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Electrocatalytic activity of simple and modified Fe–P electrodeposits for hydrogen evolution from alkaline media

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  • Sequeira, C.A.C.
  • Santos, D.M.F.
  • Brito, P.S.D.

Abstract

Electrodeposition of Fe–P, Fe–P–Pt and Fe–P–Ce into copper substrates is carried out under galvanostatic conditions. The influence of the current density on the composition of the deposits and the current efficiencies for the electrodeposition processes are determined. Preliminary data indicate that addition of formic acid to the electroplating bath improves the current efficiency for electrodeposition. Electrocatalytic activities of the heat-treated plated materials are investigated by dc polarisation and ac impedance techniques for the hydrogen evolution reaction (HER) in 1M NaOH solution at 298K. Steady-state polarisation curves and electrochemical impedance spectroscopy data show that improved catalytic activities for the HER are due to an increase in the effective surface area, a change in surface features upon heat treatment, the partial contribution of the Pt component, and the electrocatalytic synergism with Fe imposed by the Ce co-deposit. Cathodic potentiostatic measurements for medium time operation indicate that the electroplated materials are stable even in moderately aggressive alkaline solutions.

Suggested Citation

  • Sequeira, C.A.C. & Santos, D.M.F. & Brito, P.S.D., 2011. "Electrocatalytic activity of simple and modified Fe–P electrodeposits for hydrogen evolution from alkaline media," Energy, Elsevier, vol. 36(2), pages 847-853.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:2:p:847-853
    DOI: 10.1016/j.energy.2010.12.030
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    References listed on IDEAS

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    1. Penner, S.S., 2006. "Steps toward the hydrogen economy," Energy, Elsevier, vol. 31(1), pages 33-43.
    2. Mbah, Jonathan & Weaver, Eric & Srinivasan, Sesha & Krakow, Burton & Wolan, John & Goswami, Yogi & Stefanakos, Elias, 2010. "Low voltage H2O electrolysis for enhanced hydrogen production," Energy, Elsevier, vol. 35(12), pages 5008-5012.
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    Cited by:

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    2. Ensafi, Ali A. & Nabiyan, Afshin & Jafari-Asl, Mehdi & Dinari, Mohammad & Farrokhpour, Hossein & Rezaei, B., 2016. "Galvanic exchange at layered doubled hydroxide/N-doped graphene as an in-situ method to fabricate powerful electrocatalysts for hydrogen evolution reaction," Energy, Elsevier, vol. 116(P1), pages 1087-1096.
    3. Zhang, Houcheng & Lin, Guoxing & Chen, Jincan, 2011. "The performance analysis and multi-objective optimization of a typical alkaline fuel cell," Energy, Elsevier, vol. 36(7), pages 4327-4332.
    4. Santos, D.M.F. & Šljukić, B. & Sequeira, C.A.C. & Macciò, D. & Saccone, A. & Figueiredo, J.L., 2013. "Electrocatalytic approach for the efficiency increase of electrolytic hydrogen production: Proof-of-concept using platinum--dysprosium alloys," Energy, Elsevier, vol. 50(C), pages 486-492.
    5. Wu, Liang & He, Yuehui & Lei, Ting & Nan, Bo & Xu, Nanping & Zou, Jin & Huang, Baiyun & Liu, C.T., 2013. "Characterization of the porous Ni3Al–Mo electrodes during hydrogen generation from alkaline water electrolysis," Energy, Elsevier, vol. 63(C), pages 216-224.

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