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Production of renewable aromatics from jatropha oil over multifunctional ZnCo/ZSM-5 catalysts

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  • Singh, Omvir
  • Agrawal, Ankit
  • Dhiman, Neha
  • Vempatapu, Bhanu Prasad
  • Chiang, Ken
  • Tripathi, Shailendra
  • Sarkar, Bipul

Abstract

The transformation of jatropha oil into aromatics using bimetallic ZSM-5 catalyst was investigated in a continuous downflow reactor. The effect of change in surface acidity was observed closely concerning the formation of C6–C8 aromatics; a balance Lewis and Brønsted acidic sites showed a strong correlation with light aromatics. Ce as a promoter modify the surface acidity, which enhanced the dehydro-deoxygenation reaction and improved the aromatic selectivity. Hence, Ce-promoted ZnCo/Z catalysts showed better performance compared to La-promoted ZnCo/Z. The 10Zn5Co5Ce/Z catalyst showed 87.6% oil conversion, with 81.9% total aromatics. The selectivity toward C6–C8 aromatics found to be 71.8%, with the presence of 35.3% xylenes and ethylbenzene. The Normalized XANES spectra suggest that the Co resides in the tetrahedrally coordinated environment in the ZnCo2O4 catalyst and such intensity of the pre-edge feature evidence for incorporating Co into the material framework. The optimised catalyst, i.e.,10Zn5Co5Ce/Z shows negligible coke deposition, and it was calculated to be 1.33 × 10−3 (gcoke/gcat h); further, the catalyst was regenerated for three consecutive cycles.

Suggested Citation

  • Singh, Omvir & Agrawal, Ankit & Dhiman, Neha & Vempatapu, Bhanu Prasad & Chiang, Ken & Tripathi, Shailendra & Sarkar, Bipul, 2021. "Production of renewable aromatics from jatropha oil over multifunctional ZnCo/ZSM-5 catalysts," Renewable Energy, Elsevier, vol. 179(C), pages 2124-2135.
    • Handle: RePEc:eee:renene:v:179:y:2021:i:c:p:2124-2135
    DOI: 10.1016/j.renene.2021.08.011
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    References listed on IDEAS

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    Cited by:

    1. Goyal, Reena & Abraham, B. Moses & Singh, Omvir & Sameer, Siddharth & Bal, Rajaram & Mondal, Prasenjit, 2022. "One-pot transformation of glucose into hydroxymethyl furfural in water over Pd decorated acidic ZrO2," Renewable Energy, Elsevier, vol. 183(C), pages 791-801.
    2. Tang, Hongbiao & Lin, Jiayu & Cao, Yang & Jibran, Khalil & Li, Jin, 2022. "Influence of NiMoP phase on hydrodeoxygenation pathways of jatropha oil," Energy, Elsevier, vol. 243(C).

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