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Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol

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  • Kuljiraseth, Jirayu
  • Kumpradit, Thanakorn
  • Leungcharoenwattana, Tuangrat
  • Poo-arporn, Yingyot
  • Jitkarnka, Sirirat

Abstract

In order to secure the feed, a bio-based chemical production plant shall be designed to process more than one bio-based feedstock. However, the process usually requires costly H2 supply. Without H2 feeding, the effects of Cu on Cu0.3Mg1.7Al-LDO catalysts were investigated on the hydrogenolysis of glycerol with and without bio-ethanol co-feeding. As a result, the reduced catalyst dramatically increased the glycerol conversion and gave an apparently-high selectivity of chemicals such as 1,2-propandiol, ethyl lactate, and lactic acid. Apparently, besides as a hydrogen donor, ethanol also acted as a reactant that produced ethyl lactate via the esterification with lactic acid. In summary, Cu2+ and Cu+ sites promoted glycerol dehydration, the oxidation to lactic acid, and the esterification with ethanol to ethyl lactate whereas Cu0 was believed to promote the in-situ hydrogen formation from glycerol reforming. The integrated reaction pathways were also proposed and discussed.

Suggested Citation

  • Kuljiraseth, Jirayu & Kumpradit, Thanakorn & Leungcharoenwattana, Tuangrat & Poo-arporn, Yingyot & Jitkarnka, Sirirat, 2020. "Integrated glycerol- and ethanol-based chemical synthesis routes using Cu–Mg–Al LDH-derived catalysts without external hydrogen: Intervention of bio-ethanol co-fed with glycerol," Renewable Energy, Elsevier, vol. 156(C), pages 975-985.
    • Handle: RePEc:eee:renene:v:156:y:2020:i:c:p:975-985
    DOI: 10.1016/j.renene.2020.04.151
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    References listed on IDEAS

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    1. Doyle, Aidan M. & Albayati, Talib M. & Abbas, Ammar S. & Alismaeel, Ziad T., 2016. "Biodiesel production by esterification of oleic acid over zeolite Y prepared from kaolin," Renewable Energy, Elsevier, vol. 97(C), pages 19-23.
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    1. Vannucci, Julián A. & Gatti, Martín N. & Cardaci, Nicolas & Nichio, Nora N., 2022. "Economic feasibility of a solketal production process from glycerol at small industrial scale," Renewable Energy, Elsevier, vol. 190(C), pages 540-547.
    2. Singh, Vijendra & Arumugam, Selvamani & Tathod, Anup Prakash & Kuldeep, & Vempatapu, Bhanu Prasad & Viswanadham, Nagabhatla, 2023. "Sustainable production of aromatics-rich gasoline stock from bio-glycerol over hierarchically porous Zn-decorated HZSM-5 catalyst," Renewable Energy, Elsevier, vol. 217(C).

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