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Second generation biofuels production from waste cooking oil via pyrolysis process

Author

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  • Ben Hassen Trabelsi, Aïda
  • Zaafouri, Kaouther
  • Baghdadi, Withek
  • Naoui, Slim
  • Ouerghi, Aymen

Abstract

The thermal cracking of waste cooking oil (WCO) via pyrolysis was performed using a laboratory scale fixed-bed reactor. The effects of the final pyrolysis temperature (from 550 °C to 800 °C) and the heating rate (5 °C/min, 15 °C/min, 20 °C/min, 25 °C/min) on pyrolysis products distribution has been investigated and a maximum bio-oil yield of 80 wt% has been obtained at 800 °C and 15 °C/min. The bio-oil fuel properties shows that this pyrolytic oil has high caloric value (HHV around 8843 kg/Kcal) promoting its use as a liquid fuel but some other properties (high acidity index around 126.8 mg KOH/g sample and high viscosity about 8.95 cSt) need to be upgraded. The GC/MS characterization of the bio-oil highlights its high molecular complexity allowing it to be used as source of chemical products and of active molecules. The syngas heating value (reaching 8 MJ/kg) is suitable for its application as source of energy for the pyrolysis reactor. The remaining biochar is suitable for application as fertilizer since it is rich of iron and organic carbon. The stochiometric model of WCO pyrolysis has been established basing on the pyrolysis products yields, the CHNS-O composition of raw material and remaining biochar, and the syngas chemical composition.

Suggested Citation

  • Ben Hassen Trabelsi, Aïda & Zaafouri, Kaouther & Baghdadi, Withek & Naoui, Slim & Ouerghi, Aymen, 2018. "Second generation biofuels production from waste cooking oil via pyrolysis process," Renewable Energy, Elsevier, vol. 126(C), pages 888-896.
    • Handle: RePEc:eee:renene:v:126:y:2018:i:c:p:888-896
    DOI: 10.1016/j.renene.2018.04.002
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    References listed on IDEAS

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    1. Sharma, Abhishek & Pareek, Vishnu & Zhang, Dongke, 2015. "Biomass pyrolysis—A review of modelling, process parameters and catalytic studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1081-1096.
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    4. Xu, Junming & Jiang, Jianchun & Zhao, Jiaping, 2016. "Thermochemical conversion of triglycerides for production of drop-in liquid fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 331-340.
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    4. Norouzian Baghani, Abbas & Sadjadi, Sodeh & Yaghmaeian, Kamyar & Hossein Mahvi, Amir & Yunesian, Masud & Nabizadeh, Ramin, 2022. "Solid alcohol biofuel based on waste cooking oil: Preparation, properties, micromorphology, heating value optimization and its application as candle wax," Renewable Energy, Elsevier, vol. 192(C), pages 617-630.
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    6. Beims, R.F. & Simonato, C.L. & Wiggers, V.R., 2019. "Technology readiness level assessment of pyrolysis of trygliceride biomass to fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 521-529.
    7. Zhang, Qiaofei & Han, Qi & Bai, Hongjuan & Li, Yakun & Zhu, Chunshan & Xie, Wenlei, 2024. "Monolithic HZSM-5/SS-fiber catalysts with high coke-resistance and selectivity for catalytic cracking of castor oil to produce biofuel," Renewable Energy, Elsevier, vol. 229(C).
    8. Sheriff, S. Abdul & Kumar, Indrala Kishan & Mandhatha, Petluri Sai & Jambal, Samraj Sunder & Sellappan, Raja & Ashok, B. & Nanthagopal, K., 2020. "Emission reduction in CI engine using biofuel reformulation strategies through nano additives for atmospheric air quality improvement," Renewable Energy, Elsevier, vol. 147(P1), pages 2295-2308.
    9. Sukumar, V. & Manieniyan, V. & Senthilkumar, R. & Sivaprakasam, S., 2020. "Production of bio oil from sweet lime empty fruit bunch by pyrolysis," Renewable Energy, Elsevier, vol. 146(C), pages 309-315.
    10. Karla Peña Contreras & Juan Manuel Sánchez Yáñez & Quetzalli Aguilar-Virgen & Paul Taboada-González & Liliana Marquez-Benavides, 2018. "Potential for Methane Generation by Lignocellulosic Household Waste," Sustainability, MDPI, vol. 10(10), pages 1-15, September.
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