IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v80y2015icp465-473.html
   My bibliography  Save this article

A novel configuration of electrical double layer capacitor with plastic crystal based gel polymer electrolyte and graphene nano-platelets as electrodes: A high rate performance

Author

Listed:
  • Singh, Manoj K.
  • Suleman, Mohd
  • Kumar, Yogesh
  • Hashmi, S.A.

Abstract

A new, symmetrical, high rate, solid-state EDLC (electrical double layer capacitor) has been fabricated employing a plastic crystal SN (succinonitrile) based GPE (gel polymer electrolyte) and GNPs (graphene nano-platelets) as electrodes. The free-standing GPE film containing poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) exhibits the excellent suitability as electrolyte in EDLC due to its high ionic conductivity (∼2 × 10−3 S cm−1 at 20 °C), thermal stability (from −30 to 80 °C), electrochemical stability window (∼3.5 V vs. Ag), and excellent mechanical properties. The high rate capability of the EDLC has been observed from the impedance analysis in terms of high knee frequency (∼58 Hz), low response time (∼791 ms) and high pulse power (∼16.4 kW kg−1). The cyclic voltammetric response indicates the capacitive performance up to a substantially high scan rate of 1000 mV s−1, which further confirms the high rate performance of the EDLC. Though the specific energy of the solid-state EDLC is observed to be low (Emax ∼ 8.2 Wh kg−1), its power density is substantially high (Pmax > 4 kW kg−1). After ∼20% decrement in specific capacitance during the initial charge–discharge cycles, the EDLC offers almost stable performance up to ∼3500 cycles.

