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Fast pyrolysis of Miscanthus sinensis in fluidized bed reactors: Characteristics of product yields and biocrude oil quality

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  • Bok, Jin Pil
  • Choi, Hang Seok
  • Choi, Joon Weon
  • Choi, Yeon Seok

Abstract

In the present work, fast pyrolysis of Miscanthus sinensis was performed and the product yields and properties of the resulting biocrude oil were determined for varying reactor configurations and pyrolysis temperatures. Two types of reactors (rectangular and cylindrical fluidized beds) were adopted, and pyrolysis temperature was increased from 400 °C to 550 °C. Based on the results, it was found that the reaction temperature greatly influenced the product yield and the characteristics of biocrude oil. The highest yield of biocrude oil for the rectangular reactor was 48.9 wt.%, produced at 500 °C, and the highest yield for the cylindrical reactor was 50.01 wt.%, produced at 450 °C. Additionally, the biocrude oil yield in the rectangular reactor sharply decreased when reaction temperature was increased to 550 °C, while only a slight decrease was observed in the cylindrical reactor. From GC/MS analysis, biocrude oil was found to contain various chemical components, such as nonaromatic ketones, furans, sugars, lignin-derived phenols, guaiacols and syringols. In particular, the sugar content of the biocrude oil produced in rectangular reactor (2.11–9.35 wt.%) was generally lower than that produced in the cylindrical reactor (7.93–10.79 wt.%).

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  • Bok, Jin Pil & Choi, Hang Seok & Choi, Joon Weon & Choi, Yeon Seok, 2013. "Fast pyrolysis of Miscanthus sinensis in fluidized bed reactors: Characteristics of product yields and biocrude oil quality," Energy, Elsevier, vol. 60(C), pages 44-52.
    • Handle: RePEc:eee:energy:v:60:y:2013:i:c:p:44-52
    DOI: 10.1016/j.energy.2013.08.024
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    1. Emily Heaton & Stephen Long & Thomas Voigt & Michael Jones & John Clifton-Brown, 2004. "Miscanthus for Renewable Energy Generation: European Union Experience and Projections for Illinois," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 9(4), pages 433-451, October.
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    3. Bok, Jin Pil & Choi, Hang Seok & Choi, Yeon Seok & Park, Hoon Chae & Kim, Seock Joon, 2012. "Fast pyrolysis of coffee grounds: Characteristics of product yields and biocrude oil quality," Energy, Elsevier, vol. 47(1), pages 17-24.
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    2. Vilaysit Thithai & Xuanjun Jin & Muhammed Ajaz Ahmed & Joon-Weon Choi, 2021. "Physicochemical Properties of Activated Carbons Produced from Coffee Waste and Empty Fruit Bunch by Chemical Activation Method," Energies, MDPI, vol. 14(11), pages 1-16, May.
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    7. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    8. Sang Kyu Choi & Yeon Seok Choi & Yeon Woo Jeong & So Young Han & Quynh Van Nguyen, 2020. "Simulation of the Fast Pyrolysis of Coffee Ground in a Tilted-Slide Reactor," Energies, MDPI, vol. 13(24), pages 1-19, December.
    9. Kim, Jae-Young & Oh, Shinyoung & Hwang, Hyewon & Moon, Youn-Ho & Choi, Joon Weon, 2014. "Assessment of miscanthus biomass (Miscanthus sacchariflorus) for conversion and utilization of bio-oil by fluidized bed type fast pyrolysis," Energy, Elsevier, vol. 76(C), pages 284-291.
    10. Lee, Hyung Won & Jun, Bo Ram & Kim, Hannah & Kim, Do Heui & Jeon, Jong-Ki & Park, Sung Hoon & Ko, Chang Hyun & Kim, Tae-Wan & Park, Young-Kwon, 2015. "Catalytic hydrodeoxygenation of 2-methoxy phenol and dibenzofuran over Pt/mesoporous zeolites," Energy, Elsevier, vol. 81(C), pages 33-40.
    11. Hwang, Jae Gyu & Park, Hoon Chae & Choi, Joon Weon & Oh, Shin Young & Moon, Youn Ho & Choi, Hang Seok, 2016. "Fast pyrolysis of the energy crop “Geodae-Uksae 1” in a bubbling fluidized bed reactor," Energy, Elsevier, vol. 95(C), pages 1-11.
    12. Choi, Sang Kyu & Choi, Yeon Seok & Han, So Young & Kim, Seock Joon & Rahman, Tawsif & Jeong, Yeon Woo & Van Nguyen, Quynh & Cha, Young Rok, 2019. "Bio-crude oil production from a new genotype of Miscanthus sacchariflorus Geodae-Uksae 1," Renewable Energy, Elsevier, vol. 144(C), pages 153-158.
    13. Alina Kowalczyk-Juśko & Andrzej Mazur & Patrycja Pochwatka & Damian Janczak & Jacek Dach, 2022. "Evaluation of the Effects of Using the Giant Miscanthus ( Miscanthus × Giganteus ) Biomass in Various Energy Conversion Processes," Energies, MDPI, vol. 15(10), pages 1-16, May.
    14. Wang, Wei-Cheng & Jan, Jyun-Jhih, 2018. "From laboratory to pilot: Design concept and techno-economic analyses of the fluidized bed fast pyrolysis of biomass," Energy, Elsevier, vol. 155(C), pages 139-151.

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