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The valorization of glycerol: Economic assessment of an innovative process for the bioconversion of crude glycerol into ethanol and hydrogen

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  • Varrone, C.
  • Liberatore, R.
  • Crescenzi, T.
  • Izzo, G.
  • Wang, A.

Abstract

The worldwide energy demand has been continuously increasing, thus requesting more sustainable alternatives to the rapidly depleting fossil fuels. Therefore, biofuels such as hydrogen, bioethanol and biodiesel are gaining more importance as a renewable and pollution-free solution, which might give a significant contribution to the future energy mix. In recent years, the exponential growth of biodiesel production has led to a glycerol glut, however, according to some authors, crude glycerol might represent a suitable, abundant and low-priced feedstock for fermentation technologies. In this study we performed an energetic and economic assessment of an innovative process, which is under development in our lab, for the bioconversion of crude glycerol into ethanol and hydrogen. Ongoing experiments showed the possibility to reach at least 26g/L of ethanol, together with 9L of hydrogen, in non-sterile conditions and without nutrient supplements. Since kinetics and ethanol concentration need to be further improved, we performed this study with a view to evaluate the possibility of reaching economic viability. Results showed that with 26g/L of ethanol and a retention time as high as 120h, the calculated energy cost would be about 0.019€/kWhth and 0.057€/kWhel, considering the contribution of both, hydrogen and bioethanol. Moreover, bioethanol cost would be as low as 0.21€/L, even without taking into account the possible hydrogen revenues. These results are very promising and suggest that the process has reasonable chances to achieve economic viability, thus deserving further attention. The procedure followed in this work provided a realistic and concrete target to pursue in the future lab experiments, in order to bring this technology closer to the market.

Suggested Citation

  • Varrone, C. & Liberatore, R. & Crescenzi, T. & Izzo, G. & Wang, A., 2013. "The valorization of glycerol: Economic assessment of an innovative process for the bioconversion of crude glycerol into ethanol and hydrogen," Applied Energy, Elsevier, vol. 105(C), pages 349-357.
    • Handle: RePEc:eee:appene:v:105:y:2013:i:c:p:349-357
    DOI: 10.1016/j.apenergy.2013.01.015
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    References listed on IDEAS

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    1. Yu, Suiran & Tao, Jing, 2009. "Economic, energy and environmental evaluations of biomass-based fuel ethanol projects based on life cycle assessment and simulation," Applied Energy, Elsevier, vol. 86(Supplemen), pages 178-188, November.
    2. Srirangan, Kajan & Akawi, Lamees & Moo-Young, Murray & Chou, C. Perry, 2012. "Towards sustainable production of clean energy carriers from biomass resources," Applied Energy, Elsevier, vol. 100(C), pages 172-186.
    3. Sigurbjornsdottir, Margret Audur & Orlygsson, Johann, 2012. "Combined hydrogen and ethanol production from sugars and lignocellulosic biomass by Thermoanaerobacterium AK54, isolated from hot spring," Applied Energy, Elsevier, vol. 97(C), pages 785-791.
    4. Zheng, Yi & Yu, Chaowei & Cheng, Yu-Shen & Lee, Christopher & Simmons, Christopher W. & Dooley, Todd M. & Zhang, Ruihong & Jenkins, Bryan M. & VanderGheynst, Jean S., 2012. "Integrating sugar beet pulp storage, hydrolysis and fermentation for fuel ethanol production," Applied Energy, Elsevier, vol. 93(C), pages 168-175.
    5. Santori, Giulio & Di Nicola, Giovanni & Moglie, Matteo & Polonara, Fabio, 2012. "A review analyzing the industrial biodiesel production practice starting from vegetable oil refining," Applied Energy, Elsevier, vol. 92(C), pages 109-132.
    6. Hammond, G.P. & Kallu, S. & McManus, M.C., 2008. "Development of biofuels for the UK automotive market," Applied Energy, Elsevier, vol. 85(6), pages 506-515, June.
    7. Zhou, Wei & Yang, Hongxing & Rissanen, Markku & Nygren, Bertil & Yan, Jinyue, 2012. "Decrease of energy demand for bioethanol-based polygeneration system through case study," Applied Energy, Elsevier, vol. 95(C), pages 305-311.
    8. Börjesson, Pål, 2009. "Good or bad bioethanol from a greenhouse gas perspective - What determines this?," Applied Energy, Elsevier, vol. 86(5), pages 589-594, May.
    9. He, Jie & Zhang, Wennan, 2011. "Techno-economic evaluation of thermo-chemical biomass-to-ethanol," Applied Energy, Elsevier, vol. 88(4), pages 1224-1232, April.
    10. Qiu, Huanguang & Huang, Jikun & Yang, Jun & Rozelle, Scott & Zhang, Yuhua & Zhang, Yahui & Zhang, Yanli, 2010. "Bioethanol development in China and the potential impacts on its agricultural economy," Applied Energy, Elsevier, vol. 87(1), pages 76-83, January.
    11. Balat, Mustafa & Balat, Havva, 2009. "Recent trends in global production and utilization of bio-ethanol fuel," Applied Energy, Elsevier, vol. 86(11), pages 2273-2282, November.
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    1. Demichelis, Francesca & Fiore, Silvia & Pleissner, Daniel & Venus, Joachim, 2018. "Technical and economic assessment of food waste valorization through a biorefinery chain," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 38-48.
    2. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    3. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Rajaei, Kourosh & Tarighi, Sara, 2018. "Oxidation of bio-renewable glycerol to value-added chemicals through catalytic and electro-chemical processes," Applied Energy, Elsevier, vol. 230(C), pages 1347-1379.
    4. Remón, J. & Arcelus-Arrillaga, P. & García, L. & Arauzo, J., 2018. "Simultaneous production of gaseous and liquid biofuels from the synergetic co-valorisation of bio-oil and crude glycerol in supercritical water," Applied Energy, Elsevier, vol. 228(C), pages 2275-2287.
    5. Joanna Kazimierowicz & Marcin Dębowski & Marcin Zieliński & Aneta Ignaciuk & Sandra Mlonek & Jordi Cruz Sanchez, 2024. "The Biosynthesis of Liquid Fuels and Other Value-Added Products Based on Waste Glycerol—A Comprehensive Review and Bibliometric Analysis," Energies, MDPI, vol. 17(12), pages 1-31, June.

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