Suggested Citation

  • Singh, Manoj K. & Suleman, Mohd & Kumar, Yogesh & Hashmi, S.A., 2015. "A novel configuration of electrical double layer capacitor with plastic crystal based gel polymer electrolyte and graphene nano-platelets as electrodes: A high rate performance," Energy, Elsevier, vol. 80(C), pages 465-473.
    • Handle: RePEc:eee:energy:v:80:y:2015:i:c:p:465-473
    DOI: 10.1016/j.energy.2014.11.087
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214013607
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.11.087?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    2. Karandikar, Parashuram Balwant & Talange, Dhananjay Balu & Mhaskar, Uday Prakashrao & Bansal, Ramesh, 2012. "Development, modeling and characterization of aqueous metal oxide based supercapacitor," Energy, Elsevier, vol. 40(1), pages 131-138.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Liew, Chiam-Wen & Ramesh, S. & Arof, A.K., 2016. "Enhanced capacitance of EDLCs (electrical double layer capacitors) based on ionic liquid-added polymer electrolytes," Energy, Elsevier, vol. 109(C), pages 546-556.
    2. Shao, Zhou & Li, Hongji & Li, Mingji & Li, Cuiping & Qu, Changqing & Yang, Baohe, 2015. "Fabrication of polyaniline nanowire/TiO2 nanotube array electrode for supercapacitors," Energy, Elsevier, vol. 87(C), pages 578-585.
    3. Fouda, M.E. & Elwakil, A.S. & Radwan, A.G. & Allagui, A., 2016. "Power and energy analysis of fractional-order electrical energy storage devices," Energy, Elsevier, vol. 111(C), pages 785-792.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Huang, Ke-Jing & Wang, Lan & Zhang, Ji-Zong & Wang, Ling-Ling & Mo, Yan-Ping, 2014. "One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor," Energy, Elsevier, vol. 67(C), pages 234-240.
    2. Murashko, Kirill & Nevstrueva, Daria & Pihlajamäki, Arto & Koiranen, Tuomas & Pyrhönen, Juha, 2017. "Cellulose and activated carbon based flexible electrical double-layer capacitor electrode: Preparation and characterization," Energy, Elsevier, vol. 119(C), pages 435-441.
    3. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    4. Jagadale, Ajay D. & Kumbhar, Vijay S. & Bulakhe, Ravindra N. & Lokhande, Chandrakant D., 2014. "Influence of electrodeposition modes on the supercapacitive performance of Co3O4 electrodes," Energy, Elsevier, vol. 64(C), pages 234-241.
    5. Xu, Le & Zhao, Yan & Lian, Jiabiao & Xu, Yuanguo & Bao, Jian & Qiu, Jingxia & Xu, Li & Xu, Hui & Hua, Mingqing & Li, Huaming, 2017. "Morphology controlled preparation of ZnCo2O4 nanostructures for asymmetric supercapacitor with ultrahigh energy density," Energy, Elsevier, vol. 123(C), pages 296-304.
    6. Ghosh, Sampad & Withanage, Sajeevi S. & Chamlagain, Bhim & Khondaker, Saiful I. & Harish, Sivasankaran & Saha, Bidyut Baran, 2020. "Low pressure sulfurization and characterization of multilayer MoS2 for potential applications in supercapacitors," Energy, Elsevier, vol. 203(C).
    7. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    8. Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    9. Golkhatmi, Sanaz Zarabi & Sedghi, Arman & Miankushki, Hoda Nourmohammadi & Khalaj, Maryam, 2021. "Structural properties and supercapacitive performance evaluation of the nickel oxide/graphene/polypyrrole hybrid ternary nanocomposite in aqueous and organic electrolytes," Energy, Elsevier, vol. 214(C).
    10. Duan, Jiandong & Fan, Shaogui & Wu, Fengjiang & Sun, Li & Wang, Guanglin, 2017. "Power balance control of micro gas turbine generation system based on supercapacitor energy storage," Energy, Elsevier, vol. 119(C), pages 442-452.
    11. Iqbal, Muhammad Faisal & Ashiq, Muhammad Naeem & Hassan, Mahmood-Ul & Nawaz, Rahat & Masood, Aneeqa & Razaq, Aamir, 2018. "Excellent electrochemical behavior of graphene oxide based aluminum sulfide nanowalls for supercapacitor applications," Energy, Elsevier, vol. 159(C), pages 151-159.
    12. Li, Tianyu & Liu, Huiying & Ding, Daolin, 2018. "Predictive energy management of fuel cell supercapacitor hybrid construction equipment," Energy, Elsevier, vol. 149(C), pages 718-729.
    13. Li, Tianyu & Huang, Lingtao & Liu, Huiying, 2019. "Energy management and economic analysis for a fuel cell supercapacitor excavator," Energy, Elsevier, vol. 172(C), pages 840-851.
    14. Duan, Jiandong & Liu, Junjie & Xiao, Qian & Fan, Shaogui & Sun, Li & Wang, Guanglin, 2019. "Cooperative controls of micro gas turbine and super capacitor hybrid power generation system for pulsed power load," Energy, Elsevier, vol. 169(C), pages 1242-1258.
    15. Wang, Kai & Li, Liwei & Zhang, Tiezhu & Liu, Zaifei, 2014. "Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability," Energy, Elsevier, vol. 70(C), pages 612-617.
    16. Sieben, J.M. & Morallón, E. & Cazorla-Amorós, D., 2013. "Flexible ruthenium oxide-activated carbon cloth composites prepared by simple electrodeposition methods," Energy, Elsevier, vol. 58(C), pages 519-526.
    17. Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    18. Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.
    19. Cui, Yingzhi & Zuo, Pengjian & Du, Chunyu & Gao, Yunzhi & Yang, Jie & Cheng, Xinqun & Ma, Yulin & Yin, Geping, 2018. "State of health diagnosis model for lithium ion batteries based on real-time impedance and open circuit voltage parameters identification method," Energy, Elsevier, vol. 144(C), pages 647-656.
    20. Liew, Chiam-Wen & Ramesh, S. & Arof, A.K., 2016. "Enhanced capacitance of EDLCs (electrical double layer capacitors) based on ionic liquid-added polymer electrolytes," Energy, Elsevier, vol. 109(C), pages 546-556.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:80:y:2015:i:c:p:465-473. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.