IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v188y2022icp778-787.html
   My bibliography  Save this article

N-doped carbon coated Ti3C2 MXene as a high-efficiency catalyst for improving hydrogen storage kinetics and stability of NaAlH4

Author

Listed:
  • Yuan, Zhenluo
  • Zhang, Dafeng
  • Fan, Guangxin
  • Chen, Yumei
  • Fan, Yanping
  • Liu, Baozhong

Abstract

The synthesis of highly stable catalysts for the de/hydriding kinetics and cycle stability of NaAlH4 is crucial. Herein, N-doped carbon coated two-dimensional layered Ti3C2 (Ti3C2/NC) catalyst was synthesized by a self-polymerization and heat-treatment method. Impressively, the Ti3C2/NC catalyst remarkably improves the dehydrogenation properties of NaAlH4 with dramatically enhanced dehydrogenation kinetics and stability. In detail, after adding 10 wt% Ti3C2/NC, the initial dehydrogenation temperature is lowered to 85 °C, 3.0 wt% hydrogen is liberated within 4 min at 140 °C, the first step of hydrogen desorption is completed in 57 min at 100 °C, and its capacity retention after 15 cycle tests can remain up to 96.3%. It can be found that in-situ formed Ti-species (Ti0 and Ti3+) during ball milling and the interaction between pyridinic-N and Ti0 are responsible for the enhanced hydrogen storage performance of NaAlH4. Moreover, the carbon can efficiently stabilize Ti species and results in high stability. This finding provides a new understanding of Ti-based MXene to catalyze the hydrogen storage for NaAlH4.

