IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v306y2024ics0360544224022060.html
   My bibliography  Save this article

Green iron and syngas production via continuous solar-driven agricultural waste biomass gasification combined with iron(III) oxide reduction

Author

Listed:
  • Chuayboon, Srirat
  • Abanades, Stéphane

Abstract

The production of renewable synthetic fuels and chemicals from solar energy and agricultural waste biomass is considered. Solar thermochemical conversion processes offer a promising pathway to a sustainable fuel economy and green chemical industry. This study investigates the continuous solar-driven gasification of agricultural biomass (betel nut waste) combined with iron oxide (Fe2O3) reduction to produce carbon-neutral syngas and green metallic iron in a single process. A thermodynamic analysis of the system was initially conducted to predict the distribution of equilibrium products. Then, on-sun continuous processing was experimentally carried out under different operating conditions, including betel/Fe2O3 molar ratios (0.56–1.5) and temperatures (900–1200 °C) to evaluate the process feasibility and reliability. As a result, solar gasification of betel nut waste combined with Fe2O3 reduction performed exceptionally well with continuous reactant particles feeding, demonstrating a feasible pathway for producing green iron and high-quality syngas. The maximum syngas yield reached 63.3 mmol/gdry_betel, approaching its theoretical value, and high-purity Fe was simultaneously produced. The process demonstrated high efficiency, with maximum carbon conversion approaching 98 %, energy upgrade factor up to 1.26, and solar-to-fuel energy conversion efficiency up to 14.4 %, highlighting remarkable conversion performance of biomass and solar energy to chemicals.

