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Characterization of calcium chloride tetrahydrate as a phase change material and thermodynamic analysis of the results

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  • Ushak, Svetlana
  • Suárez, Miriam
  • Véliz, Sussy
  • Fernández, Angel G.
  • Flores, Elsa
  • Galleguillos, Héctor R.

Abstract

To study the feasibility of calcium chloride tetrahydrate as a phase-change material, we determined its melting point and heat of fusion using differential scanning calorimetry (DSC) in the temperature range of 0 °C-60 °C. We also determined the density and viscosity of molten calcium chloride tetrahydrate in the temperature range of 40 °C-65 °C and studied the effect of adding small quantities of LiCl, NaCl and KCl (1 mass %) on the resulting thermal and physical properties. Based on the determination of the thermophysical properties, the energy storage density was evaluated for the different systems. The CaCl2·4H2O + 1 mass % of LiCl exhibited higher values (174 J/cm3) than pure CaCl2·4H2O (156 J/cm3), and the CaCl2·4H2O + 1 mass % of NaCl (151 J/cm3).

Suggested Citation

  • Ushak, Svetlana & Suárez, Miriam & Véliz, Sussy & Fernández, Angel G. & Flores, Elsa & Galleguillos, Héctor R., 2016. "Characterization of calcium chloride tetrahydrate as a phase change material and thermodynamic analysis of the results," Renewable Energy, Elsevier, vol. 95(C), pages 213-224.
    • Handle: RePEc:eee:renene:v:95:y:2016:i:c:p:213-224
    DOI: 10.1016/j.renene.2016.04.012
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    1. Sharma, Atul & Tyagi, V.V. & Chen, C.R. & Buddhi, D., 2009. "Review on thermal energy storage with phase change materials and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(2), pages 318-345, February.
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    3. Wang, Yi & Xia, Tian Dong & Feng, Hui Xia & Zhang, Han, 2011. "Stearic acid/polymethylmethacrylate composite as form-stable phase change materials for latent heat thermal energy storage," Renewable Energy, Elsevier, vol. 36(6), pages 1814-1820.
    4. Kenisarin, Murat & Mahkamov, Khamid, 2007. "Solar energy storage using phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1913-1965, December.
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    Cited by:

    1. Mawire, Ashmore & Lefenya, Tlotlo M. & Ekwomadu, Chidiebere S. & Lentswe, Katlego A. & Shobo, Adedamola B., 2020. "Performance comparison of medium temperature domestic packed bed latent heat storage systems," Renewable Energy, Elsevier, vol. 146(C), pages 1897-1906.
    2. Liu, Yushi & Yang, Yingzi, 2018. "Form-stable phase change material based on Na2CO3·10H2O-Na2HPO4·12H2O eutectic hydrated salt/expanded graphite oxide composite: The influence of chemical structures of expanded graphite oxide," Renewable Energy, Elsevier, vol. 115(C), pages 734-740.

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