IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v273y2023ics0360544223005716.html
   My bibliography  Save this article

Effects of the carbonization temperature and intermediate cooling mode on the properties of coal-based activated carbon

Author

Listed:
  • Zhao, Can
  • Ge, Lichao
  • Li, Xi
  • Zuo, Mingjin
  • Xu, Chunyao
  • Chen, Simo
  • Li, Qian
  • Wang, Yang
  • Xu, Chang

Abstract

To optimize the production of coal-based activated carbon, the effects of carbonization temperature on the surface functional groups, crystal characteristics, degree of graphitization, thermal stability and mechanical strength of char were studied; additionally, the effects of intermediate cooling on the pore structure, adsorption capacity and mechanical strength of activated carbon were studied. The results showed that the raw material lost many functional groups during carbonization. Carbonization improved the degree of graphitization, thermal stability and mechanical strength of the raw material, and char with a high degree of graphitization, a high thermal stability and mechanical strength was obtained with a higher carbonization temperature. The activated carbon prepared by direct heating after carbonization had a more developed pore structure, adsorption capacity and mechanical strength. The pore structure of the activated carbon was mainly produced during activation. Finally, the optimal conditions were determined as follows: a carbonization temperature of 800 °C and direct heating for activation after carbonization. The yield of the activated carbon was 48.2%, the Brunauer–Emmett–Teller specific surface area was 494 m2∙g−1, the total pore volume was 0.29 cm3∙g−1, the iodine value was 785 mg∙g−1, the compressive strength was 23.5 daN, and the wear strength was 83.5%.

