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Local measurements of hydrogen crossover rate in polymer electrolyte membrane fuel cells

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  • Baik, Kyung Don
  • Kong, Im Mo
  • Hong, Bo Ki
  • Kim, Sae Hoon
  • Kim, Min Soo

Abstract

Hydrogen crossover is the main reason for membrane degradation in polymer electrolyte membrane fuel cells (PEMFCs). In this study, local measurements of the hydrogen crossover rate at the cathode in a PEMFC are investigated to analyze the distribution of hydrogen crossover rates under various temperature and relative humidity (RH) conditions. The bipolar plate for the cathode side is specially designed for local measurements. Results show that hydrogen crossover appears to occur mostly near the gas inlet region, and reduced crossover amounts near the outlet region. The hydrogen crossover rates increase with decreasing the nitrogen flow rates at a given section. The effects of temperature and RH on the hydrogen crossover rate over the entire area of the fuel cell are also analyzed and compared with the results of the open circuit voltage (OCV). The results show that the hydrogen crossover rate increases with the increase in both cell temperature and RH, resulting in a decrease in the OCV.

Suggested Citation

  • Baik, Kyung Don & Kong, Im Mo & Hong, Bo Ki & Kim, Sae Hoon & Kim, Min Soo, 2013. "Local measurements of hydrogen crossover rate in polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 101(C), pages 560-566.
    • Handle: RePEc:eee:appene:v:101:y:2013:i:c:p:560-566
    DOI: 10.1016/j.apenergy.2012.06.034
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    References listed on IDEAS

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    1. Alaefour, Ibrahim & Karimi, G. & Jiao, Kui & Li, X., 2012. "Measurement of current distribution in a proton exchange membrane fuel cell with various flow arrangements – A parametric study," Applied Energy, Elsevier, vol. 93(C), pages 80-89.
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    3. Nam, Jinmoo & Chippar, Purushothama & Kim, Whangi & Ju, Hyunchul, 2010. "Numerical analysis of gas crossover effects in polymer electrolyte fuel cells (PEFCs)," Applied Energy, Elsevier, vol. 87(12), pages 3699-3709, December.
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    Cited by:

    1. Kong, Im Mo & Jung, Aeri & Kim, Beom Jun & Baik, Kyung Don & Kim, Min Soo, 2015. "Experimental study on the start-up with dry gases from normal cell temperatures in self-humidified proton exchange membrane fuel cells," Energy, Elsevier, vol. 93(P1), pages 57-66.
    2. Ren, Peng & Pei, Pucheng & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Zhang, Lu & Li, Zizhao & Wang, Mingkai & Wang, He & Wang, Bozheng & Wang, Xizhong, 2022. "Novel analytic method of membrane electrode assembly parameters for fuel cell consistency evaluation by micro-current excitation," Applied Energy, Elsevier, vol. 306(PB).
    3. Wan, Zhongmin & Liu, Jing & Luo, Zhiping & Tu, Zhengkai & Liu, Zhichun & Liu, Wei, 2013. "Evaluation of self-water-removal in a dead-ended proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 104(C), pages 751-757.
    4. Baik, Kyung Don & Hong, Bo Ki & Han, Kookil & Kim, Min Soo, 2014. "Effects of anisotropic bending stiffness of gas diffusion layers on the performance of polymer electrolyte membrane fuel cells with bipolar plates employing different channel depths," Renewable Energy, Elsevier, vol. 69(C), pages 356-364.
    5. Pei, Pucheng & Wu, Ziyao & Li, Yuehua & Jia, Xiaoning & Chen, Dongfang & Huang, Shangwei, 2018. "Improved methods to measure hydrogen crossover current in proton exchange membrane fuel cell," Applied Energy, Elsevier, vol. 215(C), pages 338-347.
    6. Bae, Suk Joo & Kim, Seong-Joon & Lee, Jin-Hwa & Song, Inseob & Kim, Nam-In & Seo, Yongho & Kim, Ki Buem & Lee, Naesung & Park, Jun-Young, 2014. "Degradation pattern prediction of a polymer electrolyte membrane fuel cell stack with series reliability structure via durability data of single cells," Applied Energy, Elsevier, vol. 131(C), pages 48-55.
    7. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    8. Wu, Ziyao & Pei, Pucheng & Xu, Huachi & Jia, Xiaoning & Ren, Peng & Wang, Bozheng, 2019. "Study on the effect of membrane electrode assembly parameters on polymer electrolyte membrane fuel cell performance by galvanostatic charging method," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    9. Yang, Zirong & Du, Qing & Jia, Zhiwei & Yang, Chunguang & Jiao, Kui, 2019. "Effects of operating conditions on water and heat management by a transient multi-dimensional PEMFC system model," Energy, Elsevier, vol. 183(C), pages 462-476.

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