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Optimization and kinetics of biodiesel production from Mahua oil using manganese doped zinc oxide nanocatalyst

Author

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  • Baskar, G.
  • Gurugulladevi, A.
  • Nishanthini, T.
  • Aiswarya, R.
  • Tamilarasan, K.

Abstract

The production of biodiesel has rapid development in the recent years due to the benefits associated with its ability to minimize environmental pollution. Heterogeneous catalyst for production of biodiesel is a preferred route for its easier recovery and no demand for aqueous treatment. Transesterification of fatty acids into biodiesel using transition metal oxide gives higher conversion into their corresponding methyl esters in a short time. In the present work, manganese doped zinc oxide is used as a heterogeneous catalyst for the production of biodiesel from Mahua oil. The synthesized manganese doped zinc oxide nanocatalyst was characterized by XRD and SEM. The SEM and XRD results confirmed the hexagonal structure of the catalyst with the particle size of 24.18 nm. The 8% (w/v) catalyst concentration, 1:7% (v/v) of oil to methanol ratio, 50 min of reaction time and 50 °C of reaction temperature were found to be the optimum process condition for the maximum biodiesel yield of 97%. The presence of methyl esters in biodiesel was confirmed by FT-IR and GC-MS analysis.

Suggested Citation

  • Baskar, G. & Gurugulladevi, A. & Nishanthini, T. & Aiswarya, R. & Tamilarasan, K., 2017. "Optimization and kinetics of biodiesel production from Mahua oil using manganese doped zinc oxide nanocatalyst," Renewable Energy, Elsevier, vol. 103(C), pages 641-646.
    • Handle: RePEc:eee:renene:v:103:y:2017:i:c:p:641-646
    DOI: 10.1016/j.renene.2016.10.077
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    References listed on IDEAS

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    1. Zhang, X.L. & Yan, S. & Tyagi, R.D. & Surampalli, R.Y., 2013. "Biodiesel production from heterotrophic microalgae through transesterification and nanotechnology application in the production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 216-223.
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    1. Arunkumar, M. & Kannan, M. & Murali, G., 2019. "Experimental studies on engine performance and emission characteristics using castor biodiesel as fuel in CI engine," Renewable Energy, Elsevier, vol. 131(C), pages 737-744.
    2. P. Sujin & P. M. Diaz & Ajith J. Kings & L. R. Monisha Miriam, 2023. "Sustainable biodiesel production from Ceiba penandra, Mahua longifolia, and Azadirachta indica using CaO-TiO2 nano catalyst," Energy & Environment, , vol. 34(3), pages 640-662, May.
    3. Sahar, Juma & Farooq, Muhammad & Ramli, Anita & Naeem, Abdul & Khattak, Noor Saeed & Ghazi, Zahid Ali, 2022. "Highly efficient heteropoly acid decorated SnO2@Co-ZIF nanocatalyst for sustainable biodiesel production from Nannorrhops ritchiana seeds oil," Renewable Energy, Elsevier, vol. 198(C), pages 306-318.
    4. Yatish, K.V. & Lalithamba, H.S. & Suresh, R. & Latha, H.K.E., 2020. "Ochrocarpus longifolius assisted green synthesis of CaTiO3 nanoparticle for biodiesel production and its kinetic study," Renewable Energy, Elsevier, vol. 147(P1), pages 310-321.
    5. Yatish, K.V. & Prakash, R. Mithun & Ningaraju, C. & Sakar, M. & GeethaBalakrishna, R. & Lalithamba, H.S., 2021. "Terminalia chebula as a novel green source for the synthesis of copper oxide nanoparticles and as feedstock for biodiesel production and its application on diesel engine," Energy, Elsevier, vol. 215(PB).
    6. Ahmad, Tanweer & Danish, Mohammed & Kale, Pradeep & Geremew, Belete & Adeloju, Samuel B. & Nizami, Maniruddin & Ayoub, Muhammad, 2019. "Optimization of process variables for biodiesel production by transesterification of flaxseed oil and produced biodiesel characterizations," Renewable Energy, Elsevier, vol. 139(C), pages 1272-1280.
    7. Munir, Mamoona & Ahmad, Mushtaq & Saeed, Muhammad & Waseem, Amir & Rehan, Mohammad & Nizami, Abdul-Sattar & Zafar, Muhammad & Arshad, Muhammad & Sultana, Shazia, 2019. "Sustainable production of bioenergy from novel non-edible seed oil (Prunus cerasoides) using bimetallic impregnated montmorillonite clay catalyst," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 321-332.
    8. Sandouqa, Arwa & Al-Hamamre, Zayed, 2021. "Economical evaluation of jojoba cultivation for biodiesel production in Jordan," Renewable Energy, Elsevier, vol. 177(C), pages 1116-1132.
    9. Maleki, Basir & Ashraf Talesh, S. Siamak, 2022. "Optimization of ZnO incorporation to αFe2O3 nanoparticles as an efficient catalyst for biodiesel production in a sonoreactor: Application on the CI engine," Renewable Energy, Elsevier, vol. 182(C), pages 43-59.
    10. Maria Ameen & Mushtaq Ahmad & Muhammad Zafar & Mamoona Munir & Muhammad Mujtaba Mujtaba & Shazia Sultana & Rozina . & Samah Elsayed El-Khatib & Manzoore Elahi M. Soudagar & M. A. Kalam, 2022. "Prospects of Catalysis for Process Sustainability of Eco-Green Biodiesel Synthesis via Transesterification: A State-Of-The-Art Review," Sustainability, MDPI, vol. 14(12), pages 1-38, June.
    11. Shurooq T. Al-Humairi & Jonathan G. M. Lee & Musa Salihu & Adam P. Harvey, 2022. "Biodiesel Production through Acid Catalyst In Situ Reactive Extraction of Chlorella vulgaris Foamate," Energies, MDPI, vol. 15(12), pages 1-20, June.
    12. Ashok, A. & Ratnaji, T. & John Kennedy, L. & Judith Vijaya, J. & Gnana Pragash, R., 2021. "Magnetically recoverable Mg substituted zinc ferrite nanocatalyst for biodiesel production: Process optimization, kinetic and thermodynamic analysis," Renewable Energy, Elsevier, vol. 163(C), pages 480-494.
    13. Rajaeifar, Mohammad Ali & Abdi, Reza & Tabatabaei, Meisam, 2017. "Expanded polystyrene waste application for improving biodiesel environmental performance parameters from life cycle assessment point of view," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 278-298.
    14. Kazemi Shariat Panahi, Hamed & Hosseinzadeh-Bandbafha, Homa & Dehhaghi, Mona & Orooji, Yasin & Mahian, Omid & Shahbeik, Hossein & Kiehbadroudinezhad, Mohammadali & Kalam, Md Abul & Karimi-Maleh, Hassa, 2024. "Nanotechnology applications in biodiesel processing and production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).

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