IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v270y2023ics0360544223002967.html
   My bibliography  Save this article

Facilitating clathrate hydrates with extremely rapid and high gas uptake for chemical-free carbon capture and methane storage

Author

Listed:
  • Kim, Kwangbum
  • Truong-Lam, Hai Son
  • Lee, Ju Dong
  • Sa, Jeong-Hoon

Abstract

Clathrate hydrates are crystalline solid compounds comprising water and gas with remarkable potential for energy storage and carbon capture because of their large gas storage capacity and ability to selectively capture certain species upon crystallization. However, their use in real life has been hindered by low gas uptake kinetics, primarily limited by mass transfer. While extensive efforts have been made to overcome this limitation using chemical additives, their kinetic effects are insufficient, and environmental problems are caused. Here, the highest CO2 and CH4 gas uptake kinetics ever reported in clathrate hydrates were achieved without any chemical additives or mechanical mixing. The CO2 gas uptake rate and amount far exceeded previous records by 55.3% and 21.6%, respectively. Such excellent kinetics were accomplished using a fixed-bed reactor filled with surface-modified silica sand, which can be easily produced by simple treatment. Raman analysis and morphological studies demonstrated that its hydrophobic surface significantly affects interfacial interactions with water, greatly enhancing mass transfer. This new method is energy-efficient and environment-friendly, not requiring mechanical mixing or chemical injection at all. Mechanistic understandings of hydrate formation with hydrophobic surfaces would be applicable to hydrate-based carbon capture, methane storage, and natural gas hydrate production systems.

