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Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage

Author

Listed:
  • Kasper T. Møller

    (Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark)

  • Drew Sheppard

    (Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark
    Department of Physics and Astronomy, Fuels and Energy Technology Institute, Curtin University, GPO Box U1987, Perth, WA 6845, Australia)

  • Dorthe B. Ravnsbæk

    (Department of Physics, Chemistry and Pharmacy, University of Southern Denmark, Campusvej 55, 5230 Odense M, Denmark)

  • Craig E. Buckley

    (Department of Physics and Astronomy, Fuels and Energy Technology Institute, Curtin University, GPO Box U1987, Perth, WA 6845, Australia)

  • Etsuo Akiba

    (International Research Center for Hydrogen Energy, Kyushu University, Fukuoka 819-0395, Japan
    WPI International Institute for Carbon Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka 819-0395, Japan
    Department of Mechanical Engineering, Faculty of Engineering, Kyushu University, Fukuoka 819-0395, Japan)

  • Hai-Wen Li

    (Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark
    International Research Center for Hydrogen Energy, Kyushu University, Fukuoka 819-0395, Japan
    WPI International Institute for Carbon Neutral Energy Research (WPI-I2CNER), Kyushu University, Fukuoka 819-0395, Japan
    Kyushu University Platform of Inter/Transdisciplinary Energy Research, Fukuoka 819-0395, Japan)

  • Torben R. Jensen

    (Interdisciplinary Nanoscience Center (iNANO) and Department of Chemistry, Aarhus University, DK-8000 Aarhus, Denmark)

Abstract

Hydrogen has a very diverse chemistry and reacts with most other elements to form compounds, which have fascinating structures, compositions and properties. Complex metal hydrides are a rapidly expanding class of materials, approaching multi-functionality, in particular within the energy storage field. This review illustrates that complex metal hydrides may store hydrogen in the solid state, act as novel battery materials, both as electrolytes and electrode materials, or store solar heat in a more efficient manner as compared to traditional heat storage materials. Furthermore, it is highlighted how complex metal hydrides may act in an integrated setup with a fuel cell. This review focuses on the unique properties of light element complex metal hydrides mainly based on boron, nitrogen and aluminum, e.g., metal borohydrides and metal alanates. Our hope is that this review can provide new inspiration to solve the great challenge of our time: efficient conversion and large-scale storage of renewable energy.

Suggested Citation

  • Kasper T. Møller & Drew Sheppard & Dorthe B. Ravnsbæk & Craig E. Buckley & Etsuo Akiba & Hai-Wen Li & Torben R. Jensen, 2017. "Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage," Energies, MDPI, vol. 10(10), pages 1-30, October.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:10:p:1645-:d:115489
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    References listed on IDEAS

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    7. Christoph Frommen & Magnus H. Sørby & Michael Heere & Terry D. Humphries & Jørn E. Olsen & Bjørn C. Hauback, 2017. "Rare Earth Borohydrides—Crystal Structures and Thermal Properties," Energies, MDPI, vol. 10(12), pages 1-24, December.
    8. Efstathios E. Michaelides, 2021. "Thermodynamics, Energy Dissipation, and Figures of Merit of Energy Storage Systems—A Critical Review," Energies, MDPI, vol. 14(19), pages 1-41, September.
    9. Malleswararao, K. & Aswin, N. & Srinivasa Murthy, S. & Dutta, Pradip, 2022. "Studies on long-term and buffer modes of operations of a thermal energy storage system using coupled metal hydrides," Energy, Elsevier, vol. 258(C).
    10. Dragan Pamučar & Ibrahim Badi & Korica Sanja & Radojko Obradović, 2018. "A Novel Approach for the Selection of Power-Generation Technology Using a Linguistic Neutrosophic CODAS Method: A Case Study in Libya," Energies, MDPI, vol. 11(9), pages 1-25, September.
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