IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v96y2016ipap490-497.html
   My bibliography  Save this article

Reaction pathways of hemicellulose and mechanism of biomass pyrolysis in hydrogen plasma: A density functional theory study

Author

Listed:
  • Huang, Xiaoyuan
  • Cheng, Dang-guo
  • Chen, Fengqiu
  • Zhan, Xiaoli

Abstract

In this work, the reaction pathways of hemicellulose were investigated for a complete understanding of the mechanism of biomass pyrolysis in thermal plasma. Energies of the possible reaction pathways of three model compounds of hemicellulose, xylose, O-acetyl xylose and 4-O-MeGlcA, in hydrogen plasma were estimated through density functional theory (DFT), and the most favorable reaction routes were proposed. Combining with our previous work, the effects of the biomass composition on their pyrolysis behavior in hydrogen plasma were discussed, and the production distribution was predicted. The reaction mechanism of biomass pyrolysis in hydrogen plasma was clarified finally, which indicated that active H in plasma played a very important role in dehydrogenation reactions.

Suggested Citation

  • Huang, Xiaoyuan & Cheng, Dang-guo & Chen, Fengqiu & Zhan, Xiaoli, 2016. "Reaction pathways of hemicellulose and mechanism of biomass pyrolysis in hydrogen plasma: A density functional theory study," Renewable Energy, Elsevier, vol. 96(PA), pages 490-497.
    • Handle: RePEc:eee:renene:v:96:y:2016:i:pa:p:490-497
    DOI: 10.1016/j.renene.2016.04.080
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148116303822
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2016.04.080?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Gani, Asri & Naruse, Ichiro, 2007. "Effect of cellulose and lignin content on pyrolysis and combustion characteristics for several types of biomass," Renewable Energy, Elsevier, vol. 32(4), pages 649-661.
    2. Hamad, Mohamed A. & Radwan, Aly M. & Heggo, Dalia A. & Moustafa, Tarek, 2016. "Hydrogen rich gas production from catalytic gasification of biomass," Renewable Energy, Elsevier, vol. 85(C), pages 1290-1300.
    3. Parthasarathy, Prakash & Narayanan, K. Sheeba, 2014. "Hydrogen production from steam gasification of biomass: Influence of process parameters on hydrogen yield – A review," Renewable Energy, Elsevier, vol. 66(C), pages 570-579.
    4. Goumri-Said, Souraya & Ahmed, Rashid & Kanoun, Mohammed Benali, 2016. "Density-functional theory study of high hydrogen content complex hydrides Mg(BH4)2 at low temperature," Renewable Energy, Elsevier, vol. 90(C), pages 114-119.
    5. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ansari, Khursheed B. & Kamal, Bushra & Beg, Sidra & Wakeel Khan, Md. Aquib & Khan, Mohd Shariq & Al Mesfer, Mohammed K. & Danish, Mohd., 2021. "Recent developments in investigating reaction chemistry and transport effects in biomass fast pyrolysis: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    2. Elhambakhsh, Abbas & Van Duc Long, Nguyen & Lamichhane, Pradeep & Hessel, Volker, 2023. "Recent progress and future directions in plasma-assisted biomass conversion to hydrogen," Renewable Energy, Elsevier, vol. 218(C).
    3. Tamer Y. A. Fahmy & Yehia Fahmy & Fardous Mobarak & Mohamed El-Sakhawy & Ragab E. Abou-Zeid, 2020. "Biomass pyrolysis: past, present, and future," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 22(1), pages 17-32, January.
    4. Neto, Abel F.G. & Marques, Francisco C. & Amador, Adriana T. & Ferreira, Amanda D.S. & Neto, Antonio M.J.C., 2019. "DFT and canonical ensemble investigations on the thermodynamic properties of Syngas and natural gas/Syngas mixtures," Renewable Energy, Elsevier, vol. 130(C), pages 495-509.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Couto, Nuno Dinis & Silva, Valter Bruno & Monteiro, Eliseu & Rouboa, Abel & Brito, Paulo, 2017. "An experimental and numerical study on the Miscanthus gasification by using a pilot scale gasifier," Renewable Energy, Elsevier, vol. 109(C), pages 248-261.
    2. Elena David, 2020. "Evaluation of Hydrogen Yield Evolution in Gaseous Fraction and Biochar Structure Resulting from Walnut Shells Pyrolysis," Energies, MDPI, vol. 13(23), pages 1-17, December.
