IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v57y2013icp234-239.html
   My bibliography  Save this article

Effects of operating parameters on hydrogen crossover rate through Nafion® membranes in polymer electrolyte membrane fuel cells

Author

Listed:
  • Baik, Kyung Don
  • Hong, Bo Ki
  • Kim, Min Soo

Abstract

This study examines the effects of operating parameters—comprising temperature, relative humidity, hydrogen pressure, and membrane thickness—on hydrogen crossover rate in a polymer electrolyte membrane fuel cell (PEMFC). It is found that the hydrogen crossover rate increases proportional to both temperature and relative humidity for all membrane samples. Increased hydrogen crossover rate is also observed with increasing hydrogen pressure. The hydrogen crossover rate increases gradually with the decrease of membrane thickness from 258 to 135 μm. When the membrane thickness decreases from 63 to 21 μm, there is a dramatic increase of hydrogen crossover. Multiple linear regression analysis was used to analyze the effects of all the operating parameters on hydrogen crossover rate. The results indicate that increased hydrogen crossover rate is mainly determined by the inverse of the logarithmic membrane thickness, followed by hydrogen pressure, relative humidity, and temperature, respectively.

Suggested Citation

  • Baik, Kyung Don & Hong, Bo Ki & Kim, Min Soo, 2013. "Effects of operating parameters on hydrogen crossover rate through Nafion® membranes in polymer electrolyte membrane fuel cells," Renewable Energy, Elsevier, vol. 57(C), pages 234-239.
    • Handle: RePEc:eee:renene:v:57:y:2013:i:c:p:234-239
    DOI: 10.1016/j.renene.2013.01.046
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148113000840
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2013.01.046?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Nam, Jinmoo & Chippar, Purushothama & Kim, Whangi & Ju, Hyunchul, 2010. "Numerical analysis of gas crossover effects in polymer electrolyte fuel cells (PEFCs)," Applied Energy, Elsevier, vol. 87(12), pages 3699-3709, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jia, Fei & Tian, Xiaodi & Liu, Fengfeng & Ye, Junjie & Yang, Chengpeng, 2023. "Oxidant starvation under various operating conditions on local and transient performance of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 331(C).
    2. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    3. Li, Sida & Wei, Xuezhe & Jiang, Shangfeng & Yuan, Hao & Ming, Pingwen & Wang, Xueyuan & Dai, Haifeng, 2022. "Hydrogen crossover diagnosis for fuel cell stack: An electrochemical impedance spectroscopy based method," Applied Energy, Elsevier, vol. 325(C).
    4. Sayadi, Parvin & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of hydrogen crossover and proton conductivity of self-humidifying nanocomposite proton exchange membrane based on sulfonated poly (ether ether ketone)," Energy, Elsevier, vol. 94(C), pages 292-303.
    5. Colmenar-Santos, Antonio & Alberdi-Jiménez, Lucía & Nasarre-Cortés, Lorenzo & Mora-Larramona, Joaquín, 2014. "Residual heat use generated by a 12 kW fuel cell in an electric vehicle heating system," Energy, Elsevier, vol. 68(C), pages 182-190.
    6. Pineda-Delgado, J.L. & Chávez-Ramirez, A.U. & Gutierrez B, Cynthia K. & Rivas, S. & Marisela, Cruz-Ramírez & de Jesús Hernández-Cortes, Ramiro & Menchaca-Rivera, J.A. & Pérez-Robles, J.F., 2022. "Effect of relative humidity and temperature on the performance of an electrochemical hydrogen compressor," Applied Energy, Elsevier, vol. 311(C).
    7. Pengcheng Liu & Sichuan Xu, 2022. "Experimental Research on the Dynamic Characteristics and Voltage Uniformity of a PEMFC Stack under Subzero Temperatures," Energies, MDPI, vol. 15(9), pages 1-14, April.
    8. Kannan, Vishvak & Xue, Hansong & Raman, K. Ashoke & Chen, Jiasheng & Fisher, Adrian & Birgersson, Erik, 2020. "Quantifying operating uncertainties of a PEMFC – Monte Carlo-machine learning based approach," Renewable Energy, Elsevier, vol. 158(C), pages 343-359.
    9. Kong, Im Mo & Jung, Aeri & Kim, Beom Jun & Baik, Kyung Don & Kim, Min Soo, 2015. "Experimental study on the start-up with dry gases from normal cell temperatures in self-humidified proton exchange membrane fuel cells," Energy, Elsevier, vol. 93(P1), pages 57-66.
    10. Liu, Hao & Chen, Jian & Hissel, Daniel & Lu, Jianguo & Hou, Ming & Shao, Zhigang, 2020. "Prognostics methods and degradation indexes of proton exchange membrane fuel cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 123(C).
