IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v304y2024ics0360544224019431.html
   My bibliography  Save this article

Organic-inorganic hybrid phase change materials with high energy storage density based on porous shaped paraffin/hydrated salt/expanded graphite composites

Author

Listed:
  • Lei, Hui
  • Wang, Xuezi
  • Li, Yifan
  • Xie, Huaqing
  • Yu, Wei

Abstract

Latent heat thermal energy storage based on phase change materials (PCM) is considered to be an effective method to solve the contradiction between solar energy supply and demand in time and space. The development of PCM composites with high solar energy absorption efficiency and high energy storage density is the key to solar thermal storage technology. In this paper, a green and simple method is proposed to fabricate a porous PCM with stable shape, low supercooling degree and excellent photo-thermal conversion performance. The novel PCM which combine porous expanded graphite as the carrier material, n-eicosane as the stabilizer and sodium acetate trihydrate (SAT) as phase change energy storage material are designed and prepared by melt blending method. The expanded graphite contributes to the stable shape of the composites, and provides excellent thermal conductivity channels and light absorption properties as well. The composite PCM sample containing 3.3 wt% expanded graphite achieves excellent performance, phase change enthalpy of 266.54 J/g and a photothermal conversion efficiency of 91.14 %, and shows low supercooling degree of 2.2 °C with almost no leakage at 90 °C.

