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Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals

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  • Yan, Kai
  • Wu, Guosheng
  • Lafleur, Todd
  • Jarvis, Cody

Abstract

As our high dependence on the supply of diminishing fossil fuel reserves raise great concerns in its environmental, political and economic consequences, utilization of renewable biomass as an alternative resource has become increasingly important. Along this background, furfural as a building block, offers a promising, rich platform for lignocellulosic biofuels and value-added chemicals. These include 2-methylfuran and 2-methyltetrahydrofuran, furfuryl alcohol, tetrahydrofurfuryl alcohol, furan, tetrahydrofuran as well as various cyclo-products (e.g., cyclopentanol, cyclopentanone). The various production routes started from furfural to various fuel additives and chemicals are critically reviewed, and the current technologies for efficient production are identified. Their potential applications as well as the fuel properties of these products are discussed. Challenges and areas that need improvement are also highlighted in the corresponding area. In short, we conduct a comprehensive review of the strategies to produce furfural, new approaches and numerous possibilities to utilize furfural in industrial and laboratory sector for the production of fuel additives and value-added chemicals.

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  • Yan, Kai & Wu, Guosheng & Lafleur, Todd & Jarvis, Cody, 2014. "Production, properties and catalytic hydrogenation of furfural to fuel additives and value-added chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 663-676.
    • Handle: RePEc:eee:rensus:v:38:y:2014:i:c:p:663-676
    DOI: 10.1016/j.rser.2014.07.003
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    1. Mazen A. Eldeeb & Benjamin Akih-Kumgeh, 2018. "Recent Trends in the Production, Combustion and Modeling of Furan-Based Fuels," Energies, MDPI, vol. 11(3), pages 1-47, February.
    2. Magdalena Modelska & Michal J. Binczarski & Piotr Dziugan & Szymon Nowak & Zdzisława Romanowska-Duda & Adam Sadowski & Izabela A. Witońska, 2020. "Potential of Waste Biomass from the Sugar Industry as a Source of Furfural and Its Derivatives for Use as Fuel Additives in Poland," Energies, MDPI, vol. 13(24), pages 1-15, December.
    3. Zhao, Yuan & Lu, Kaifeng & Xu, Hao & Zhu, Lingjun & Wang, Shurong, 2021. "A critical review of recent advances in the production of furfural and 5-hydroxymethylfurfural from lignocellulosic biomass through homogeneous catalytic hydrothermal conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    4. Omid Doustdar & Soheil Zeraati-Rezaei & Jose Martin Herreros & Athanasios Tsolakis & Karl D. Dearn & Miroslaw Lech Wyszynski, 2021. "Tribological Performance of Biomass-Derived Bio-Alcohol and Bio-Ketone Fuels," Energies, MDPI, vol. 14(17), pages 1-11, August.
    5. Wiranarongkorn, Kunlanan & Im-orb, Karittha & Panpranot, Joongjai & Maréchal, François & Arpornwichanop, Amornchai, 2021. "Exergy and exergoeconomic analyses of sustainable furfural production via reactive distillation," Energy, Elsevier, vol. 226(C).
    6. Chen, Hao & Su, Xin & He, Jingjing & Zhang, Peng & Xu, Hongming & Zhou, Chenglong, 2021. "Investigation on combustion characteristics of cyclopentanol/diesel fuel blends in an optical engine," Renewable Energy, Elsevier, vol. 167(C), pages 811-829.
    7. Cornejo, A. & Barrio, I. & Campoy, M. & Lázaro, J. & Navarrete, B., 2017. "Oxygenated fuel additives from glycerol valorization. Main production pathways and effects on fuel properties and engine performance: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1400-1413.
    8. Rajneesh, & Singh, Shailendra P. & Pathak, Jainendra & Sinha, Rajeshwer P., 2017. "Cyanobacterial factories for the production of green energy and value-added products: An integrated approach for economic viability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 69(C), pages 578-595.
    9. Martin J. Taylor & Hassan A. Alabdrabalameer & Vasiliki Skoulou, 2019. "Choosing Physical, Physicochemical and Chemical Methods of Pre-Treating Lignocellulosic Wastes to Repurpose into Solid Fuels," Sustainability, MDPI, vol. 11(13), pages 1-27, June.
    10. Morone, Amruta & Apte, Mayura & Pandey, R.A., 2015. "Levulinic acid production from renewable waste resources: Bottlenecks, potential remedies, advancements and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 548-565.
    11. Wiranarongkorn, K. & Im-orb, K. & Patcharavorachot, Y. & Maréchal, F. & Arpornwichanop, A., 2023. "Comparative techno-economic and energy analyses of integrated biorefinery processes of furfural and 5-hydroxymethylfurfural from biomass residue," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    12. Mofijur, M. & Rasul, M.G. & Hyde, J. & Azad, A.K. & Mamat, R. & Bhuiya, M.M.K., 2016. "Role of biofuel and their binary (diesel–biodiesel) and ternary (ethanol–biodiesel–diesel) blends on internal combustion engines emission reduction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 265-278.
    13. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part I," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1427-1445.
    14. Hu, Di & Zhang, Man & Xu, Hong & Wang, Yuchen & Yan, Kai, 2021. "Recent advance on the catalytic system for efficient production of biomass-derived 5-hydroxymethylfurfural," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    15. Yan, Kai & Jarvis, Cody & Gu, Jing & Yan, Yong, 2015. "Production and catalytic transformation of levulinic acid: A platform for speciality chemicals and fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 986-997.
    16. Tuan Hoang, Anh & Viet Pham, Van, 2021. "2-Methylfuran (MF) as a potential biofuel: A thorough review on the production pathway from biomass, combustion progress, and application in engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    17. Zhou, Ziyuan & Liu, Dehua & Zhao, Xuebing, 2021. "Conversion of lignocellulose to biofuels and chemicals via sugar platform: An updated review on chemistry and mechanisms of acid hydrolysis of lignocellulose," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    18. Zoran V. Simić & Mirjana Lj. Kijevčanin & Ivona R. Radović & Miha Grilc & Gorica R. Ivaniš, 2021. "Thermodynamic and Transport Properties of Biomass-Derived Furfural, Furfuryl Alcohol and Their Mixtures," Energies, MDPI, vol. 14(22), pages 1-18, November.
    19. He, Yifeng & Zhao, Yingnan & Chai, Meiyun & Zhou, Zhongyue & Sarker, Manobendro & Li, Chong & Liu, Ronghou & Cai, Junmeng & Liu, Xinghua, 2020. "Comparative study of fast pyrolysis, hydropyrolysis and catalytic hydropyrolysis of poplar sawdust and rice husk in a modified Py-GC/MS microreactor system: Insights into product distribution, quantum," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).

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