IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v133y2019icp411-421.html
   My bibliography  Save this article

BaZrO3 and Cs-BaZrO3 catalysed transesterification of Millettia Pinnata oil and optimisation of reaction variables by response surface Box-Behnken design

Author

Listed:
  • Kumar, Dipesh
  • Singh, Bhaskar

Abstract

Perovskite BaZrO3 was synthesised via a relatively mild solid-state reaction route by using nitrate precursors. Thermal behaviour, the presence of crystalline phases and functional groups, specific surface area, microstructural characteristics, elemental composition, and basic strength of the synthesised material was examined. Further, the partial ionic exchange of Ba ions in BaZrO3 was attempted to synthesise Cs modified BaZrO3. Characterisation results revealed the synthesis of phase pure and strongly basic materials. BaZrO3 was tested as a transesterification catalyst for the synthesis of biodiesel. Transesterification reaction variables for BaZrO3 catalysed transesterification were optimised using response surface methodology based Box-Behnken designing approach. Under the suggested optimal conditions the predicted conversion was 94.12%, and the experimentally determined conversion of 93.2 ± 0.3% confirmed the validity of the generated quadratic model. Cs modification of BaZrO3 enhanced its basic strength. Under the optimised conditions for pristine BaZrO3, the effect of Cs modification on BaZrO3 was assessed, and it led to a conversion of 97.27 ± 0.4%. Both the materials were effective in catalysing the transesterification of M. pinnata oil, however; only Cs-BaZrO3 catalysed oil met the EN 14214:2003 specification for minimum ester content in biodiesel.

