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Static heterogeneities in liquid water

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  • Stanley, H.Eugene
  • Buldyrev, Sergey V.
  • Giovambattista, Nicolas

Abstract

The thermodynamic behavior of water seems to be closely related to static heterogeneities. These static heterogeneities are related to the local structure of water molecules, and when properly characterized, may offer an economical explanation of thermodynamic data. The key feature of liquid water is not so much that the existence of hydrogen bonds, first pointed out by Linus Pauling, but rather the local geometry of the liquid molecules is not spherical or oblong but tetrahedral. In the consideration of static heterogeneities, this local geometry is critical. Recent experiments suggested more than one phase of amorphous solid water, while simulations suggest that one of these phases is metastable with respect to another, so that in fact there are only two stable phases.

Suggested Citation

  • Stanley, H.Eugene & Buldyrev, Sergey V. & Giovambattista, Nicolas, 2004. "Static heterogeneities in liquid water," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 342(1), pages 40-47.
    • Handle: RePEc:eee:phsmap:v:342:y:2004:i:1:p:40-47
    DOI: 10.1016/j.physa.2004.06.045
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    References listed on IDEAS

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    1. Osamu Mishima & H. Eugene Stanley, 1998. "Decompression-induced melting of ice IV and the liquid–liquid transition in water," Nature, Nature, vol. 392(6672), pages 164-168, March.
    2. Osamu Mishima & H. Eugene Stanley, 1998. "The relationship between liquid, supercooled and glassy water," Nature, Nature, vol. 396(6709), pages 329-335, November.
    3. Stanley, H.E. & Buldyrev, S.V. & Giovambattista, N. & La Nave, E. & Scala, A. & Sciortino, F. & Starr, F.W., 2002. "Statistical physics and liquid water: “What matters”," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 306(C), pages 230-242.
    4. Franzese, Giancarlo & Eugene Stanley, H., 2002. "A theory for discriminating the mechanism responsible for the water density anomaly," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 314(1), pages 508-513.
    5. Masakazu Matsumoto & Shinji Saito & Iwao Ohmine, 2002. "Molecular dynamics simulation of the ice nucleation and growth process leading to water freezing," Nature, Nature, vol. 416(6879), pages 409-413, March.
    6. Buldyrev, Sergey V. & Stanley, H.Eugene, 2003. "A system with multiple liquid–liquid critical points," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 330(1), pages 124-129.
    7. Stanley, H.Eugene & Barbosa, M.C & Mossa, S & Netz, P.A & Sciortino, F & Starr, F.W & Yamada, M, 2002. "Statistical physics and liquid water at negative pressures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 315(1), pages 281-289.
    8. Jeffrey R. Errington & Pablo G. Debenedetti, 2001. "Relationship between structural order and the anomalies of liquid water," Nature, Nature, vol. 409(6818), pages 318-321, January.
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    Cited by:

    1. Gorban, Alexander, 2007. "Order–disorder separation: Geometric revision," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 374(1), pages 85-102.

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