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Mass transfer and kinetic study on BEA zeolite-catalysed oil hydroesterification

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  • Mowla, Omid
  • Kennedy, Eric
  • Stockenhuber, Michael

Abstract

In the present study, we have assessed the effect of mass transfer on the both steps of the zeolite catalysed oil hydroesterification to produce biodiesel (hydrolysis of the feed soybean oil producing free fatty acid and free fatty acid esterification). Both reactions were conducted over BEA zeolite in a batch reactor. Experimental results indicate the absence of internal and external mass transfer limitations on the overall rate of either reaction. A reversible, second order reaction was invoked in order to estimate the reaction rate constant, pre-exponential factor and activation energy of the esterification and hydrolysis reactions. Activation energy of 25.9 kJ/mol (soybean oil hydrolysis), 38.5 kJ/mol (ethyl acetate hydrolysis), 24.8 kJ/mol (oleic acid esterification) and 46.7 kJ/mol (acetic acid esterification) were calculated over H-BEA zeolite, illustrating the importance of reactant size and the fact that reactions take place on the pour mouth of the mesopouros zeolite in a case of large molecules reaction. Experimental results suggested that the relative hydrophobicity of the catalyst is a key parameter, which influences whether the reaction is under kinetic or diffusion control.

Suggested Citation

  • Mowla, Omid & Kennedy, Eric & Stockenhuber, Michael, 2019. "Mass transfer and kinetic study on BEA zeolite-catalysed oil hydroesterification," Renewable Energy, Elsevier, vol. 135(C), pages 417-425.
  • Handle: RePEc:eee:renene:v:135:y:2019:i:c:p:417-425
    DOI: 10.1016/j.renene.2018.12.012
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    1. Joelianingsih, & Maeda, Hitoshi & Hagiwara, Shoji & Nabetani, Hiroshi & Sagara, Yasuyuki & Soerawidjaya, Tatang H. & Tambunan, Armansyah H. & Abdullah, Kamaruddin, 2008. "Biodiesel fuels from palm oil via the non-catalytic transesterification in a bubble column reactor at atmospheric pressure: A kinetic study," Renewable Energy, Elsevier, vol. 33(7), pages 1629-1636.
    2. Kuss, Vivian Vicentini & Kuss, Anelise Vicentini & Rosa, Rosana Gomes da & Aranda, Donato A.G. & Cruz, Yordanka Reyes, 2015. "Potential of biodiesel production from palm oil at Brazilian Amazon," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1013-1020.
    3. Doyle, Aidan M. & Albayati, Talib M. & Abbas, Ammar S. & Alismaeel, Ziad T., 2016. "Biodiesel production by esterification of oleic acid over zeolite Y prepared from kaolin," Renewable Energy, Elsevier, vol. 97(C), pages 19-23.
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    2. Gomes, Glaucio J. & Costa, Michelle Budke & Bittencourt, Paulo R.S. & Zalazar, María Fernanda & Arroyo, Pedro A., 2021. "Catalytic improvement of biomass conversion: Effect of adding mesoporosity on MOR zeolite for esterification with oleic acid," Renewable Energy, Elsevier, vol. 178(C), pages 1-12.

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