Suggested Citation

  • Chuayboon, Srirat & Abanades, Stéphane, 2024. "Green iron and syngas production via continuous solar-driven agricultural waste biomass gasification combined with iron(III) oxide reduction," Energy, Elsevier, vol. 306(C).
    • Handle: RePEc:eee:energy:v:306:y:2024:i:c:s0360544224022060
    DOI: 10.1016/j.energy.2024.132432
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544224022060
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2024.132432?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Han, Chengjin & Wei, Guangsheng & Zhu, Rong & Cheng, Yu & Wang, Runzhe & Wu, Wenhe & Wang, Yefeng, 2023. "Characterization and kinetics of iron oxide reduction by corn straw biochar prepared by pyrolysis using superheated steam atmosphere and hydrothermal processes," Renewable Energy, Elsevier, vol. 219(P2).
    2. Chimres, Nares & Wongwises, Somchai, 2016. "Critical review of the current status of solar energy in Thailand," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 198-207.
    3. Prasertsan, S. & Sajjakulnukit, B., 2006. "Biomass and biogas energy in Thailand: Potential, opportunity and barriers," Renewable Energy, Elsevier, vol. 31(5), pages 599-610.
    4. Chuayboon, Srirat & Abanades, Stéphane, 2023. "Carbon-neutral synfuel production via continuous solar H2O and CO2 gasification of oil palm empty fruit bunch," Energy, Elsevier, vol. 281(C).
    5. Jakapong Pongthanaisawan & Weerin Wangjiraniran & Nitida Nakapreecha, 2023. "Thailand Energy Scenarios: Pathways towards Carbon Neutrality 2050," International Journal of Energy Economics and Policy, Econjournals, vol. 13(1), pages 489-500, January.
    6. Ubando, Aristotle T. & Chen, Wei-Hsin & Ong, Hwai Chyuan, 2019. "Iron oxide reduction by graphite and torrefied biomass analyzed by TG-FTIR for mitigating CO2 emissions," Energy, Elsevier, vol. 180(C), pages 968-977.
    7. Boujjat, Houssame & Rodat, Sylvain & Chuayboon, Srirat & Abanades, Stéphane, 2019. "Experimental and numerical study of a directly irradiated hybrid solar/combustion spouted bed reactor for continuous steam gasification of biomass," Energy, Elsevier, vol. 189(C).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chuayboon, Srirat & Abanades, Stéphane, 2023. "Carbon-neutral synfuel production via continuous solar H2O and CO2 gasification of oil palm empty fruit bunch," Energy, Elsevier, vol. 281(C).
    2. Cromratie Clemons, Sáde K. & Salloum, Coleman R. & Herdegen, Kyle G. & Kamens, Richard M. & Gheewala, Shabbir H., 2021. "Life cycle assessment of a floating photovoltaic system and feasibility for application in Thailand," Renewable Energy, Elsevier, vol. 168(C), pages 448-462.
    3. Abdeshahian, Peyman & Lim, Jeng Shiun & Ho, Wai Shin & Hashim, Haslenda & Lee, Chew Tin, 2016. "Potential of biogas production from farm animal waste in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 714-723.
    4. Parnphumeesup, Piya & Kerr, Sandy A., 2011. "Stakeholder preferences towards the sustainable development of CDM projects: Lessons from biomass (rice husk) CDM project in Thailand," Energy Policy, Elsevier, vol. 39(6), pages 3591-3601, June.
    5. Maw Maw Tun & Dagmar Juchelková, 2019. "Biomass Sources and Energy Potential for Energy Sector in Myanmar: An Outlook," Resources, MDPI, vol. 8(2), pages 1-19, May.
    6. Baharoon, Dhyia Aidroos & Rahman, Hasimah Abdul & Fadhl, Saeed Obaid, 2016. "Publics׳ knowledge, attitudes and behavioral toward the use of solar energy in Yemen power sector," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 498-515.
    7. Changbo Wang & Lixiao Zhang & Shuying Yang & Mingyue Pang, 2012. "A Hybrid Life-Cycle Assessment of Nonrenewable Energy and Greenhouse-Gas Emissions of a Village-Level Biomass Gasification Project in China," Energies, MDPI, vol. 5(8), pages 1-16, July.
    8. Ali, Ghaffar & Nitivattananon, Vilas & Abbas, Sawaid & Sabir, Muazzam, 2012. "Green waste to biogas: Renewable energy possibilities for Thailand's green markets," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5423-5429.
    9. Ali, Shahid & Taweekun, Juntakan & Techato, Kuaanan & Waewsak, Jompob & Gyawali, Saroj, 2019. "GIS based site suitability assessment for wind and solar farms in Songkhla, Thailand," Renewable Energy, Elsevier, vol. 132(C), pages 1360-1372.
    10. Saha, Chayan Kumer & Nandi, Rajesh & Akter, Shammi & Hossain, Samira & Kabir, Kazi Bayzid & Kirtania, Kawnish & Islam, Md Tahmid & Guidugli, Laura & Reza, M. Toufiq & Alam, Md Monjurul, 2024. "Technical prospects and challenges of anaerobic co-digestion in Bangladesh: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 197(C).
    11. Luis Ángel Castillo-Gracia & Néstor Andrés Urbina-Suarez & Ángel Darío González-Delgado, 2024. "Bibliometric and Co-Occurrence Study of the Production of Bioethanol and Hydrogen from African Palm Rachis (2003–2023)," Sustainability, MDPI, vol. 17(1), pages 1-33, December.
    12. José Antonio Soriano & Reyes García-Contreras & Antonio José Carpio de Los Pinos, 2021. "Study of the Thermochemical Properties of Lignocellulosic Biomass from Energy Crops," Energies, MDPI, vol. 14(13), pages 1-18, June.
    13. Juanicó, Luis E. & Di Lalla, Nicolás & González, Alejandro D., 2017. "Full thermal-hydraulic and solar modeling to study low-cost solar collectors based on a single long LDPE hose," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 187-195.
    14. Tharaka Rama Krishna C. Doddapaneni & Timo Kikas, 2023. "Advanced Applications of Torrefied Biomass: A Perspective View," Energies, MDPI, vol. 16(4), pages 1-8, February.
    15. Tippayawong, N. & Thanompongchart, P., 2010. "Biogas quality upgrade by simultaneous removal of CO2 and H2S in a packed column reactor," Energy, Elsevier, vol. 35(12), pages 4531-4535.
    16. Lim, Xin-Le & Lam, Wei-Haur, 2014. "Public Acceptance of Marine Renewable Energy in Malaysia," Energy Policy, Elsevier, vol. 65(C), pages 16-26.
    17. Daniela Szymańska & Aleksandra Lewandowska, 2015. "Biogas Power Plants in Poland—Structure, Capacity, and Spatial Distribution," Sustainability, MDPI, vol. 7(12), pages 1-19, December.
    18. Curcio, Axel & Rodat, Sylvain & Vuillerme, Valéry & Abanades, Stéphane, 2022. "Design and validation of reactant feeding control strategies for the solar-autothermal hybrid gasification of woody biomass," Energy, Elsevier, vol. 254(PC).
    19. Youssef Karout & Axel Curcio & Julien Eynard & Stéphane Thil & Sylvain Rodat & Stéphane Abanades & Valéry Vuillerme & Stéphane Grieu, 2023. "Model-Based Predictive Control of a Solar Hybrid Thermochemical Reactor for High-Temperature Steam Gasification of Biomass," Clean Technol., MDPI, vol. 5(1), pages 1-23, March.
    20. Cheng, Shikun & Li, Zifu & Mang, Heinz-Peter & Neupane, Kalidas & Wauthelet, Marc & Huba, Elisabeth-Maria, 2014. "Application of fault tree approach for technical assessment of small-sized biogas systems in Nepal," Applied Energy, Elsevier, vol. 113(C), pages 1372-1381.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:306:y:2024:i:c:s0360544224022060. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.