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Thermodynamics and Kinetics of CO 2 /CH 4 Adsorption on Shale from China: Measurements and Modeling

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  • Yuan Chi

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China)

  • Changzhong Zhao

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China)

  • Junchen Lv

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China)

  • Jiafei Zhao

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China)

  • Yi Zhang

    (Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy and Power Engineering, Dalian University of Technology, Dalian 116024, China)

Abstract

CO 2 -enhanced shale gas recovery (CO 2 -ESGR) sequestrates anthropogenic CO 2 and improves the profitability of shale gas exploitation. This work investigated the adsorption behaviors of CO 2 and CH 4 on shale from China at 20, 40, 60 and 80 °C. The pressure ranges for CO 2 and CH 4 were 1–5 and 1–15 MPa, respectively. The excess adsorbed amount of CH 4 increased with increasing pressure from the beginning to the end, while the maximum excess CO 2 adsorption was observed at approximately 4 MPa. The absolute average deviations (AADs) of CO 2 and CH 4 , determined by the Langmuir + k model, were 2.12–3.10% and 0.88–1.11%, respectively. Relatively good adsorptivity for CO 2 was exhibited when the pressure was less than 5 MPa, which was beneficial to the implementation of CO 2 -ESGR. With continuous increases in pressure, the adsorption capacity of CO 2 was weaker than that of CH 4 , suggesting that the injected CO 2 would reduce the partial pressure of CH 4 for CO 2 -ESGR and the displacement effect would no longer be significant. In addition, the adsorption rate of CO 2 was much faster than that of CH 4 . CO 2 was more active in the competitive adsorption and it was advantageous to the efficiency of CO 2 -ESGR.

Suggested Citation

  • Yuan Chi & Changzhong Zhao & Junchen Lv & Jiafei Zhao & Yi Zhang, 2019. "Thermodynamics and Kinetics of CO 2 /CH 4 Adsorption on Shale from China: Measurements and Modeling," Energies, MDPI, vol. 12(6), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:6:p:978-:d:213587
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    References listed on IDEAS

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    Cited by:

    1. Wenxiao Chu & Maria Vicidomini & Francesco Calise & Neven Duić & Poul Alborg Østergaard & Qiuwang Wang & Maria da Graça Carvalho, 2022. "Recent Advances in Low-Carbon and Sustainable, Efficient Technology: Strategies and Applications," Energies, MDPI, vol. 15(8), pages 1-30, April.
    2. Xie, Weidong & Wang, Hua & Vandeginste, Veerle & Chen, Si & Gan, Huajun & Wang, Meng & Yu, Zhenghong, 2023. "Thermodynamic and kinetic affinity of CO2 relative to CH4 and their pressure, temperature and pore structure sensitivity in the competitive adsorption system in shale gas reservoirs," Energy, Elsevier, vol. 277(C).

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