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Rare Earth Borohydrides—Crystal Structures and Thermal Properties

Author

Listed:
  • Christoph Frommen

    (Institute for Energy Technology, Physics Department, P.O. Box 40, NO-2027 Kjeller, Norway)

  • Magnus H. Sørby

    (Institute for Energy Technology, Physics Department, P.O. Box 40, NO-2027 Kjeller, Norway)

  • Michael Heere

    (Institute for Energy Technology, Physics Department, P.O. Box 40, NO-2027 Kjeller, Norway
    Research Neutron Source Munich (FRM2) and Karlsruhe Institute of Technology (KIT), Institute for Applied Materials—Energy Storage Systems (IAM-ESS), 76344 Eggenstein, Germany)

  • Terry D. Humphries

    (Department of Physics and Astronomy, Fuels and Energy Technology Institute, Curtin University, GPO Box U1987, Perth 6845, Australia)

  • Jørn E. Olsen

    (Institute for Energy Technology, Physics Department, P.O. Box 40, NO-2027 Kjeller, Norway)

  • Bjørn C. Hauback

    (Institute for Energy Technology, Physics Department, P.O. Box 40, NO-2027 Kjeller, Norway)

Abstract

Rare earth ( RE ) borohydrides have received considerable attention during the past ten years as possible hydrogen storage materials due to their relatively high gravimetric hydrogen density. This review illustrates the rich chemistry, structural diversity and thermal properties of borohydrides containing RE elements. In addition, it highlights the decomposition and rehydrogenation properties of composites containing RE -borohydrides, light-weight metal borohydrides such as LiBH 4 and additives such as LiH.

Suggested Citation

  • Christoph Frommen & Magnus H. Sørby & Michael Heere & Terry D. Humphries & Jørn E. Olsen & Bjørn C. Hauback, 2017. "Rare Earth Borohydrides—Crystal Structures and Thermal Properties," Energies, MDPI, vol. 10(12), pages 1-24, December.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:12:p:2115-:d:122585
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    References listed on IDEAS

    as
    1. Kasper T. Møller & Drew Sheppard & Dorthe B. Ravnsbæk & Craig E. Buckley & Etsuo Akiba & Hai-Wen Li & Torben R. Jensen, 2017. "Complex Metal Hydrides for Hydrogen, Thermal and Electrochemical Energy Storage," Energies, MDPI, vol. 10(10), pages 1-30, October.
    2. Pascal Schouwink & Morten B. Ley & Antoine Tissot & Hans Hagemann & Torben R. Jensen & Ľubomír Smrčok & Radovan Černý, 2014. "Structure and properties of complex hydride perovskite materials," Nature Communications, Nature, vol. 5(1), pages 1-10, December.
    3. Hai-Wen Li & Yigang Yan & Shin-ichi Orimo & Andreas Züttel & Craig M. Jensen, 2011. "Recent Progress in Metal Borohydrides for Hydrogen Storage," Energies, MDPI, vol. 4(1), pages 1-30, January.
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