    3. Antonio Molino & Vincenzo Larocca & Simeone Chianese & Dino Musmarra, 2018. "Biofuels Production by Biomass Gasification: A Review," Energies, MDPI, vol. 11(4), pages 1-31, March.
    4. Ramos, Ana & Monteiro, Eliseu & Rouboa, Abel, 2019. "Numerical approaches and comprehensive models for gasification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 188-206.
    5. Cheng Li & Xiaochen Yue & Jun Yang & Yafeng Yang & Haiping Gu & Wanxi Peng, 2019. "Catalytic Fast Pyrolysis of Forestry Wood Waste for Bio-Energy Recovery Using Nano-Catalysts," Energies, MDPI, vol. 12(20), pages 1-12, October.
    6. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    7. Burra, K.G. & Hussein, M.S. & Amano, R.S. & Gupta, A.K., 2016. "Syngas evolutionary behavior during chicken manure pyrolysis and air gasification," Applied Energy, Elsevier, vol. 181(C), pages 408-415.
    8. Devasahayam, Sheila & Albijanic, Boris, 2024. "Predicting hydrogen production from co-gasification of biomass and plastics using tree based machine learning algorithms," Renewable Energy, Elsevier, vol. 222(C).
    9. Alam, Mahboob & Bhavanam, Anjireddy & Jana, Ashirbad & Viroja, Jaimin kumar S. & Peela, Nageswara Rao, 2020. "Co-pyrolysis of bamboo sawdust and plastic: Synergistic effects and kinetics," Renewable Energy, Elsevier, vol. 149(C), pages 1133-1145.
    10. Banerjee, Debarun & Kushwaha, Nidhi & Shetti, Nagaraj P. & Aminabhavi, Tejraj M. & Ahmad, Ejaz, 2022. "Green hydrogen production via photo-reforming of bio-renewable resources," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    11. Chen, Yu-Kai & Lin, Cheng-Han & Wang, Wei-Cheng, 2020. "The conversion of biomass into renewable jet fuel," Energy, Elsevier, vol. 201(C).
    12. Król, Danuta & Poskrobko, Sławomir, 2016. "High-methane gasification of fuels from waste – Experimental identification," Energy, Elsevier, vol. 116(P1), pages 592-600.
    13. Ansari, Khursheed B. & Gaikar, Vilas G., 2019. "Investigating production of hydrocarbon rich bio-oil from grassy biomass using vacuum pyrolysis coupled with online deoxygenation of volatile products over metallic iron," Renewable Energy, Elsevier, vol. 130(C), pages 305-318.
    14. Peter N. Ciesielski & M. Brennan Pecha & Vivek S. Bharadwaj & Calvin Mukarakate & G. Jeremy Leong & Branden Kappes & Michael F. Crowley & Seonah Kim & Thomas D. Foust & Mark R. Nimlos, 2018. "Advancing catalytic fast pyrolysis through integrated multiscale modeling and experimentation: Challenges, progress, and perspectives," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 7(4), July.
    15. Dong, Shengfei & Liu, Ziyu & Yang, Xiaoyi, 2024. "Exploration of hydrothermal liquefaction of multiple algae to improve bio-crude quality and carbohydrate utilization," Applied Energy, Elsevier, vol. 361(C).
    16. Arnob Das & Susmita Datta Peu, 2022. "A Comprehensive Review on Recent Advancements in Thermochemical Processes for Clean Hydrogen Production to Decarbonize the Energy Sector," Sustainability, MDPI, vol. 14(18), pages 1-42, September.
    17. Al-Rahbi, Amal S. & Williams, Paul T., 2017. "Hydrogen-rich syngas production and tar removal from biomass gasification using sacrificial tyre pyrolysis char," Applied Energy, Elsevier, vol. 190(C), pages 501-509.
    18. Lacrimioara Senila & Ioan Tenu & Petru Carlescu & Daniela Alexandra Scurtu & Eniko Kovacs & Marin Senila & Oana Cadar & Marius Roman & Diana Elena Dumitras & Cecilia Roman, 2022. "Characterization of Biobriquettes Produced from Vineyard Wastes as a Solid Biofuel Resource," Agriculture, MDPI, vol. 12(3), pages 1-13, February.
    19. Xie, Yingpu & Zeng, Kuo & Flamant, Gilles & Yang, Haiping & Liu, Nian & He, Xiao & Yang, Xinyi & Nzihou, Ange & Chen, Hanping, 2019. "Solar pyrolysis of cotton stalk in molten salt for bio-fuel production," Energy, Elsevier, vol. 179(C), pages 1124-1132.
    20. Zhang, Guozhao & Liu, Hao & Wang, Jia & Wu, Baojia, 2018. "Catalytic gasification characteristics of rice husk with calcined dolomite," Energy, Elsevier, vol. 165(PB), pages 1173-1177.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:96:y:2016:i:pa:p:490-497. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.