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Conversion of lignin into renewable carboxylic acid compounds by advanced oxidation processes

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  • Kang, Juhyon
  • Irmak, Sibel
  • Wilkins, Mark

Abstract

The present study was designed to investigate formation of possible carboxylic acids from oxidation of lignin by Fenton and UV-Fenton advanced oxidation processes (AOPs). The study was performed with model lignin monomers (syringaldehyde (SA), 4-hydroxybenzaldehyde (4-HBA), 2-methoxyphenol (2-MP) and 2,6-dimethoxyphenol (2,6-DMP)) and also with lignin isolated from eastern red cedar. Products in samples withdrawn from the reactor mixture at different oxidation stages were determined by GC-MS. Oxidation of one of lignin monomer (2-MP) was also performed with a different AOPs (UV/TiO2) for comparison of oxidation products.

Suggested Citation

  • Kang, Juhyon & Irmak, Sibel & Wilkins, Mark, 2019. "Conversion of lignin into renewable carboxylic acid compounds by advanced oxidation processes," Renewable Energy, Elsevier, vol. 135(C), pages 951-962.
    • Handle: RePEc:eee:renene:v:135:y:2019:i:c:p:951-962
    DOI: 10.1016/j.renene.2018.12.076
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    References listed on IDEAS

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    1. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
    2. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
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