    11. Ren, Peng & Pei, Pucheng & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Zhang, Lu & Li, Zizhao & Wang, Mingkai & Wang, He & Wang, Bozheng & Wang, Xizhong, 2022. "Novel analytic method of membrane electrode assembly parameters for fuel cell consistency evaluation by micro-current excitation," Applied Energy, Elsevier, vol. 306(PB).
    12. Chang, Huawei & Cai, Fengyang & Yu, Xianxian & Duan, Chen & Chan, Siew Hwa & Tu, Zhengkai, 2023. "Experimental study on the thermal management of an open-cathode air-cooled proton exchange membrane fuel cell stack with ultra-thin metal bipolar plates," Energy, Elsevier, vol. 263(PA).
    13. Jouin, Marine & Gouriveau, Rafael & Hissel, Daniel & Péra, Marie-Cécile & Zerhouni, Noureddine, 2016. "Degradations analysis and aging modeling for health assessment and prognostics of PEMFC," Reliability Engineering and System Safety, Elsevier, vol. 148(C), pages 78-95.
    14. Özçelep, Yasin & Sevgen, Selcuk & Samli, Ruya, 2020. "A study on the hydrogen consumption calculation of proton exchange membrane fuel cells for linearly increasing loads: Artificial Neural Networks vs Multiple Linear Regression," Renewable Energy, Elsevier, vol. 156(C), pages 570-578.
    15. Baik, Kyung Don & Hong, Bo Ki & Han, Kookil & Kim, Min Soo, 2014. "Effects of anisotropic bending stiffness of gas diffusion layers on the performance of polymer electrolyte membrane fuel cells with bipolar plates employing different channel depths," Renewable Energy, Elsevier, vol. 69(C), pages 356-364.
    16. Pei, Pucheng & Wu, Ziyao & Li, Yuehua & Jia, Xiaoning & Chen, Dongfang & Huang, Shangwei, 2018. "Improved methods to measure hydrogen crossover current in proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 215(C), pages 338-347.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Bae, Suk Joo & Kim, Seong-Joon & Lee, Jin-Hwa & Song, Inseob & Kim, Nam-In & Seo, Yongho & Kim, Ki Buem & Lee, Naesung & Park, Jun-Young, 2014. "Degradation pattern prediction of a polymer electrolyte membrane fuel cell stack with series reliability structure via durability data of single cells," Applied Energy, Elsevier, vol. 131(C), pages 48-55.
    2. Pei, Pucheng & Wu, Ziyao & Li, Yuehua & Jia, Xiaoning & Chen, Dongfang & Huang, Shangwei, 2018. "Improved methods to measure hydrogen crossover current in proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 215(C), pages 338-347.
    3. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    4. Wu, Horng-Wen & Ku, Hui-Wen, 2011. "The optimal parameters estimation for rectangular cylinders installed transversely in the flow channel of PEMFC from a three-dimensional PEMFC model and the Taguchi method," Applied Energy, Elsevier, vol. 88(12), pages 4879-4890.
    5. Wang, H.Y. & Yang, W.J. & Kim, Y.B., 2014. "Analyzing in-plane temperature distribution via a micro-temperature sensor in a unit polymer electrolyte membrane fuel cell," Applied Energy, Elsevier, vol. 124(C), pages 148-155.
    6. Xuan, Jin & Leung, D.Y.C. & Wang, Huizhi & Leung, Michael K.H. & Wang, Bin & Ni, Meng, 2013. "Air-breathing membraneless laminar flow-based fuel cells: Do they breathe enough oxygen?," Applied Energy, Elsevier, vol. 104(C), pages 400-407.
    7. Ismail, M.S. & Hughes, K.J. & Ingham, D.B. & Ma, L. & Pourkashanian, M., 2012. "Effects of anisotropic permeability and electrical conductivity of gas diffusion layers on the performance of proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 95(C), pages 50-63.
    8. Baik, Kyung Don & Kong, Im Mo & Hong, Bo Ki & Kim, Sae Hoon & Kim, Min Soo, 2013. "Local measurements of hydrogen crossover rate in polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 101(C), pages 560-566.
    9. Ko, Johan & Ju, Hyunchul, 2012. "Comparison of numerical simulation results and experimental data during cold-start of polymer electrolyte fuel cells," Applied Energy, Elsevier, vol. 94(C), pages 364-374.
    10. Yang, Weiguang & Guo, Hui & Niu, Fuquan & Wang, Bingjie & Huang, Bin & Niu, Sirui & Liu, Jianli & Yang, Shuting & Yang, Yange, 2023. "A novel strategy for accelerating degradation of proton exchange membranes in fuel cell," Renewable Energy, Elsevier, vol. 213(C), pages 38-46.
    11. Lin, Chien-Hung, 2013. "Surface roughness effect on the metallic bipolar plates of a proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 104(C), pages 898-904.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:57:y:2013:i:c:p:234-239. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.