Suggested Citation

  • Lei, Hui & Wang, Xuezi & Li, Yifan & Xie, Huaqing & Yu, Wei, 2024. "Organic-inorganic hybrid phase change materials with high energy storage density based on porous shaped paraffin/hydrated salt/expanded graphite composites," Energy, Elsevier, vol. 304(C).
    • Handle: RePEc:eee:energy:v:304:y:2024:i:c:s0360544224019431
    DOI: 10.1016/j.energy.2024.132169
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544224019431
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2024.132169?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Quan, Bingqing & Wang, Jinzhi & Li, Yi & Sui, Miao & Xie, Heng & Liu, Zhigang & Wu, Hao & Lu, Xiang & Tong, Yi, 2023. "Cellulose nanofibrous/MXene aerogel encapsulated phase change composites with excellent thermal energy conversion and storage capacity," Energy, Elsevier, vol. 262(PB).
    2. Cui, Wenlong & Yuan, Yanping & Sun, Liangliang & Cao, Xiaoling & Yang, Xiaojiao, 2016. "Experimental studies on the supercooling and melting/freezing characteristics of nano-copper/sodium acetate trihydrate composite phase change materials," Renewable Energy, Elsevier, vol. 99(C), pages 1029-1037.
    3. Lin, Yaxue & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal performances and applications of thermal energy storage systems with inorganic phase change materials," Energy, Elsevier, vol. 165(PA), pages 685-708.
    4. Mohamed, Shamseldin A. & Al-Sulaiman, Fahad A. & Ibrahim, Nasiru I. & Zahir, Md. Hasan & Al-Ahmed, Amir & Saidur, R. & Yılbaş, B.S. & Sahin, A.Z., 2017. "A review on current status and challenges of inorganic phase change materials for thermal energy storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1072-1089.
    5. Nazari, Saeed & Safarzadeh, Habibollah & Bahiraei, Mehdi, 2019. "Experimental and analytical investigations of productivity, energy and exergy efficiency of a single slope solar still enhanced with thermoelectric channel and nanofluid," Renewable Energy, Elsevier, vol. 135(C), pages 729-744.
    6. Shi, Lei & Hu, Yanwei & Bai, Yijie & He, Yurong, 2020. "Dynamic tuning of magnetic phase change composites for solar-thermal conversion and energy storage," Applied Energy, Elsevier, vol. 263(C).
    7. Li, Min & Wang, Chengcheng, 2019. "Preparation and characterization of GO/PEG photo-thermal conversion form-stable composite phase change materials," Renewable Energy, Elsevier, vol. 141(C), pages 1005-1012.
    8. Chandel, S.S. & Agarwal, Tanya, 2017. "Review of current state of research on energy storage, toxicity, health hazards and commercialization of phase changing materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 581-596.
    9. Milián, Yanio E. & Gutiérrez, Andrea & Grágeda, Mario & Ushak, Svetlana, 2017. "A review on encapsulation techniques for inorganic phase change materials and the influence on their thermophysical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 983-999.
    10. Xiao, Qiangqiang & Fan, Jiaxin & Li, Li & Xu, Tao & Yuan, Wenhui, 2018. "Solar thermal energy storage based on sodium acetate trihydrate phase change hydrogels with excellent light-to-thermal conversion performance," Energy, Elsevier, vol. 165(PB), pages 1240-1247.
    11. Yari, Shahram & Safarzadeh, Habibollah & Bahiraei, Mehdi, 2021. "Experimental study of an absorber coil in spherical solar collector with practical dimensions at different flow rates," Renewable Energy, Elsevier, vol. 180(C), pages 1248-1259.
    12. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    13. Yang, Haibin & Bao, Xiaohua & Cui, Hongzhi & Lo, Tommy Y. & Chen, Xiangsheng, 2022. "Optimization of supercooling, thermal conductivity, photothermal conversion, and phase change temperature of sodium acetate trihydrate for thermal energy storage applications," Energy, Elsevier, vol. 254(PA).
    14. Li, Yanchen & Wang, Beibei & Zhang, Weiye & Zhao, Junqi & Fang, Xiaoyang & Sun, Jingmeng & Xia, Rongqi & Guo, Hongwu & Liu, Yi, 2022. "Processing wood into a phase change material with high solar-thermal conversion efficiency by introducing stable polyethylene glycol-based energy storage polymer," Energy, Elsevier, vol. 254(PA).
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Du, Kun & Calautit, John & Eames, Philip & Wu, Yupeng, 2021. "A state-of-the-art review of the application of phase change materials (PCM) in Mobilized-Thermal Energy Storage (M-TES) for recovering low-temperature industrial waste heat (IWH) for distributed heat," Renewable Energy, Elsevier, vol. 168(C), pages 1040-1057.
    2. Lin, Yaxue & Jia, Yuting & Alva, Guruprasad & Fang, Guiyin, 2018. "Review on thermal conductivity enhancement, thermal properties and applications of phase change materials in thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2730-2742.
    3. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    4. Yang, Haibin & Bao, Xiaohua & Cui, Hongzhi & Lo, Tommy Y. & Chen, Xiangsheng, 2022. "Optimization of supercooling, thermal conductivity, photothermal conversion, and phase change temperature of sodium acetate trihydrate for thermal energy storage applications," Energy, Elsevier, vol. 254(PA).
    5. Zhang, Yi & Tao, Wen & Wang, Kehan & Li, Dongxu, 2020. "Analysis of thermal properties of gypsum materials incorporated with microencapsulated phase change materials based on silica," Renewable Energy, Elsevier, vol. 149(C), pages 400-408.
    6. Li, Han & Li, Jinchao & Kong, Xiangfei & Long, Hao & Yang, Hua & Yao, Chengqiang, 2020. "A novel solar thermal system combining with active phase-change material heat storage wall (STS-APHSW): Dynamic model, validation and thermal performance," Energy, Elsevier, vol. 201(C).
    7. Fan, Ruijin & Wan, Minghan & Zhou, Tian & Zheng, Nianben & Sun, Zhiqiang, 2024. "Graphene-enhanced phase change material systems: Minimizing optical and thermal losses for solar thermal applications," Energy, Elsevier, vol. 289(C).
    8. M. Mofijur & Teuku Meurah Indra Mahlia & Arridina Susan Silitonga & Hwai Chyuan Ong & Mahyar Silakhori & Muhammad Heikal Hasan & Nandy Putra & S.M. Ashrafur Rahman, 2019. "Phase Change Materials (PCM) for Solar Energy Usages and Storage: An Overview," Energies, MDPI, vol. 12(16), pages 1-20, August.
    9. Wong-Pinto, Liey-Si & Milian, Yanio & Ushak, Svetlana, 2020. "Progress on use of nanoparticles in salt hydrates as phase change materials," Renewable and Sustainable Energy Reviews, Elsevier, vol. 122(C).
    10. Wang, Yan & Yu, Kaixiang & Peng, Hao & Ling, Xiang, 2019. "Preparation and thermal properties of sodium acetate trihydrate as a novel phase change material for energy storage," Energy, Elsevier, vol. 167(C), pages 269-274.
    11. Zhao, B.C. & Wang, R.Z., 2019. "Perspectives for short-term thermal energy storage using salt hydrates for building heating," Energy, Elsevier, vol. 189(C).
    12. Yu, Kunyang & Liu, Yushi & Yang, Yingzi, 2021. "Review on form-stable inorganic hydrated salt phase change materials: Preparation, characterization and effect on the thermophysical properties," Applied Energy, Elsevier, vol. 292(C).
    13. Dubey, Abhayjeet kumar & Sun, Jingyi & Choudhary, Tushar & Dash, Madhusmita & Rakshit, Dibakar & Ansari, M Zahid & Ramakrishna, Seeram & Liu, Yong & Nanda, Himansu Sekhar, 2023. "Emerging phase change materials with improved thermal efficiency for a clean and sustainable environment: An approach towards net zero," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    14. Faraj, Khaireldin & Khaled, Mahmoud & Faraj, Jalal & Hachem, Farouk & Castelain, Cathy, 2020. "Phase change material thermal energy storage systems for cooling applications in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    15. Huo, Ying-Jie & Yan, Ting & Wu, Shao-Fei & Kuai, Zi-Han & Pan, Wei-Guo, 2024. "Preparation and thermal properties of palmitic acid/copper foam phase change materials," Energy, Elsevier, vol. 293(C).
    16. Jayathunga, D.S. & Karunathilake, H.P. & Narayana, M. & Witharana, S., 2024. "Phase change material (PCM) candidates for latent heat thermal energy storage (LHTES) in concentrated solar power (CSP) based thermal applications - A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    17. Daniarta, Sindu & Nemś, Magdalena & Kolasiński, Piotr, 2023. "A review on thermal energy storage applicable for low- and medium-temperature organic Rankine cycle," Energy, Elsevier, vol. 278(PA).
    18. Wang, Ting & Qiu, Xiaolin & Chen, Xiaojing & Lu, Lixin & Zhou, Binglin, 2022. "Sponge-like form-stable phase change materials with embedded graphene oxide for enhancing the thermal storage efficiency and the temperature response in transport packaging applications," Applied Energy, Elsevier, vol. 325(C).
    19. Zhao, B.C. & Li, T.X. & Gao, J.C. & Wang, R.Z., 2020. "Latent heat thermal storage using salt hydrates for distributed building heating: A multi-level scale-up research," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    20. Liu, Chenzhen & Cheng, Qingjiang & Li, Baohuan & Liu, Xinjian & Rao, Zhonghao, 2023. "Recent advances of sugar alcohols phase change materials for thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:304:y:2024:i:c:s0360544224019431. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.