IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v113y2017icp1399-1407.html
   My bibliography  Save this article

De/hydrogenation kinetics against air exposure and microstructure evolution during hydrogen absorption/desorption of Mg-Ni-Ce alloys

Author

Listed:
  • Xie, Lishuai
  • Li, Jinshan
  • Zhang, Tiebang
  • Kou, Hongchao

Abstract

Aiming at elucidating the positive effects of Ce element on the oxidation resistance of Mg-based hydrogen storage alloys, Mg-Ni-Ce alloys with different Ce contents have been prepared in a resistance furnace with furnace cooling. The mass fraction of Mg in each sample is 80% to maintain high and consistent hydrogen storage capacity. An 18R-type long-period stacking ordered phase (LPSO) is observed within the Mg12Ce matrix in Mg-Ni-Ce alloys. A two-step activation process is observed in Ce containing alloys. Detailed microstructural characterization of activated samples during air exposure and in-depth analysis of absorption/desorption kinetics on air-exposed samples based on Johnson-Mehl-Avrami (JMA) model are performed to discuss the mechanism underlying improved anti-oxidation properties. CeH2.73 forms after activation and transforms to CeO2 during air exposure, which is earlier and faster than the MgO formation during initial air contact preventing forming a compact and uniform MgO layer on the surface. The formed CeH2.73/CeO2 particles with average particle size less than 60 nm act as catalysts accelerating the hydrogen dissociation and nucleation sites for the MgH2 formation during hydrogenation. After de-/hydrogenation cycles, CeO2 turns back to CeH2.73, which can react with oxygen again when the sample is exposed to air.

