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Fabrication and characterization of phase change material composite fibers with wide phase-transition temperature range by co-electrospinning method

Author

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  • Golestaneh, S.I.
  • Mosallanejad, A.
  • Karimi, G.
  • Khorram, M.
  • Khashi, M.

Abstract

An innovative electrospun form-stable phase change composite material is fabricated by combining binary fatty acid eutectics of capric-lauric acid (CA-LA) and capric-palmitic acid (CA-PA) as the phase change materials (PCMs) and polyethylene terephthalate (PET) as the supporting matrix. The encapsulated PCM composite fibers are produced by co-electrospinning of different fibers at various PCM-to-PET ratios of 50/100, 70/100, 100/100 and 120/100. Thermal behavior and characteristics of individual fatty acids, fatty acid eutectics and composite fibers as well as the structural morphology of the composite fibers are characterized by differential scanning calorimetry (DSC), thermogravimetric analyses (TGA), scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FT-IR). Scanning electron microscopy images revealed that the average diameter of the composite fibers is slightly increased by increasing the PCM contents. Comparison of FT-IR plots for fatty acids and PET with those of composite fibers containing PCMs clearly indicates that no chemical reaction occurred between PCM and PET matrices. In addition, thermogravimetric analysis results have shown that composite fibers have two steps of degradation which correspond to decomposition of PCM molecular chains and PET structure, respectively. Moreover, DSC results have indicated that enthalpy of composite fibers is improved by increasing PCM contents while no considerable change is observed in phase-transition temperature. Compared to previous studies, the present fabricated co-electrospun composite fibers offer wider phase-transition temperature range (−9 to 34°C) and higher enthalpy values even with lower amounts of PCM. Therefore, these composite fibers are very promising for use in near ambient storage and retrieval energy systems.

Suggested Citation

  • Golestaneh, S.I. & Mosallanejad, A. & Karimi, G. & Khorram, M. & Khashi, M., 2016. "Fabrication and characterization of phase change material composite fibers with wide phase-transition temperature range by co-electrospinning method," Applied Energy, Elsevier, vol. 182(C), pages 409-417.
    • Handle: RePEc:eee:appene:v:182:y:2016:i:c:p:409-417
    DOI: 10.1016/j.apenergy.2016.08.136
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    References listed on IDEAS

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    2. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    3. Wu, Yang & Chen, Changzhong & Jia, Yifan & Wu, Jie & Huang, Yong & Wang, Linge, 2018. "Review on electrospun ultrafine phase change fibers (PCFs) for thermal energy storage," Applied Energy, Elsevier, vol. 210(C), pages 167-181.
    4. Rezaie, Ali Bashiri & Montazer, Majid, 2018. "One-step fabrication of fatty acids/nano copper/polyester shape-stable composite phase change material for thermal energy management and storage," Applied Energy, Elsevier, vol. 228(C), pages 1911-1920.
    5. Darzi, Mohammad Ebrahimnejad & Golestaneh, Seyyed Iman & Kamali, Marziyeh & Karimi, Gholamreza, 2019. "Thermal and electrical performance analysis of co-electrospun-electrosprayed PCM nanofiber composites in the presence of graphene and carbon fiber powder," Renewable Energy, Elsevier, vol. 135(C), pages 719-728.
    6. Liu, Changhui & Xiao, Tong & Zhao, Jiateng & Liu, Qingyi & Sun, Wenjie & Guo, Chenglong & Ali, Hafiz Muhammad & Chen, Xiao & Rao, Zhonghao & Gu, Yanlong, 2023. "Polymer engineering in phase change thermal storage materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).
    7. Bashiri Rezaie, Ali & Montazer, Majid, 2020. "Shape-stable thermo-responsive nano Fe3O4/fatty acids/PET composite phase-change material for thermal energy management and saving applications," Applied Energy, Elsevier, vol. 262(C).
    8. Golestaneh, Seyyed Iman & Karimi, Gholamreza & Babapoor, Aziz & Torabi, Farshid, 2018. "Thermal performance of co-electrospun fatty acid nanofiber composites in the presence of nanoparticles," Applied Energy, Elsevier, vol. 212(C), pages 552-564.

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