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PVT properties and vapor-pressures of ordinary water substance in the critical region

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  • Morita, T.
  • Sato, H.
  • Uematsu, M.
  • Watanabe, K.

Abstract

For the purpose of revealing the rather complicated thermodynamic surface of ordinary water substance in the critical region, a series of measurements of the PVT properties and the vapor-pressures of this technically important fluid have been performed by means of a constant-volume method. Ninety-three PVT measurements along 14 isotherms between 638.15 K and 652.15 K have been completed covering pressures from 18.5 to 39.2 MPa and densities from 122 to 610kg/m3. Twenty-six vapor-pressure measurements have also been performed at temperatures between 620.15 K and 647.05 K in the near vicinity of the critical point. Our measurements are compared with other available experimental data as well as with several equations of state. We also propose a new vapor-pressure correlation from the triple point to the critical point.

Suggested Citation

  • Morita, T. & Sato, H. & Uematsu, M. & Watanabe, K., 1989. "PVT properties and vapor-pressures of ordinary water substance in the critical region," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(1), pages 436-453.
    • Handle: RePEc:eee:phsmap:v:156:y:1989:i:1:p:436-453
    DOI: 10.1016/0378-4371(89)90133-7
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