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Tungsten supported Ti/SiO2 nanoflowers as reusable heterogeneous catalyst for biodiesel production

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  • Kaur, Mandeep
  • Malhotra, Rashi
  • Ali, Amjad

Abstract

Present work demonstrates an easy route by sol-gel method, without using any template, for the synthesis of flower shaped tungsten (W) supported TiO2/SiO2catalyst for the triglyceride transesterification. The structure of the catalyst was established by powder X-ray diffraction and surface morphology and particle size by field emission scanning and high resolution transmission electron microscopy studies, respectively. The oxidation state of tungsten by X-ray photoelectron spectroscopy was found to be +6. Under the optimized reaction conditions of 5 wt% of 20-W/TiO2/SiO2-700 catalyst, 30:1 methanol to oil molar ratio and 65 °C reaction temperature, more than 98% fatty acid ethyl ester yield was obtained in 4 h. The kinetic and thermodynamic parameter of the reaction was also evaluated following the pseudo-first order equation. The catalyst was recycled in four consecutive runs and total metal contents in biodiesel was observed <5 ppm to maintain the stability of the catalyst.

Suggested Citation

  • Kaur, Mandeep & Malhotra, Rashi & Ali, Amjad, 2018. "Tungsten supported Ti/SiO2 nanoflowers as reusable heterogeneous catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 116(PA), pages 109-119.
    • Handle: RePEc:eee:renene:v:116:y:2018:i:pa:p:109-119
    DOI: 10.1016/j.renene.2017.09.065
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    1. Ma, Yingqun & Wang, Qunhui & Sun, Xiaohong & Wu, Chuanfu & Gao, Zhen, 2017. "Kinetics studies of biodiesel production from waste cooking oil using FeCl3-modified resin as heterogeneous catalyst," Renewable Energy, Elsevier, vol. 107(C), pages 522-530.
    2. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Zarei, Alireza & Noshadi, Iman, 2013. "Transesterification of waste cooking oil by heteropoly acid (HPA) catalyst: Optimization and kinetic model," Applied Energy, Elsevier, vol. 102(C), pages 283-292.
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    5. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
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    7. Nath, Biswajit & Basumatary, Bidangshri & Brahma, Sujata & Das, Bipul & Kalita, Pranjal & Rokhum, Samuel Lalthazuala & Basumatary, Sanjay, 2023. "Musa champa peduncle waste-derived efficient catalyst: Studies of biodiesel synthesis, reaction kinetics and thermodynamics," Energy, Elsevier, vol. 270(C).
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    9. de Brito, Vitor Lima & Gonçalves, Matheus Arrais & dos Santos, Hiarla Cristina Lima & da Rocha Filho, Geraldo Narciso & da Conceição, Leyvison Rafael Vieira, 2023. "Biodiesel production from waste frying oil using molybdenum over niobia as heterogeneous acid catalyst: Process optimization and kinetics study," Renewable Energy, Elsevier, vol. 215(C).
    10. Al-Saadi, Ali & Mathan, Bobby & He, Yinghe, 2020. "Esterification and transesterification over SrO–ZnO/Al2O3 as a novel bifunctional catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 158(C), pages 388-399.
    11. Singh, Himmat & Ali, Amjad, 2023. "Esterification as well as transesterification of waste oil using potassium imbued tungstophosphoric acid supported graphene oxide as heterogeneous catalyst: Optimization and kinetic modeling," Renewable Energy, Elsevier, vol. 207(C), pages 422-435.

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