Suggested Citation

  • Yuan, Zhenluo & Zhang, Dafeng & Fan, Guangxin & Chen, Yumei & Fan, Yanping & Liu, Baozhong, 2022. "N-doped carbon coated Ti3C2 MXene as a high-efficiency catalyst for improving hydrogen storage kinetics and stability of NaAlH4," Renewable Energy, Elsevier, vol. 188(C), pages 778-787.
    • Handle: RePEc:eee:renene:v:188:y:2022:i:c:p:778-787
    DOI: 10.1016/j.renene.2022.02.068
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122002105
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.02.068?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Olha Mashtalir & Michael Naguib & Vadym N. Mochalin & Yohan Dall’Agnese & Min Heon & Michel W. Barsoum & Yury Gogotsi, 2013. "Intercalation and delamination of layered carbides and carbonitrides," Nature Communications, Nature, vol. 4(1), pages 1-7, June.
    2. Zhang, J. & He, L. & Yao, Y. & Zhou, X.J. & Yu, L.P. & Lu, X.Z. & Zhou, D.W., 2020. "Catalytic effect and mechanism of NiCu solid solutions on hydrogen storage properties of MgH2," Renewable Energy, Elsevier, vol. 154(C), pages 1229-1239.
    3. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    4. Yong, Hui & Guo, Shihai & Yuan, Zeming & Qi, Yan & Zhao, Dongliang & Zhang, Yanghuan, 2020. "Catalytic effect of in situ formed Mg2Ni and REHx (RE: Ce and Y) on thermodynamics and kinetics of Mg-RE-Ni hydrogen storage alloy," Renewable Energy, Elsevier, vol. 157(C), pages 828-839.
    5. Wang, Peng & Wang, Zexuan & Tian, Zhihui & Xia, Chaoqun & Yang, Tai & Liang, Chunyong & Li, Qiang, 2020. "Enhanced hydrogen absorption and desorption properties of MgH2 with NiS2: The catalytic effect of in-situ formed MgS and Mg2NiH4 phases," Renewable Energy, Elsevier, vol. 160(C), pages 409-417.
    6. Runwei Mo & David Rooney & Kening Sun & Hui Ying Yang, 2017. "3D nitrogen-doped graphene foam with encapsulated germanium/nitrogen-doped graphene yolk-shell nanoarchitecture for high-performance flexible Li-ion battery," Nature Communications, Nature, vol. 8(1), pages 1-9, April.
    7. Cermak, Jiri & Kral, Lubomir & Roupcova, Pavla, 2020. "Significantly decreased stability of MgH2 in the Mg-In-C alloy system: Long-period-stacking-ordering as a new way how to improve performance of hydrogen storage alloys?," Renewable Energy, Elsevier, vol. 150(C), pages 204-212.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ding, Xin & Chen, Ruirun & Chen, Xiaoyu & Cao, Wenchao & Su, Yanqing & Ding, Hongsheng & Guo, Jingjie, 2020. "Formation of Mg2Ni/Cu phase and de-/hydrogenation behavior of Mg91Ni9-xCux alloy at moderate temperatures," Renewable Energy, Elsevier, vol. 166(C), pages 81-90.
    2. Wang, Peng & Wang, Zexuan & Tian, Zhihui & Xia, Chaoqun & Yang, Tai & Liang, Chunyong & Li, Qiang, 2020. "Enhanced hydrogen absorption and desorption properties of MgH2 with NiS2: The catalytic effect of in-situ formed MgS and Mg2NiH4 phases," Renewable Energy, Elsevier, vol. 160(C), pages 409-417.
    3. Wang, Zexuan & Tian, Zhihui & Yao, Pufan & Zhao, Huimin & Xia, Chaoqun & Yang, Tai, 2022. "Improved hydrogen storage kinetic properties of magnesium-based materials by adding Ni2P," Renewable Energy, Elsevier, vol. 189(C), pages 559-569.
    4. Komova, O.V. & Simagina, V.I. & Butenko, V.R. & Odegova, G.V. & Bulavchenko, O.A. & Nikolaeva, O.A. & Ozerova, A.M. & Lipatnikova, I.L. & Tayban, E.S. & Mukha, S.A. & Netskina, O.V., 2022. "Dehydrogenation of ammonia borane recrystallized by different techniques," Renewable Energy, Elsevier, vol. 184(C), pages 460-472.
    5. Chung, Kyong-Hwan, 2010. "High-pressure hydrogen storage on microporous zeolites with varying pore properties," Energy, Elsevier, vol. 35(5), pages 2235-2241.
    6. Pandey, Mayank & Deshmukh, Kalim & Raman, Akhila & Asok, Aparna & Appukuttan, Saritha & Suman, G.R., 2024. "Prospects of MXene and graphene for energy storage and conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    7. Sukanta Mondal & Pratim Kumar Chattaraj, 2023. "Aromatic Clusters and Hydrogen Storage," Energies, MDPI, vol. 16(6), pages 1-18, March.
    8. Wang, Qing & Han, Ning & Bokhari, Awais & Li, Xue & Cao, Yue & Asif, Saira & Shen, Zhengfeng & Si, Weimeng & Wang, Fagang & Klemeš, Jiří Jaromír & Zhao, Xiaolin, 2022. "Insights into MXenes-based electrocatalysts for oxygen reduction," Energy, Elsevier, vol. 255(C).
    9. Melaina, Marc W., 2007. "Turn of the century refueling: A review of innovations in early gasoline refueling methods and analogies for hydrogen," Energy Policy, Elsevier, vol. 35(10), pages 4919-4934, October.
    10. Toyoto Sato & Shin-ichi Orimo, 2021. "The Crystal Structures in Hydrogen Absorption Reactions of REMgNi 4 -Based Alloys (RE: Rare-Earth Metals)," Energies, MDPI, vol. 14(23), pages 1-10, December.
    11. Sharma, Monikankana & N, Rakesh & Dasappa, S., 2016. "Solid oxide fuel cell operating with biomass derived producer gas: Status and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 450-463.
    12. Ádám Révész & Marcell Gajdics & Miratul Alifah & Viktória Kovács Kis & Erhard Schafler & Lajos Károly Varga & Stanislava Todorova & Tony Spassov & Marcello Baricco, 2022. "Thermal, Microstructural and Electrochemical Hydriding Performance of a Mg 65 Ni 20 Cu 5 Y 10 Metallic Glass Catalyzed by CNT and Processed by High-Pressure Torsion," Energies, MDPI, vol. 15(15), pages 1-15, August.
    13. Lijuan Yan & Yange Zhang & Jun Liu, 2019. "The Dissociation and Diffusion Features of H2 Molecule on Two Ti Atoms Doped Al(111) Surface," Biomedical Journal of Scientific & Technical Research, Biomedical Research Network+, LLC, vol. 16(3), pages 1-4, March.
    14. Fan Li & Dong Liu & Ke Sun & Songheng Yang & Fangzheng Peng & Kexin Zhang & Guodong Guo & Yuan Si, 2024. "Towards a Future Hydrogen Supply Chain: A Review of Technologies and Challenges," Sustainability, MDPI, vol. 16(5), pages 1-36, February.
    15. Ádám Révész & Roman Paramonov & Tony Spassov & Marcell Gajdics, 2023. "Microstructure and Hydrogen Storage Performance of Ball-Milled MgH 2 Catalyzed by FeTi," Energies, MDPI, vol. 16(3), pages 1-14, January.
    16. Tao Fu & Yun-Ting Tsai & Qiang Zhou, 2022. "Numerical Simulation of Magnesium Dust Dispersion and Explosion in 20 L Apparatus via an Euler–Lagrange Method," Energies, MDPI, vol. 15(2), pages 1-12, January.
    17. Min Xu & Jinjun Qu & Mai Li, 2022. "National Policies, Recent Research Hotspots, and Application of Sustainable Energy: Case of China, USA, and European Countries," Sustainability, MDPI, vol. 14(16), pages 1-30, August.
    18. Valero-Pedraza, María José & Martín-Cortés, Alexandra & Navarrete, Alexander & Bermejo, María Dolores & Martín, Ángel, 2015. "Kinetics of hydrogen release from dissolutions of ammonia borane in different ionic liquids," Energy, Elsevier, vol. 91(C), pages 742-750.
    19. Kai Ma & Erfei Lv & Di Zheng & Weichun Cui & Shuai Dong & Weijie Yang & Zhengyang Gao & Yu Zhou, 2021. "A First-Principles Study on Titanium-Decorated Adsorbent for Hydrogen Storage," Energies, MDPI, vol. 14(20), pages 1-8, October.
    20. Oner, Oytun & Khalilpour, Kaveh, 2022. "Evaluation of green hydrogen carriers: A multi-criteria decision analysis tool," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:188:y:2022:i:c:p:778-787. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.