IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v4y2013i1d10.1038_ncomms2664.html
   My bibliography  Save this article

Intercalation and delamination of layered carbides and carbonitrides

Author

Listed:
  • Olha Mashtalir

    (Drexel University
    A.J. Drexel Nanotechnology Institute, Drexel University)

  • Michael Naguib

    (Drexel University
    A.J. Drexel Nanotechnology Institute, Drexel University)

  • Vadym N. Mochalin

    (Drexel University
    A.J. Drexel Nanotechnology Institute, Drexel University)

  • Yohan Dall’Agnese

    (Drexel University
    A.J. Drexel Nanotechnology Institute, Drexel University)

  • Min Heon

    (Drexel University
    A.J. Drexel Nanotechnology Institute, Drexel University)

  • Michel W. Barsoum

    (Drexel University)

  • Yury Gogotsi

    (Drexel University
    A.J. Drexel Nanotechnology Institute, Drexel University)

Abstract

Intercalation and delamination of two-dimensional solids in many cases is a requisite step for exploiting their unique properties. Herein we report on the intercalation of two-dimensional Ti3C2, Ti3CN and TiNbC—so called MXenes. Intercalation of hydrazine, and its co-intercalation with N,N-dimethylformamide, resulted in increases of the c-lattice parameters of surface functionalized f-Ti3C2, from 19.5 to 25.48 and 26.8 Å, respectively. Urea is also intercalated into f-Ti3C2. Molecular dynamics simulations suggest that a hydrazine monolayer intercalates between f-Ti3C2 layers. Hydrazine is also intercalated into f-Ti3CN and f-TiNbC. When dimethyl sulphoxide is intercalated into f-Ti3C2, followed by sonication in water, the f-Ti3C2 is delaminated forming a stable colloidal solution that is in turn filtered to produce MXene ‘paper’. The latter shows excellent Li-ion capacity at extremely high charging rates.

Suggested Citation

  • Olha Mashtalir & Michael Naguib & Vadym N. Mochalin & Yohan Dall’Agnese & Min Heon & Michel W. Barsoum & Yury Gogotsi, 2013. "Intercalation and delamination of layered carbides and carbonitrides," Nature Communications, Nature, vol. 4(1), pages 1-7, June.
  • Handle: RePEc:nat:natcom:v:4:y:2013:i:1:d:10.1038_ncomms2664
    DOI: 10.1038/ncomms2664
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/ncomms2664
    File Function: Abstract
    Download Restriction: no

    File URL: https://libkey.io/10.1038/ncomms2664?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pandey, Mayank & Deshmukh, Kalim & Raman, Akhila & Asok, Aparna & Appukuttan, Saritha & Suman, G.R., 2024. "Prospects of MXene and graphene for energy storage and conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    2. Wang, Qing & Han, Ning & Bokhari, Awais & Li, Xue & Cao, Yue & Asif, Saira & Shen, Zhengfeng & Si, Weimeng & Wang, Fagang & Klemeš, Jiří Jaromír & Zhao, Xiaolin, 2022. "Insights into MXenes-based electrocatalysts for oxygen reduction," Energy, Elsevier, vol. 255(C).
    3. Yuan, Zhenluo & Zhang, Dafeng & Fan, Guangxin & Chen, Yumei & Fan, Yanping & Liu, Baozhong, 2022. "N-doped carbon coated Ti3C2 MXene as a high-efficiency catalyst for improving hydrogen storage kinetics and stability of NaAlH4," Renewable Energy, Elsevier, vol. 188(C), pages 778-787.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:4:y:2013:i:1:d:10.1038_ncomms2664. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.