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Unsaturated polyester resin supported form-stable phase change materials with enhanced thermal conductivity for solar energy storage and conversion

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  • Bing, Naici
  • Yang, Jie
  • Gao, Huan
  • Xie, Huaqing
  • Yu, Wei

Abstract

Solar energy absorption, conversion, transportation and storage are crucial for high-efficiency solar thermal utilization. It is positive and promising to develop novel phase change materials (PCMs) with good shape stability, excellent photo-absorption and thermal-physical properties in the practical solar thermal application. Polymer supported PCMs with good heat transfer performance show an extensive application prospect. This research introduces a straightforward and practical strategy to prepare flexible poly (ethylene glycol) (PEG) form-stable phase change materials (FSPCMs) by taking cross-linked unsaturated polyester resin as skeleton and expanded graphite (EG) as thermal conductivity additive. The results show the FSCMs have excellent stability, thermal reliability and can be kept from leaking at 80 °C. The efficiency of photo-thermal conversion of FSPCMs doped with 7 wt % EG is up to 93.3%. The thermal conductivity is 1150% higher than PEG. Comparing to PEG, FSPCMs doped with 7 wt % EG can save time of 67.1% and 51.4% during the heating and cooling processes, respectively. The unsaturated polyester resin as common industry materials will provide more possibility for FSPCMs with enhanced thermal conductivity in practical solar thermal application.

Suggested Citation

  • Bing, Naici & Yang, Jie & Gao, Huan & Xie, Huaqing & Yu, Wei, 2021. "Unsaturated polyester resin supported form-stable phase change materials with enhanced thermal conductivity for solar energy storage and conversion," Renewable Energy, Elsevier, vol. 173(C), pages 926-933.
    • Handle: RePEc:eee:renene:v:173:y:2021:i:c:p:926-933
    DOI: 10.1016/j.renene.2021.04.033
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    Cited by:

    1. Jiang, Feng & Ge, Zhiwei & Ling, Xiang & Cang, Daqiang & Zhang, Lingling & Ding, Yulong, 2021. "Improved thermophysical properties of shape-stabilized NaNO3 using a modified diatomite-based porous ceramic for solar thermal energy storage," Renewable Energy, Elsevier, vol. 179(C), pages 327-338.
    2. Gao, Huan & Bing, Naici & Xie, Huaqing & Yu, Wei, 2022. "Energy harvesting and storage blocks based on 3D oriented expanded graphite and stearic acid with high thermal conductivity for solar thermal application," Energy, Elsevier, vol. 254(PA).

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