Suggested Citation

  • Zhao, Can & Ge, Lichao & Li, Xi & Zuo, Mingjin & Xu, Chunyao & Chen, Simo & Li, Qian & Wang, Yang & Xu, Chang, 2023. "Effects of the carbonization temperature and intermediate cooling mode on the properties of coal-based activated carbon," Energy, Elsevier, vol. 273(C).
  • Handle: RePEc:eee:energy:v:273:y:2023:i:c:s0360544223005716
    DOI: 10.1016/j.energy.2023.127177
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223005716
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2023.127177?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhu, Wenkun & Li, Xiaohui & Sun, Rui & Yan, Yonghong & Liu, Jing & Wang, Zhuozhi & Yu, Xing, 2023. "Microstructural evolution of coal to char after pyrolysis using laser-induced breakdown spectroscopy and Raman spectroscopy," Energy, Elsevier, vol. 267(C).
    2. Li, He & Shi, Shiliang & Lin, Baiquan & Lu, Jiexin & Ye, Qing & Lu, Yi & Wang, Zheng & Hong, Yidu & Zhu, Xiangnan, 2019. "Effects of microwave-assisted pyrolysis on the microstructure of bituminous coals," Energy, Elsevier, vol. 187(C).
    3. Ge, Lichao & Zhao, Can & Chen, Simo & Li, Qian & Zhou, Tianhong & Jiang, Han & Li, Xi & Wang, Yang & Xu, Chang, 2022. "An analysis of the carbonization process and volatile-release characteristics of coal-based activated carbon," Energy, Elsevier, vol. 257(C).
    4. Xin, Lin & An, Mingyu & Feng, Mingze & Li, Kaixuan & Cheng, Weimin & Liu, Weitao & Hu, Xiangming & Wang, Zhigang & Han, Limin, 2021. "Study on pyrolysis characteristics of lump coal in the context of underground coal gasification," Energy, Elsevier, vol. 237(C).
    5. Ge, Lichao & Zhao, Can & Zhou, Tianhong & Chen, Simo & Li, Qian & Wang, Xuguang & Shen, Dong & Wang, Yang & Xu, Chang, 2023. "An analysis of the carbonization process of coal-based activated carbon at different heating rates," Energy, Elsevier, vol. 267(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhao, Can & Ge, Lichao & Zuo, Mingjin & Mai, Longhui & Chen, Simo & Li, Xiaolong & Li, Qian & Wang, Yang & Xu, Chang, 2023. "Study on the mechanical strength and iodine adsorption behavior of coal-based activated carbon based on orthogonal experiments," Energy, Elsevier, vol. 282(C).
    2. Feng, Hongcui & Zhou, Tianhong & Ge, Lichao & Li, Qian & Zhao, Chan & Huang, Jing & Wang, Yang, 2024. "Study on the preparation of high value-added activated carbon from petroleum coke: Comparison between one- and two-step methods for carbonization and activation," Energy, Elsevier, vol. 292(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhao, Can & Ge, Lichao & Mai, Longhui & Chen, Simo & Li, Qian & Yao, Lei & Li, Dongyang & Wang, Yang & Xu, Chang, 2023. "Preparation and performance of coal-based activated carbon based on an orthogonal experimental study," Energy, Elsevier, vol. 274(C).
    2. Zhao, Can & Ge, Lichao & Zuo, Mingjin & Mai, Longhui & Chen, Simo & Li, Xiaolong & Li, Qian & Wang, Yang & Xu, Chang, 2023. "Study on the mechanical strength and iodine adsorption behavior of coal-based activated carbon based on orthogonal experiments," Energy, Elsevier, vol. 282(C).
    3. Ge, Lichao & Zhao, Can & Zhou, Tianhong & Chen, Simo & Li, Qian & Wang, Xuguang & Shen, Dong & Wang, Yang & Xu, Chang, 2023. "An analysis of the carbonization process of coal-based activated carbon at different heating rates," Energy, Elsevier, vol. 267(C).
    4. Zhang, Chao & Zhao, Yangsheng & Feng, Zijun & Meng, Qiaorong & Wang, Lei & Lu, Yang, 2023. "Thermal maturity and chemical structure evolution of lump long-flame coal during superheated water vapor–based in situ pyrolysis," Energy, Elsevier, vol. 263(PC).
    5. Zhang, Chao & Zhao, Yangsheng & Feng, Zijun & Wang, Lei & Meng, Qiaorong & Lu, Yang & Gao, Qiang, 2023. "Comparative study on the chemical structure characteristics of lump coal during superheated water vapor pyrolysis and conventional pyrolysis," Energy, Elsevier, vol. 276(C).
    6. Kuang, Yucen & Jiang, Tao & Wu, Longqi & Liu, Xiaoqian & Yang, Xuke & Sher, Farooq & Wei, Zhifang & Zhang, Shengfu, 2023. "High-temperature rheological behavior and non-isothermal pyrolysis mechanism of macerals separated from different coals," Energy, Elsevier, vol. 277(C).
    7. Yuxuan Zhou & Shugang Li & Yang Bai & Hang Long & Yuchu Cai & Jingfei Zhang, 2023. "Joint Characterization and Fractal Laws of Pore Structure in Low-Rank Coal," Sustainability, MDPI, vol. 15(12), pages 1-19, June.
    8. Tao, Ming & Yang, Zheng & Zhao, Yan & Wu, Xingyu & Wu, Chengqing, 2024. "Failure characteristics of microwave heat-treated stressed sandstone: Implications for deep rock breakage using TBM cutting," Energy, Elsevier, vol. 292(C).
    9. Haijun Guo & Zhixiang Cheng & Kai Wang & Baolin Qu & Liang Yuan & Chao Xu, 2020. "Coal permeability evolution characteristics: Analysis under different loading conditions," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 347-363, April.
    10. Wang, Xiaorui & Zhang, Qinghe & Yuan, Liang, 2024. "A coupled thermal-force-chemical-displacement multi-field model for underground coal gasification based on controlled retraction injection point technology and its thermal analysis," Energy, Elsevier, vol. 293(C).
    11. Yongzan, Wen & Guanhua, Ni & Xinyue, Zhang & Yicheng, Zheng & Gang, Wang & Zhenyang, Wang & Qiming, Huang, 2023. "Fine characterization of pore structure of acidified anthracite based on liquid intrusion method and Micro-CT," Energy, Elsevier, vol. 263(PA).
    12. Ge, Lichao & Zhao, Can & Chen, Simo & Li, Qian & Zhou, Tianhong & Jiang, Han & Li, Xi & Wang, Yang & Xu, Chang, 2022. "An analysis of the carbonization process and volatile-release characteristics of coal-based activated carbon," Energy, Elsevier, vol. 257(C).
    13. Bai, Gang & Su, Jun & Zhang, Zunguo & Lan, Anchang & Zhou, Xihua & Gao, Fei & Zhou, Jianbin, 2022. "Effect of CO2 injection on CH4 desorption rate in poor permeability coal seams: An experimental study," Energy, Elsevier, vol. 238(PA).
    14. Liu, Jia & Xue, Yi & Fu, Yong & Yao, Kai & Liu, Jianqiang, 2023. "Numerical investigation on microwave-thermal recovery of shale gas based on a fully coupled electromagnetic, heat transfer, and multiphase flow model," Energy, Elsevier, vol. 263(PE).
    15. Hao Wang & Xiaogang Li & Jingyi Zhu & Zhaozhong Yang & Jie Zhou & Liangping Yi, 2022. "Numerical Simulation of Oil Shale Pyrolysis under Microwave Irradiation Based on a Three-Dimensional Porous Medium Multiphysics Field Model," Energies, MDPI, vol. 15(9), pages 1-20, April.
    16. Feng, Lele & Zhou, Sibo & Xu, Xiangcen & Qin, Botao, 2022. "Importance evaluation for influencing factors of underground coal gasification through ex-situ experiment and analytic hierarchy process," Energy, Elsevier, vol. 261(PA).
    17. Yi Zhang & Jun Xu & Deming Wang, 2020. "Experimental Study on the Inhibition Effects of Nitrogen and Carbon Dioxide on Coal Spontaneous Combustion," Energies, MDPI, vol. 13(20), pages 1-14, October.
    18. Li, Min & Yang, Xueqin & Lu, Yi & Wang, Deming & Shi, Shiliang & Ye, Qing & Li, He & Wang, Zheng, 2023. "Thermodynamic variation law and influence mechanism of low-temperature oxidation of lignite samples with different moisture contents," Energy, Elsevier, vol. 262(PB).
    19. Wang, Yihan & Yang, Wei & Yang, Wenming & Luo, Liming & lyu, Jieyao, 2024. "Effect of AES anionic surfactant on the microstructure and wettability of coal," Energy, Elsevier, vol. 289(C).
    20. Dong, Maifan & Feng, Lele & Qin, Botao, 2023. "Characteristics of coal gasification with CO2 after microwave irradiation based on TGA, FTIR and DFT theory," Energy, Elsevier, vol. 267(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:273:y:2023:i:c:s0360544223005716. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.