Suggested Citation

  • Xie, Lishuai & Li, Jinshan & Zhang, Tiebang & Kou, Hongchao, 2017. "De/hydrogenation kinetics against air exposure and microstructure evolution during hydrogen absorption/desorption of Mg-Ni-Ce alloys," Renewable Energy, Elsevier, vol. 113(C), pages 1399-1407.
  • Handle: RePEc:eee:renene:v:113:y:2017:i:c:p:1399-1407
    DOI: 10.1016/j.renene.2017.06.102
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148117306067
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2017.06.102?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Niaz, Saba & Manzoor, Taniya & Pandith, Altaf Hussain, 2015. "Hydrogen storage: Materials, methods and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 457-469.
    2. Bhattacharyya, Rupsha & Mohan, Sadhana, 2015. "Solid state storage of hydrogen and its isotopes: An engineering overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 872-883.
    3. Goumri-Said, Souraya & Ahmed, Rashid & Kanoun, Mohammed Benali, 2016. "Density-functional theory study of high hydrogen content complex hydrides Mg(BH4)2 at low temperature," Renewable Energy, Elsevier, vol. 90(C), pages 114-119.
    4. Wang, Yan & Shen, Yan & Qi, Kezhen & Cao, Zhongqiu & Zhang, Ke & Wu, Shiwei, 2016. "Nanostructured cobalt–phosphorous catalysts for hydrogen generation from hydrolysis of sodium borohydride solution," Renewable Energy, Elsevier, vol. 89(C), pages 285-294.
    5. Baniasadi, Ehsan, 2017. "Concurrent hydrogen and water production from brine water based on solar spectrum splitting: Process design and thermoeconomic analysis," Renewable Energy, Elsevier, vol. 102(PA), pages 50-64.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ding, Xin & Chen, Ruirun & Chen, Xiaoyu & Cao, Wenchao & Su, Yanqing & Ding, Hongsheng & Guo, Jingjie, 2020. "Formation of Mg2Ni/Cu phase and de-/hydrogenation behavior of Mg91Ni9-xCux alloy at moderate temperatures," Renewable Energy, Elsevier, vol. 166(C), pages 81-90.
    2. Yong, Hui & Guo, Shihai & Yuan, Zeming & Qi, Yan & Zhao, Dongliang & Zhang, Yanghuan, 2020. "Catalytic effect of in situ formed Mg2Ni and REHx (RE: Ce and Y) on thermodynamics and kinetics of Mg-RE-Ni hydrogen storage alloy," Renewable Energy, Elsevier, vol. 157(C), pages 828-839.
    3. Cermak, Jiri & Kral, Lubomir & Roupcova, Pavla, 2022. "A new light-element multi-principal-elements alloy AlMg2TiZn and its potential for hydrogen storage," Renewable Energy, Elsevier, vol. 198(C), pages 1186-1192.
    4. Yang, Tai & Wang, Peng & Li, Qiang & Xia, Chaoqun & Yin, Fuxing & Liang, Chunyong & Zhang, Yanghuan, 2018. "Hydrogen absorption and desorption behavior of Ni catalyzed Mg–Y–C–Ni nanocomposites," Energy, Elsevier, vol. 165(PA), pages 709-719.
    5. Zhang, Yanghuan & Li, Xufeng & Cai, Ying & Qi, Yan & Guo, Shihai & Zhao, Dongliang, 2019. "Improved hydrogen storage performances of Mg-Y-Ni-Cu alloys by melt spinning," Renewable Energy, Elsevier, vol. 138(C), pages 263-271.
    6. Zhang, Yanghuan & Zhang, Wei & Bu, Wengang & Cai, Ying & Qi, Yan & Guo, Shihai, 2019. "Improved hydrogen storage dynamics of amorphous and nanocrystalline Ce-Mg-Ni-based CeMg12-type alloys synthesized by ball milling," Renewable Energy, Elsevier, vol. 132(C), pages 167-175.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Yuan, Zeming & Zhang, Yanghuan & Yang, Tai & Bu, Wengang & Guo, Shihai & Zhao, Dongliang, 2018. "Microstructure and enhanced gaseous hydrogen storage behavior of CoS2-catalyzed Sm5Mg41 alloy," Renewable Energy, Elsevier, vol. 116(PA), pages 878-891.
    2. Alina E. Kozhukhova & Stephanus P. du Preez & Dmitri G. Bessarabov, 2021. "Catalytic Hydrogen Combustion for Domestic and Safety Applications: A Critical Review of Catalyst Materials and Technologies," Energies, MDPI, vol. 14(16), pages 1-32, August.
    3. Ye, Yang & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2020. "Numerical simulation on the storage performance of a phase change materials based metal hydride hydrogen storage tank," Applied Energy, Elsevier, vol. 278(C).
    4. Ye, Yang & Yue, Yi & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "Enhanced hydrogen storage of a LaNi5 based reactor by using phase change materials," Renewable Energy, Elsevier, vol. 180(C), pages 734-743.
    5. Ye, Yang & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "The storage performance of metal hydride hydrogen storage tanks with reaction heat recovery by phase change materials," Applied Energy, Elsevier, vol. 299(C).
    6. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
    7. Reuß, Markus & Grube, Thomas & Robinius, Martin & Stolten, Detlef, 2019. "A hydrogen supply chain with spatial resolution: Comparative analysis of infrastructure technologies in Germany," Applied Energy, Elsevier, vol. 247(C), pages 438-453.
    8. Wang, Cong & Feng, Yu & Liu, Zekuan & Wang, Yilin & Fang, Jiwei & Qin, Jiang & Shao, Jiahui & Huang, Hongyan, 2022. "Assessment of thermodynamic performance and CO2 emission reduction for a supersonic precooled turbine engine cycle fueled with a new green fuel of ammonia," Energy, Elsevier, vol. 261(PA).
    9. Perčić, Maja & Vladimir, Nikola & Fan, Ailong, 2021. "Techno-economic assessment of alternative marine fuels for inland shipping in Croatia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    10. Zheng, Jianpeng & Chen, Liubiao & Liu, Xuming & Zhu, Honglai & Zhou, Yuan & Wang, Junjie, 2020. "Thermodynamic optimization of composite insulation system with cold shield for liquid hydrogen zero-boil-off storage," Renewable Energy, Elsevier, vol. 147(P1), pages 824-832.
    11. Sreedhar, I. & Kamani, Krutarth M. & Kamani, Bansi M. & Reddy, Benjaram M. & Venugopal, A., 2018. "A Bird's Eye view on process and engineering aspects of hydrogen storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 838-860.
    12. Bhandari, Ramchandra & Shah, Ronak Rakesh, 2021. "Hydrogen as energy carrier: Techno-economic assessment of decentralized hydrogen production in Germany," Renewable Energy, Elsevier, vol. 177(C), pages 915-931.
    13. Gorlova, A.M. & Kayl, N.L. & Komova, O.V. & Netskina, O.V. & Ozerova, A.M. & Odegova, G.V. & Bulavchenko, O.A. & Ishchenko, A.V. & Simagina, V.I., 2018. "Fast hydrogen generation from solid NH3BH3 under moderate heating and supplying a limited quantity of CoCl2 or NiCl2 solution," Renewable Energy, Elsevier, vol. 121(C), pages 722-729.
    14. Usman, Muhammad R., 2022. "Hydrogen storage methods: Review and current status," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    15. Minsoo Choi & Wongwan Jung & Sanghyuk Lee & Taehwan Joung & Daejun Chang, 2021. "Thermal Efficiency and Economics of a Boil-Off Hydrogen Re-Liquefaction System Considering the Energy Efficiency Design Index for Liquid Hydrogen Carriers," Energies, MDPI, vol. 14(15), pages 1-23, July.
    16. Anand, Abhijeet & Kumar, Vivek & Kaushal, Priyanka, 2022. "Biochar and its twin benefits: Crop residue management and climate change mitigation in India," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    17. Ádám Révész & Marcell Gajdics, 2021. "Improved H-Storage Performance of Novel Mg-Based Nanocomposites Prepared by High-Energy Ball Milling: A Review," Energies, MDPI, vol. 14(19), pages 1-31, October.
    18. Chen, Bin & Hajimolana, Yashar S. & Venkataraman, Vikrant & Ni, Meng & Aravind, P.V., 2019. "Integration of reversible solid oxide cells with methane synthesis (ReSOC-MS) in grid stabilization: A dynamic investigation," Applied Energy, Elsevier, vol. 250(C), pages 558-567.
    19. Guo, Feng & Zou, Hongtao & Yao, Qilu & Huang, Bin & Lu, Zhang-Hui, 2020. "Monodispersed bimetallic nanoparticles anchored on TiO2-decorated titanium carbide MXene for efficient hydrogen production from hydrazine in aqueous solution," Renewable Energy, Elsevier, vol. 155(C), pages 1293-1301.
    20. Parra, David & Swierczynski, Maciej & Stroe, Daniel I. & Norman, Stuart.A. & Abdon, Andreas & Worlitschek, Jörg & O’Doherty, Travis & Rodrigues, Lucelia & Gillott, Mark & Zhang, Xiaojin & Bauer, Chris, 2017. "An interdisciplinary review of energy storage for communities: Challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 730-749.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:113:y:2017:i:c:p:1399-1407. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.