IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v118y1983i1p360-370.html
   My bibliography  Save this article

Fast pressure quenches near the critical point of a binary liquid mixture

Author

Listed:
  • Clerke, E.A.
  • Sengers, J.V.

Abstract

Spinodal decomposition can be induced in liquid mixtures near the critical point by application of a fast pressure quench. As a result of such a pressure quench 1) the relative temperature of the system with respect to the critical temperature changes because of the dependence of the critical temperature on pressure, and 2) the absolute temperature of the system changes because of the finite value of the adiabatic thermal pressure coefficient. Experiments show that the first effect is dominant in isobutyric acid + water studied by other investigators and the second effect is dominant in 3-methylpentane + nitroethane studied by us. It is demonstrated that the adiabatic thermal pressure coefficient undergoes a rapidly varying anomalous behavior at temperatures very close to the critical temperature.

Suggested Citation

  • Clerke, E.A. & Sengers, J.V., 1983. "Fast pressure quenches near the critical point of a binary liquid mixture," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 118(1), pages 360-370.
  • Handle: RePEc:eee:phsmap:v:118:y:1983:i:1:p:360-370
    DOI: 10.1016/0378-4371(83)90205-4
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/0378437183902054
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

    File URL: https://libkey.io/10.1016/0378-4371(83)90205-4?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Easwar, N. & Joshua, M. & Maher, J.V. & Goldburg, W.I., 1983. "Observation of the relaxation of composition fluctuations in a binary liquid mixture," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 118(1), pages 268-281.
    2. Levelt Sengers, J.M.H., 1979. "Liquidons and gasons; controversies about the continuity of states," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 98(3), pages 363-402.
    3. Sengers, J.V. & Van Leeuwen, J.M.J., 1982. "Nonlocal gravity-induced density profiles in gases near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 116(3), pages 345-367.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. van Leeuwen, J.M.J. & Sengers, J.V., 1984. "Gravity effects on the correlation length in gases near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 128(1), pages 99-131.
    2. Morita, T. & Sato, H. & Uematsu, M. & Watanabe, K., 1989. "PVT properties and vapor-pressures of ordinary water substance in the critical region," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(1), pages 436-453.
    3. Nieuwoudt, J.C. & Sengers, J.V., 1987. "Frequency dependence of transport properties of fluids near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 147(1), pages 368-386.
    4. Tang, S. & Sengers, J.V. & Chen, Z.Y., 1991. "Nonasymptotic critical thermodynamical behavior of fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 179(3), pages 344-377.
    5. Onuki, Akira, 1996. "Adiabatic effects in nucleation near the gas-liquid critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 234(1), pages 189-205.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Nieuwoudt, J.C. & Sengers, J.V., 1987. "Frequency dependence of transport properties of fluids near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 147(1), pages 368-386.
    2. Van Leeuwen, J.M.J. & Sengers, J.V., 1989. "Capillary waves of a vapor-liquid interface in a gravitational field very close to the critical temperature," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 157(2), pages 839-856.
    3. Diller, Dwain E. & Saber, John M., 1981. "Measurements of the viscosity of compressed gaseous and liquid ethane," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 108(1), pages 143-152.
    4. Morita, T. & Sato, H. & Uematsu, M. & Watanabe, K., 1989. "PVT properties and vapor-pressures of ordinary water substance in the critical region," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(1), pages 436-453.
    5. Kestin, J. & Korfali, Ö. & Sengers, J.V., 1980. "Density expansion of the viscosity of carbon dioxide near the critical temperature," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 100(2), pages 335-348.
    6. Sengers, J.V. & Van Leeuwen, J.M.J. & Schmidt, J.W., 1991. "Capillary waves of fluid interfaces near a critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 172(1), pages 20-39.
    7. Van Leeuwen, J.M.J. & Sengers, J.V., 1985. "Gravity effects on the vapor-liquid interface very close to the critical temperature," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 132(2), pages 207-232.
    8. Tang, S. & Sengers, J.V. & Chen, Z.Y., 1991. "Nonasymptotic critical thermodynamical behavior of fluids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 179(3), pages 344-377.
    9. Sengers, J.V. & Van Leeuwen, J.M.J., 1982. "Nonlocal gravity-induced density profiles in gases near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 116(3), pages 345-367.
    10. van Leeuwen, J.M.J. & Sengers, J.V., 1984. "Gravity effects on the correlation length in gases near the critical point," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 128(1), pages 99-131.
    11. Tracy, Craig A. & Widom, Harold, 1997. "On exact solutions to the cylindrical Poisson-Boltzmann equation with applications to polyelectrolytes," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 244(1), pages 402-413.
    12. Van Leeuwen, J.M.J. & Sengers, J.V., 1986. "Scaling laws and universality of critical phenomena in the presence of an external field," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 138(1), pages 1-21.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:118:y:1983:i:1:p:360-370. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.