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A study of influence on nanocomposite membrane of sulfonated TiO2 and sulfonated polystyrene-ethylene-butylene-polystyrene for microbial fuel cell application

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  • Ayyaru, Sivasankaran
  • Dharmalingam, Sangeetha

Abstract

Microbial fuel cell (MFC) is a device that uses bacteria as a catalyst to oxidize various substrates for simultaneous electricity generation and wastewater treatment. In the present work, (sulfonated TiO2 (S-TiO2)/polystyrene ethylene butylene polystyrene) SPSEBS nanocomposite membranes were prepared by solution casting. The IEC (ion exchange capacity), water uptake, proton conductivity and MFC performance of the composite membranes were explored. SPSEBS-S-TiO2 membrane (7.5%) exhibited the highest IEC value, water uptake and proton conductivity capacity. The results revealed that the incorporation of sulfonated TiO2 improved the proton conductivity of the SPSEBS membrane effectively and exhibited the highest peak power density of 1345 ± 17 mWm−2 for SPSEBS-S-TiO2 7.5%, when compared to 695 ± 7 mWm−2 and 835 ± 8 mWm−2 obtained for SPSEBS and SPSEBS-TiO2 membranes respectively in a (single chambered microbial fuel cell) SCMFC. In comparison to previously reported work with Nafion (300 ± 10 mWm−2) in MFCs, the composite membrane delivered more than 4-fold higher power density. The oxygen mass transfer coefficient (KO) of nanocomposite membranes decreased with incorporation of the sulfonated TiO2 which in turn increased the (columbic efficiency) CE.

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  • Ayyaru, Sivasankaran & Dharmalingam, Sangeetha, 2015. "A study of influence on nanocomposite membrane of sulfonated TiO2 and sulfonated polystyrene-ethylene-butylene-polystyrene for microbial fuel cell application," Energy, Elsevier, vol. 88(C), pages 202-208.
    • Handle: RePEc:eee:energy:v:88:y:2015:i:c:p:202-208
    DOI: 10.1016/j.energy.2015.05.015
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    3. Pourzare, K. & Mansourpanah, Y. & Farhadi, S. & Sadrabadi, M.M. Hasani & Ulbricht, M., 2022. "Improvement of proton conductivity of magnetically aligned phosphotungstic acid-decorated cobalt oxide embedded Nafion membrane," Energy, Elsevier, vol. 239(PA).
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    5. Miguel Ángel López Zavala & Pamela Renée Torres Delenne & Omar Israel González Peña, 2018. "Improvement of Wastewater Treatment Performance and Power Generation in Microbial Fuel Cells by Enhancing Hydrolysis and Acidogenesis, and by Reducing Internal Losses," Energies, MDPI, vol. 11(9), pages 1-14, September.
    6. Sugumar, Moogambigai & Dharmalingam, Sangeetha, 2022. "Statistical assessment of operational parameters using optimized sulphonated titanium nanotubes incorporated sulphonated polystyrene ethylene butylene polystyrene nanocomposite membrane for efficient ," Energy, Elsevier, vol. 242(C).
    7. Ortiz-Martínez, V.M. & Salar-García, M.J. & Hernández-Fernández, F.J. & de los Ríos, A.P., 2015. "Development and characterization of a new embedded ionic liquid based membrane-cathode assembly for its application in single chamber microbial fuel cells," Energy, Elsevier, vol. 93(P2), pages 1748-1757.
    8. Alipour Moghaddam, Jafar & Parnian, Mohammad Javad & Rowshanzamir, Soosan, 2018. "Preparation, characterization, and electrochemical properties investigation of recycled proton exchange membrane for fuel cell applications," Energy, Elsevier, vol. 161(C), pages 699-709.

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