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Bifunctional N-doped graphene Ti and Co nanocomposites for the oxygen reduction and evolution reactions

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  • Luque-Centeno, J.M.
  • Martínez-Huerta, M.V.
  • Sebastián, D.
  • Lemes, G.
  • Pastor, E.
  • Lázaro, M.J.

Abstract

Developing efficient, durable, and low cost catalysts based on earth-abundant elements for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is essential for renewable energy conversion and energy storage devices. We report herein a simple one-pot procedure for the synthesis of non-precious metals N-doped graphene composites employing urea as nitrogen source, and their application as bifunctional catalysts for both the ORR and OER in alkaline environment. In this study, the effects of the addition of Ti and Co on the structure and performance of the N-doped graphene composites are investigated. The incorporation of Ti leads to a composite with both anatase and rutile TiO2 crystalline phases as well as Ti3+ species stabilized upon hybridization with N-doped reduced graphene oxide. The ORR onset potential for the Ti-based composite is 0.85 V (vs. RHE) and the number of electrons transferred is 3.5, showing superior stability than Pt/C after accelerated potential cycling in alkaline solution. However, this composite shows low activity and stability for the OER. On the other hand, the composite consisting of metallic Co and Co3O4 nanocrystals grown on N-doped reduced graphene oxide exhibits the best performance as bifunctional catalyst, with ORR and OER onset potentials of 0.95 V and 1.51 V (vs. RHE), respectively, and a number of electrons transferred of 3.6 (ORR). The results reveal the presence of important structural features such as metallic Co as the predominant crystalline component, amorphous Co3O4 phase and the coordination of Co-N-doped graphene. All of them seem to be fundamental for the high activity and stability towards ORR and OER.

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  • Luque-Centeno, J.M. & Martínez-Huerta, M.V. & Sebastián, D. & Lemes, G. & Pastor, E. & Lázaro, M.J., 2018. "Bifunctional N-doped graphene Ti and Co nanocomposites for the oxygen reduction and evolution reactions," Renewable Energy, Elsevier, vol. 125(C), pages 182-192.
    • Handle: RePEc:eee:renene:v:125:y:2018:i:c:p:182-192
    DOI: 10.1016/j.renene.2018.02.073
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    1. Ruiz-Cornejo, J.C. & Vivo-Vilches, J.F. & Sebastián, D. & Martínez-Huerta, M.V. & Lázaro, M.J., 2021. "Carbon nanofiber-supported tantalum oxides as durable catalyst for the oxygen evolution reaction in alkaline media," Renewable Energy, Elsevier, vol. 178(C), pages 307-317.
    2. David Sebastián & María Jesús Nieto-Monge & Sara Pérez-Rodríguez & Elena Pastor & María Jesús Lázaro, 2018. "Nitrogen Doped Ordered Mesoporous Carbon as Support of PtRu Nanoparticles for Methanol Electro-Oxidation," Energies, MDPI, vol. 11(4), pages 1-16, April.
    3. Tamilselvi, R. & Lekshmi, G.S. & Padmanathan, N. & Selvaraj, V. & Bazaka, O. & Levchenko, I. & Bazaka, K. & Mandhakini, M., 2022. "NiFe2O4 / rGO nanocomposites produced by soft bubble assembly for energy storage and environmental remediation," Renewable Energy, Elsevier, vol. 181(C), pages 1386-1401.
    4. Qian, Guangfu & Mo, Yanshan & Yu, Chen & Zhang, Hao & Yu, Tianqi & Luo, Lin & Yin, Shibin, 2020. "Free-standing bimetallic CoNiTe2 nanosheets as efficient catalysts with high stability at large current density for oxygen evolution reaction," Renewable Energy, Elsevier, vol. 162(C), pages 2190-2196.
    5. Xu, Fei & Yu, Chen & Qian, Guangfu & Luo, Lin & Hasan, Syed Waqar & Yin, Shibin & Tsiakaras, Panagiotis, 2020. "Electrocatalytic production of hydrogen over highly efficient ultrathin carbon encapsulated S, P co-existence copper nanorods composite," Renewable Energy, Elsevier, vol. 151(C), pages 1278-1285.

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