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Fast pyrolysis of fermentation residue derived from Saccharina japonica for a hybrid biological and thermal process

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  • Choi, Jae Hyung
  • Kim, Seung-Soo
  • Kim, Jinsoo
  • Woo, Hee Chul

Abstract

Pyrolysis characteristics of Saccharina japonica fermentation residue (SJFR) were systematically investigated using a thermogravimetric analyzer and a bubbling fluidized-bed reactor. Thermogravimetric (TG) characteristics of the SJFRs with increasing fermentation time (1–6 day) showed a decrease of second peak related to fermentable carbohydrates (e.g., alginate and fucoidan) and an increase of third peak related to non-fermentable carbon sources. The calculated apparent activation energy of the SJFRs ranged from 20.21 to 295.46 kJ/mol, depending on the conversion rate of 5–80%. Between 10 and 40% conversion at 225–310 °C, the apparent activation energies of the SJFRs on each conversion decreased with increasing the fermentation time (1–6 day). The bubbling fluidized-bed pyrolysis of the SJFR-4D and -6D showed the high bio-oil yield of 39.86 and 40.12 wt%, respectively at 375 °C and 4.0 × Umf, and the HHVs of the organic bio-oils were 28.95–29.34 MJ/kg. The characteristics of the bio-oil derived from SJFRs were analyzed by GC-MS and the TG-based simulated distillation. The fractions of gas oil and heavy gas oil were increased, whereas the one of gasoline decreased with increasing fermentation time. It is attributed to a decrease of the fermented carbohydrates (e.g., alginate and fucoidan) related to the gasoline fraction.

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  • Choi, Jae Hyung & Kim, Seung-Soo & Kim, Jinsoo & Woo, Hee Chul, 2019. "Fast pyrolysis of fermentation residue derived from Saccharina japonica for a hybrid biological and thermal process," Energy, Elsevier, vol. 170(C), pages 239-249.
  • Handle: RePEc:eee:energy:v:170:y:2019:i:c:p:239-249
    DOI: 10.1016/j.energy.2018.12.136
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    References listed on IDEAS

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    1. Monlau, F. & Sambusiti, C. & Antoniou, N. & Barakat, A. & Zabaniotou, A., 2015. "A new concept for enhancing energy recovery from agricultural residues by coupling anaerobic digestion and pyrolysis process," Applied Energy, Elsevier, vol. 148(C), pages 32-38.
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    Cited by:

    1. Sebastián Serna-Loaiza & Angela Miltner & Martin Miltner & Anton Friedl, 2019. "A Review on the Feedstocks for the Sustainable Production of Bioactive Compounds in Biorefineries," Sustainability, MDPI, vol. 11(23), pages 1-24, November.
    2. Chen, Chao & Liang, Rui & Ge, Yadong & Li, Jian & Yan, Beibei & Cheng, Zhanjun & Tao, Junyu & Wang, Zhenyu & Li, Meng & Chen, Guanyi, 2022. "Fast characterization of biomass pyrolysis oil via combination of ATR-FTIR and machine learning models," Renewable Energy, Elsevier, vol. 194(C), pages 220-231.

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