Black Sea," Energies, MDPI, vol. 14(5), pages 1-24, March.
    8. Liu, Fa-Ping & Li, Ai-Rong & Qing, Sheng-Lan & Luo, Ze-Dong & Ma, Yu-Ling, 2022. "Formation kinetics, mechanism of CO2 hydrate and its applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    9. Jyoti Shanker Pandey & Yousef Jouljamal Daas & Adam Paul Karcz & Nicolas von Solms, 2020. "Enhanced Hydrate-Based Geological CO 2 Capture and Sequestration as a Mitigation Strategy to Address Climate Change," Energies, MDPI, vol. 13(21), pages 1-28, October.
    10. Ouyang, Qian & Zheng, Junjie & Pandey, Jyoti Shanker & von Solms, Nicolas & Linga, Praveen, 2024. "Coupling amino acid injection and slow depressurization with hydrate swapping exploitation: An effective strategy to enhance in-situ CO2 storage in hydrate-bearing sediment," Applied Energy, Elsevier, vol. 366(C).

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