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Monolithic HZSM-5/SS-fiber catalysts with high coke-resistance and selectivity for catalytic cracking of castor oil to produce biofuel

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  • Zhang, Qiaofei
  • Han, Qi
  • Bai, Hongjuan
  • Li, Yakun
  • Zhu, Chunshan
  • Xie, Wenlei

Abstract

Monolithic HZSM-5/SS-fiber catalysts with hierarchical porous structure from micro-to macro-size for catalytic cracking of castor oil to produce biofuel were fabricated by seed coating and subsequent hydrothermal synthesis of ZSM-5 zeolite crystals onto the thin-sheet stainless steel fiber (SS-fiber). Compared with the powdered HZSM-5, the HZSM-5/SS-fiber catalyst exhibited high hydrocarbon selectivity (78% in gasoline and 57% in diesel) with enhanced physical properties of liquid products, as well as excellent coke-resistance with coking rate of 0.47 mg gzeolite−1 h−1 (one-eighth of the powdered HZSM-5), indicating a significant intensification on cracking process due to a unique combination of high heat/mass transfer and hierarchical pore structure. SiO2/Al2O3 ratio exerts a pivotal influence on HZSM-5 loading and acid strength/amount of the HZSM-5/SS-fiber, which thereby strongly relates to the degree of cracking, aromatization, and deoxygenation. The HZSM-5/SS-fiber (200) with moderate acid amount and strength permitted mild secondary cracking and sufficient deoxygenation reactions, resulting in a low coke yield, a high liquid product yield and a high hydrocarbon/aromatic selectivity along with reduced acid values (7.4 mg KOH g−1 in gasoline and 83.2 mg KOH g−1 in diesel). The physical properties including kinematic viscosity, density, oxygen content and heating value, were optimal at SiO2/Al2O3 ratio of 200.

Suggested Citation

  • Zhang, Qiaofei & Han, Qi & Bai, Hongjuan & Li, Yakun & Zhu, Chunshan & Xie, Wenlei, 2024. "Monolithic HZSM-5/SS-fiber catalysts with high coke-resistance and selectivity for catalytic cracking of castor oil to produce biofuel," Renewable Energy, Elsevier, vol. 229(C).
  • Handle: RePEc:eee:renene:v:229:y:2024:i:c:s0960148124008231
    DOI: 10.1016/j.renene.2024.120755
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    References listed on IDEAS

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