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Comprehensive performance of composite phase change materials based on eutectic chloride with SiO2 nanoparticles and expanded graphite for thermal energy storage system

Author

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  • Yu, Qiang
  • Zhang, Cancan
  • Lu, Yuanwei
  • Kong, Qinglong
  • Wei, Haijiao
  • Yang, Yanchun
  • Gao, Qi
  • Wu, Yuting
  • Sciacovelli, Adriano

Abstract

This paper focuses on the formulation, fabrication and characterization of a novel composite for high-temperature heat energy storage. The proposed composite is a shape-stable phase change material consisting of the eutectic chloride (MgCl2–NaCl–KCl) as phase change material, expanded graphite (EG) for heat conduction enhancement and shape stability, and SiO2 nanoparticles for the further improvement of specific heat and thermal conductivity. The composite was prepared following a three-step procedure: mechanical dispersion, tableting and sintering. Concerning the material characterization, a suite of techniques were used, including simultaneous thermal analysis (STA) and laser flash analysis (LFA). The consequences demonstrate that using EG and SiO2 nanoparticles ensure the stability and preventing the leakage of the eutectic chloride. A thorough comparison with the pure ternary chloride shows that the composite specific heat increased up to 1.36 times in solid-state and 1.63 times in liquid-state, and the thermal conductivity increased by 23.2 and 9.2 times in the solid and liquid state, respectively. Upon inspection with scanning electron microscopy, a high-density nanostructure was observed and distributed evenly in the pores of EG, which appear to be the reason for the enhancement of specific heat and thermal conductivity of the material. Finally, the nano-SiO2/MgCl2–NaCl–KCl/EG composite has the advantages of wide working temperature range, shape stability, high specific heat and thermal conductivity, which has a promising application in a high-temperature thermal storage system.

Suggested Citation

  • Yu, Qiang & Zhang, Cancan & Lu, Yuanwei & Kong, Qinglong & Wei, Haijiao & Yang, Yanchun & Gao, Qi & Wu, Yuting & Sciacovelli, Adriano, 2021. "Comprehensive performance of composite phase change materials based on eutectic chloride with SiO2 nanoparticles and expanded graphite for thermal energy storage system," Renewable Energy, Elsevier, vol. 172(C), pages 1120-1132.
    • Handle: RePEc:eee:renene:v:172:y:2021:i:c:p:1120-1132
    DOI: 10.1016/j.renene.2021.03.061
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    as
    1. Yuan, Mengdi & Ren, Yunxiu & Xu, Chao & Ye, Feng & Du, Xiaoze, 2019. "Characterization and stability study of a form-stable erythritol/expanded graphite composite phase change material for thermal energy storage," Renewable Energy, Elsevier, vol. 136(C), pages 211-222.
    2. Assi, Ala Fathi & Zhakanova Isiksal, Aliya & Tursoy, Turgut, 2021. "Renewable energy consumption, financial development, environmental pollution, and innovations in the ASEAN + 3 group: Evidence from (P-ARDL) model," Renewable Energy, Elsevier, vol. 165(P1), pages 689-700.
    3. Muñoz-Sánchez, Belén & Nieto-Maestre, Javier & Iparraguirre-Torres, Iñigo & García-Romero, Ana & Sala-Lizarraga, Jose M., 2018. "Molten salt-based nanofluids as efficient heat transfer and storage materials at high temperatures. An overview of the literature," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3924-3945.
    4. Palacios, Anabel & Cong, Lin & Navarro, M.E. & Ding, Yulong & Barreneche, Camila, 2019. "Thermal conductivity measurement techniques for characterizing thermal energy storage materials – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 32-52.
    5. Kenisarin, Murat M., 2010. "High-temperature phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 955-970, April.
    6. Ong, Teng-Cheong & Sarvghad, Madjid & Lippiatt, Kaleb & Griggs, Lewis & Ryan, Hollie & Will, Geoffrey & Steinberg, Theodore A., 2020. "Review of the solubility, monitoring, and purification of impurities in molten salts for energy storage in concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    7. Tian, Heqing & Du, Lichan & Wei, Xiaolan & Deng, Suyan & Wang, Weilong & Ding, Jing, 2017. "Enhanced thermal conductivity of ternary carbonate salt phase change material with Mg particles for solar thermal energy storage," Applied Energy, Elsevier, vol. 204(C), pages 525-530.
    8. Myers, Philip D. & Alam, Tanvir E. & Kamal, Rajeev & Goswami, D.Y. & Stefanakos, E., 2016. "Nitrate salts doped with CuO nanoparticles for thermal energy storage with improved heat transfer," Applied Energy, Elsevier, vol. 165(C), pages 225-233.
    9. Qin, Frank G.F. & Yang, Xiaoping & Ding, Zhan & Zuo, Yuanzhi & Shao, Youyan & Jiang, Runhua & Yang, Xiaoxi, 2012. "Thermocline stability criterions in single-tanks of molten salt thermal energy storage," Applied Energy, Elsevier, vol. 97(C), pages 816-821.
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    Cited by:

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    4. Hou, Yicheng & Qiu, Jun & Wang, Wei & He, Xibo & Ayyub, Mubashar & Shuai, Yong, 2022. "Preparation and performance improvement of chlorides/MgO ceramics shape-stabilized phase change materials with expanded graphite for thermal energy storage system," Applied Energy, Elsevier, vol. 316(C).
    5. Fan, Man & Suo, Hanxiao & Yang, Hua & Zhang, Xuemei & Li, Xiaofei & Guo, Leihong & Kong, Xiangfei, 2022. "Experimental study on thermophysical parameters of a solar assisted cascaded latent heat thermal energy storage (CLHTES) system," Energy, Elsevier, vol. 256(C).
    6. Liu, Dinghai & Xie, Kai & Zhang, Hui & Qiang, Yujie & Yang, Di & Wang, Zhaoxiao & Zhu, Lidong & Akkurt, Nevzat & Du, Yanping & Shen, Meng & Zhong, Liqiong & Yu, Fan & Xu, Qian, 2022. "Numerical evaluation of convective heat transfer properties of two-dimensional rotating PCM melt in the unilaterally heated rectangular container," Renewable Energy, Elsevier, vol. 193(C), pages 920-940.
    7. Kassianne Tofani & Saeed Tiari, 2021. "Nano-Enhanced Phase Change Materials in Latent Heat Thermal Energy Storage Systems: A Review," Energies, MDPI, vol. 14(13), pages 1-34, June.
    8. Li, Yuanji & Niu, Zhaoyang & Gao, Xinyu & Ji, Ruiyang & Yang, Xiaohu & Yan, Jinyue, 2023. "Experimental and numerical investigations on tilt filling design of metal foam in a heat storage tank," Renewable Energy, Elsevier, vol. 217(C).

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