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Nonasymptotic critical thermodynamical behavior of fluids

Author

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  • Tang, S.
  • Sengers, J.V.
  • Chen, Z.Y.

Abstract

The paper is concerned with some theoretical and empirical attempts to obtain a unified equation for the thermodynamic properties of fluids that incorporates the nonclassical scaling laws near the critical point and crosses over to a classical analytic equation far away from the critical point. Specifically we investigate to what extent the various proposed crossover models agree with the known theoretical predictions for the universal ratios among the asymptotic and correction-to-scaling amplitudes in the power-law expansions of the thermodynamic properties around the critical point.

Suggested Citation

  • Tang, S. & Sengers, J.V. & Chen, Z.Y., 1991. "Nonasymptotic critical thermodynamical behavior of fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 179(3), pages 344-377.
    • Handle: RePEc:eee:phsmap:v:179:y:1991:i:3:p:344-377
    DOI: 10.1016/0378-4371(91)90084-P
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    References listed on IDEAS

    as
    1. Nieuwoudt, J.C. & Sengers, J.V., 1987. "Frequency dependence of transport properties of fluids near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 147(1), pages 368-386.
    2. Albright, Elizabeth Gerber & Albright, Robert J., 1985. "The economic impact of uncertainties associated with energy-saving technologies," Energy, Elsevier, vol. 10(5), pages 631-634.
    3. Sengers, J.V. & Gillespie, D.T. & Perez-Esandi, J.J., 1978. "Three-particle collision effects in the transport properties of a gas of hard spheres," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 90(3), pages 365-409.
    4. van Leeuwen, J.M.J. & Sengers, J.V., 1984. "Gravity effects on the correlation length in gases near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 128(1), pages 99-131.
    5. Kestin, J. & Korfali, Ö. & Sengers, J.V. & Kamgar-Parsi, B., 1981. "Density dependence and composition dependence of the viscosity of neon-helium and neon-argon mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 106(3), pages 415-442.
    6. Sengers, J.V. & Van Leeuwen, J.M.J., 1982. "Nonlocal gravity-induced density profiles in gases near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 116(3), pages 345-367.
    7. Clerke, E.A. & Sengers, J.V., 1983. "Fast pressure quenches near the critical point of a binary liquid mixture," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 118(1), pages 360-370.
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