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Statistical assessment of operational parameters using optimized sulphonated titanium nanotubes incorporated sulphonated polystyrene ethylene butylene polystyrene nanocomposite membrane for efficient electricity generation in microbial fuel cell

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  • Sugumar, Moogambigai
  • Dharmalingam, Sangeetha

Abstract

Sulphonated Polystyrene Ethylene Butylene Polystyrene (SPSEBS) mixed with different weight percentages (2, 4, 6 and 8%) of synthesized Sulphonated Titanium Nanotubes (STNT) to prepare proton exchange membranes (PEM). The membrane properties confirms that SPSEBS +6% STNT exhibits higher water uptake, ion exchange capacity and proton conductivity when compared to certain previously reported membranes thereby suggesting better suitability for fuel cell performance. In present study, three operational parameters were investigated using optimized SPSEBS +6% STNT as PEM for better performance in MFC by adopting Box Behnken design. RSM results reveal that STAT 15 with acetate as substrate, 1000 Ω external resistance and 0.3% catalyst loading rate exhibits a maximum power density of 138 mW/m2. Thus, the synthesized and characterized nanocomposite membranes pose potentials in the fabricated tubular MFC design for enhanced power production. In addition, a regression equation for selected operational parameters for enhanced electricity generation in MFC has been proposed.

Suggested Citation

  • Sugumar, Moogambigai & Dharmalingam, Sangeetha, 2022. "Statistical assessment of operational parameters using optimized sulphonated titanium nanotubes incorporated sulphonated polystyrene ethylene butylene polystyrene nanocomposite membrane for efficient ," Energy, Elsevier, vol. 242(C).
    • Handle: RePEc:eee:energy:v:242:y:2022:i:c:s0360544221032497
    DOI: 10.1016/j.energy.2021.123000
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    References listed on IDEAS

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    1. Ayyaru, Sivasankaran & Dharmalingam, Sangeetha, 2015. "A study of influence on nanocomposite membrane of sulfonated TiO2 and sulfonated polystyrene-ethylene-butylene-polystyrene for microbial fuel cell application," Energy, Elsevier, vol. 88(C), pages 202-208.
    2. Leong, Jun Xing & Daud, Wan Ramli Wan & Ghasemi, Mostafa & Liew, Kien Ben & Ismail, Manal, 2013. "Ion exchange membranes as separators in microbial fuel cells for bioenergy conversion: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 575-587.
    3. Abdullah, M. & Kamarudin, S.K., 2017. "Titanium dioxide nanotubes (TNT) in energy and environmental applications: An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 212-225.
    4. Slate, Anthony J. & Whitehead, Kathryn A. & Brownson, Dale A.C. & Banks, Craig E., 2019. "Microbial fuel cells: An overview of current technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 60-81.
    5. Bhattacharyya, Subhes C., 2015. "Influence of India’s transformation on residential energy demand," Applied Energy, Elsevier, vol. 143(C), pages 228-237.
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