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Activated carbon derived from peat soil as a framework for the preparation of shape-stabilized phase change material

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  • Khadiran, Tumirah
  • Hussein, Mohd Zobir
  • Zainal, Zulkarnain
  • Rusli, Rafeadah

Abstract

This work focuses on the preparation of AC (activated carbon) through a physical activation method using peat soil as a precursor, followed by the use of the AC as an inorganic framework for the preparation of SPCM (shape-stabilized phase change material). The SPCM, composed of n-octadecane as the core and AC pores as a framework, was fabricated by a simple impregnation method, with the mass fraction of n-octadecane varying from 10 to 90 wt.%. The AC has a specific surface area of 893 m2 g−1 and an average pore size of 22 Å. The field emission scanning electron microscope images and nitrogen gas adsorption-desorption isotherms shows that the n-octadecane was actually encapsulated into the AC pores. The melting and freezing temperatures of the composite PCM (phase change material) were 30.9 °C and 24.1 °C, respectively, and its corresponding latent heat values were 95.4 Jg−1 and 99.6 Jg−1, respectively. The composite shows a good thermal reliability, even after 1000 melting/freezing cycles. The present research provided a new SPCM material for thermal energy storage as well as some new insights into the design of composite PCM by tailoring the pore structure of AC derived from peat soil, a natural resource.

Suggested Citation

  • Khadiran, Tumirah & Hussein, Mohd Zobir & Zainal, Zulkarnain & Rusli, Rafeadah, 2015. "Activated carbon derived from peat soil as a framework for the preparation of shape-stabilized phase change material," Energy, Elsevier, vol. 82(C), pages 468-478.
    • Handle: RePEc:eee:energy:v:82:y:2015:i:c:p:468-478
    DOI: 10.1016/j.energy.2015.01.057
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    7. Sarı, Ahmet & Hekimoğlu, Gökhan & Karabayır, Yasemin & Sharma, R.K. & Arslanoğlu, Hasan & Gencel, Osman & Tyagi, V.V., 2022. "Capric-stearic acid mixture impregnated carbonized waste sugar beet pulp as leak-resistive composite phase change material with effective thermal conductivity and thermal energy storage performance," Energy, Elsevier, vol. 247(C).
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