Suggested Citation

  • Kumar, Dipesh & Singh, Bhaskar, 2019. "BaZrO3 and Cs-BaZrO3 catalysed transesterification of Millettia Pinnata oil and optimisation of reaction variables by response surface Box-Behnken design," Renewable Energy, Elsevier, vol. 133(C), pages 411-421.
    • Handle: RePEc:eee:renene:v:133:y:2019:i:c:p:411-421
    DOI: 10.1016/j.renene.2018.10.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148118312217
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2018.10.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Jain, Siddharth & Sharma, M.P., 2010. "Prospects of biodiesel from Jatropha in India: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 763-771, February.
    2. Kumar Biswas, Pradip & Pohit, Sanjib & Kumar, Rajesh, 2010. "Biodiesel from jatropha: Can India meet the 20% blending target?," Energy Policy, Elsevier, vol. 38(3), pages 1477-1484, March.
    3. Torres-Rodríguez, Daniela A. & Romero-Ibarra, Issis C. & Ibarra, Ilich A. & Pfeiffer, Heriberto, 2016. "Biodiesel production from soybean and Jatropha oils using cesium impregnated sodium zirconate as a heterogeneous base catalyst," Renewable Energy, Elsevier, vol. 93(C), pages 323-331.
    4. Guo, Mingxin & Song, Weiping & Buhain, Jeremy, 2015. "Bioenergy and biofuels: History, status, and perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 712-725.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Safaripour, Maryam & Saidi, Majid & Nodeh, Hamid Rashidi, 2023. "Synthesis and application of barium tin oxide-reduced graphene oxide nanocomposite as a highly stable heterogeneous catalyst for the biodiesel production," Renewable Energy, Elsevier, vol. 217(C).
    2. Maleki, Basir & Ashraf Talesh, S. Siamak, 2022. "Optimization of ZnO incorporation to αFe2O3 nanoparticles as an efficient catalyst for biodiesel production in a sonoreactor: Application on the CI engine," Renewable Energy, Elsevier, vol. 182(C), pages 43-59.
    3. Zhang, Yujiao & Niu, Shengli & Xia, Sunwen & Liu, Sitong & Liu, Jisen, 2023. "One-step conversion of acidified oil to biodiesel by novel bifunctional SrZr1-xFexO3 catalyst," Renewable Energy, Elsevier, vol. 217(C).
    4. Maleki, Basir & Ashraf Talesh, S. Siamak, 2024. "Sustainable biodiesel production from wild oak (Quercus brantii Lindl) oil as a novel and potential feedstock via highly efficient Co@CuO nanocatalyst: RSM optimization and CI engine assessment," Renewable Energy, Elsevier, vol. 224(C).
    5. Li, Ying & Niu, Shengli & Wang, Jun & Zhou, Wenbo & Wang, Yongzheng & Han, Kuihua & Lu, Chunmei, 2022. "Mesoporous SrTiO3 perovskite as a heterogeneous catalyst for biodiesel production: Experimental and DFT studies," Renewable Energy, Elsevier, vol. 184(C), pages 164-175.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Pandey, Vimal Chandra & Singh, Kripal & Singh, Jay Shankar & Kumar, Akhilesh & Singh, Bajrang & Singh, Rana P., 2012. "Jatropha curcas: A potential biofuel plant for sustainable environmental development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2870-2883.
    2. Ceasar, S.A. & Ignacimuthu, S., 2011. "Applications of biotechnology and biochemical engineering for the improvement of Jatropha and Biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 5176-5185.
    3. Findlater, K.M. & Kandlikar, M., 2011. "Land use and second-generation biofuel feedstocks: The unconsidered impacts of Jatropha biodiesel in Rajasthan, India," Energy Policy, Elsevier, vol. 39(6), pages 3404-3413, June.
    4. Kumar, Sunil & Chaube, Alok & Jain, Shashi Kumar, 2012. "Sustainability issues for promotion of Jatropha biodiesel in Indian scenario: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(2), pages 1089-1098.
    5. Silitonga, A.S. & Masjuki, H.H. & Mahlia, T.M.I. & Ong, H.C. & Atabani, A.E. & Chong, W.T., 2013. "A global comparative review of biodiesel production from jatropha curcas using different homogeneous acid and alkaline catalysts: Study of physical and chemical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 514-533.
    6. Edrisi, Sheikh Adil & Dubey, Rama Kant & Tripathi, Vishal & Bakshi, Mansi & Srivastava, Pankaj & Jamil, Sarah & Singh, H.B. & Singh, Nandita & Abhilash, P.C., 2015. "Jatropha curcas L.: A crucified plant waiting for resurgence," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 855-862.
    7. Motasemi, F. & Ani, F.N., 2012. "A review on microwave-assisted production of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4719-4733.
    8. Atabani, A.E. & Silitonga, A.S. & Badruddin, Irfan Anjum & Mahlia, T.M.I. & Masjuki, H.H. & Mekhilef, S., 2012. "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2070-2093.
    9. M'Arimi, M.M. & Mecha, C.A. & Kiprop, A.K. & Ramkat, R., 2020. "Recent trends in applications of advanced oxidation processes (AOPs) in bioenergy production: Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    10. Renzi, Massimiliano & Bietresato, Marco & Mazzetto, Fabrizio, 2016. "An experimental evaluation of the performance of a SI internal combustion engine for agricultural purposes fuelled with different bioethanol blends," Energy, Elsevier, vol. 115(P1), pages 1069-1080.
    11. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    12. Eksi, Guner & Karaosmanoglu, Filiz, 2017. "Combined bioheat and biopower: A technology review and an assessment for Turkey," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1313-1332.
    13. Luis Santos Pereira, 2017. "Water, Agriculture and Food: Challenges and Issues," Water Resources Management: An International Journal, Published for the European Water Resources Association (EWRA), Springer;European Water Resources Association (EWRA), vol. 31(10), pages 2985-2999, August.
    14. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
    15. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    16. Leonel J. R. Nunes & Abel M. Rodrigues & João C. O. Matias & Ana I. Ferraz & Ana C. Rodrigues, 2021. "Production of Biochar from Vine Pruning: Waste Recovery in the Wine Industry," Agriculture, MDPI, vol. 11(6), pages 1-15, May.
    17. Ekaterina S. Titova, 2019. "Biofuel Application as a Factor of Sustainable Development Ensuring: The Case of Russia," Energies, MDPI, vol. 12(20), pages 1-30, October.
    18. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
    19. Vaz, Fernanda Leitão & da Rocha Lins, Jennyfer & Alves Alencar, Bárbara Ribeiro & Silva de Abreu, Íthalo Barbosa & Vidal, Esteban Espinosa & Ribeiro, Ester & Valadares de Sá Barretto Sampaio, Everardo, 2021. "Chemical pretreatment of sugarcane bagasse with liquid fraction recycling," Renewable Energy, Elsevier, vol. 174(C), pages 666-673.
    20. Zhu, Yixin & Xu, Jianchu & Li, Qiaohong & Mortimer, Peter E., 2014. "Investigation of rubber seed yield in Xishuangbanna and estimation of rubber seed oil based biodiesel potential in Southeast Asia," Energy, Elsevier, vol. 69(C), pages 837-842.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:133:y:2019:i:c:p:411-421. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.