Suggested Citation

  • Kim, Kwangbum & Truong-Lam, Hai Son & Lee, Ju Dong & Sa, Jeong-Hoon, 2023. "Facilitating clathrate hydrates with extremely rapid and high gas uptake for chemical-free carbon capture and methane storage," Energy, Elsevier, vol. 270(C).
  • Handle: RePEc:eee:energy:v:270:y:2023:i:c:s0360544223002967
    DOI: 10.1016/j.energy.2023.126902
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544223002967
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2023.126902?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Babu, Ponnivalavan & Linga, Praveen & Kumar, Rajnish & Englezos, Peter, 2015. "A review of the hydrate based gas separation (HBGS) process for carbon dioxide pre-combustion capture," Energy, Elsevier, vol. 85(C), pages 261-279.
    2. E. Dendy Sloan, 2003. "Fundamental principles and applications of natural gas hydrates," Nature, Nature, vol. 426(6964), pages 353-359, November.
    3. Veluswamy, Hari Prakash & Kumar, Asheesh & Kumar, Rajnish & Linga, Praveen, 2017. "An innovative approach to enhance methane hydrate formation kinetics with leucine for energy storage application," Applied Energy, Elsevier, vol. 188(C), pages 190-199.
    4. Cai, Jing & Zhang, Yu & Xu, Chun-Gang & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen, 2018. "Raman spectroscopic studies on carbon dioxide separation from fuel gas via clathrate hydrate in the presence of tetrahydrofuran," Applied Energy, Elsevier, vol. 214(C), pages 92-102.
    5. Ho, Leong Chuan & Babu, Ponnivalavan & Kumar, Rajnish & Linga, Praveen, 2013. "HBGS (hydrate based gas separation) process for carbon dioxide capture employing an unstirred reactor with cyclopentane," Energy, Elsevier, vol. 63(C), pages 252-259.
    6. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Shen, Xiaodong & Li, Yang & Shen, Long & Zeng, Wenjing & Zhou, Xuebing & He, Juan & Yin, Zhenyuan & Zhang, Yinde & Wang, Xiaoguang, 2024. "Promotion mechanism of carbon dioxide hydrate formation by l-Methionine and its competitive effects with NaCl," Energy, Elsevier, vol. 302(C).
    2. Antonio Pavón-García & Abel Zúñiga-Moreno & Ricardo García-Morales & Francisco Javier Verónico-Sánchez & Octavio Elizalde-Solis, 2023. "Evaluation of Temperature on the Methane Hydrates Formation Process Using Sodium Surfactin and Rhamnolipids," Energies, MDPI, vol. 17(1), pages 1-15, December.
    3. Kang, Dong Woo & Lee, Wonhyeong & Ahn, Yun-Ho & Kim, Kwangbum & Lee, Jae W., 2024. "Facile and sustainable methane storage via clathrate hydrate formation with low dosage promoters in a sponge matrix," Energy, Elsevier, vol. 292(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Ze-Yu & Xia, Zhi-Ming & Chen, Zhao-Yang & Li, Xiao-Sen & Xu, Chun-Gang & Yan, Ran, 2019. "The plateau effects and crystal transition study in Tetrahydrofuran (THF)/CO2/H2 hydrate formation processes," Applied Energy, Elsevier, vol. 238(C), pages 195-201.
    2. Liu, Fa-Ping & Li, Ai-Rong & Qing, Sheng-Lan & Luo, Ze-Dong & Ma, Yu-Ling, 2022. "Formation kinetics, mechanism of CO2 hydrate and its applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    3. Veluswamy, Hari Prakash & Kumar, Asheesh & Premasinghe, Kulesha & Linga, Praveen, 2017. "Effect of guest gas on the mixed tetrahydrofuran hydrate kinetics in a quiescent system," Applied Energy, Elsevier, vol. 207(C), pages 573-583.
    4. Zheng, Junjie & Bhatnagar, Krittika & Khurana, Maninder & Zhang, Peng & Zhang, Bao-Yong & Linga, Praveen, 2018. "Semiclathrate based CO2 capture from fuel gas mixture at ambient temperature: Effect of concentrations of tetra-n-butylammonium fluoride (TBAF) and kinetic additives," Applied Energy, Elsevier, vol. 217(C), pages 377-389.
    5. Olga Gaidukova & Sergey Misyura & Vladimir Morozov & Pavel Strizhak, 2023. "Gas Hydrates: Applications and Advantages," Energies, MDPI, vol. 16(6), pages 1-19, March.
    6. Qureshi, M Fahed & Khandelwal, Himanshu & Usadi, Adam & Barckholtz, Timothy A. & Mhadeshwar, Ashish B. & Linga, Praveen, 2022. "CO2 hydrate stability in oceanic sediments under brine conditions," Energy, Elsevier, vol. 256(C).
    7. Wang, Yiwei & Deng, Ye & Guo, Xuqiang & Sun, Qiang & Liu, Aixian & Zhang, Guangqing & Yue, Gang & Yang, Lanying, 2018. "Experimental and modeling investigation on separation of methane from coal seam gas (CSG) using hydrate formation," Energy, Elsevier, vol. 150(C), pages 377-395.
    8. Veluswamy, Hari Prakash & Kumar, Asheesh & Seo, Yutaek & Lee, Ju Dong & Linga, Praveen, 2018. "A review of solidified natural gas (SNG) technology for gas storage via clathrate hydrates," Applied Energy, Elsevier, vol. 216(C), pages 262-285.
    9. Feng, Jing-Chun & Wang, Yi & Li, Xiao-Sen, 2016. "Energy and entropy analyses of hydrate dissociation in different scales of hydrate simulator," Energy, Elsevier, vol. 102(C), pages 176-186.
    10. Zhang, Qiang & Zheng, Junjie & Zhang, Baoyong & Linga, Praveen, 2021. "Coal mine gas separation of methane via clathrate hydrate process aided by tetrahydrofuran and amino acids," Applied Energy, Elsevier, vol. 287(C).
    11. Jyoti Shanker Pandey & Yousef Jouljamal Daas & Adam Paul Karcz & Nicolas von Solms, 2020. "Enhanced Hydrate-Based Geological CO 2 Capture and Sequestration as a Mitigation Strategy to Address Climate Change," Energies, MDPI, vol. 13(21), pages 1-28, October.
    12. Sa, Jeong-Hoon & Sum, Amadeu K., 2019. "Promoting gas hydrate formation with ice-nucleating additives for hydrate-based applications," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    13. Zhang, Fengyuan & Wang, Xiaolin & Lou, Xia & Lipiński, Wojciech, 2021. "The effect of sodium dodecyl sulfate and dodecyltrimethylammonium chloride on the kinetics of CO2 hydrate formation in the presence of tetra-n-butyl ammonium bromide for carbon capture applications," Energy, Elsevier, vol. 227(C).
    14. Remi-Erempagamo Tariyemienyo Meindinyo & Thor Martin Svartaas, 2016. "Gas Hydrate Growth Kinetics: A Parametric Study," Energies, MDPI, vol. 9(12), pages 1-29, December.
    15. Wang, Xiaolin & Zhang, Fengyuan & Lipiński, Wojciech, 2020. "Research progress and challenges in hydrate-based carbon dioxide capture applications," Applied Energy, Elsevier, vol. 269(C).
    16. Olga Gaidukova & Sergei Misyura & Pavel Strizhak, 2022. "Key Areas of Gas Hydrates Study: Review," Energies, MDPI, vol. 15(5), pages 1-18, February.
    17. Nguyen, Ngoc N. & La, Vinh T. & Huynh, Chinh D. & Nguyen, Anh V., 2022. "Technical and economic perspectives of hydrate-based carbon dioxide capture," Applied Energy, Elsevier, vol. 307(C).
    18. Thakre, Niraj & Jana, Amiya K., 2021. "Physical and molecular insights to Clathrate hydrate thermodynamics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    19. Yan, Jin & Lu, Yi-Yu & Zhong, Dong-Liang & Zou, Zhen-Lin & Li, Jian-Bo, 2019. "Enhanced methane recovery from low-concentration coalbed methane by gas hydrate formation in graphite nanofluids," Energy, Elsevier, vol. 180(C), pages 728-736.
    20. Foroutan, Shima & Mohsenzade, Hanie & Dashti, Ali & Roosta, Hadi, 2021. "New insights into the evaluation of kinetic hydrate inhibitors and energy consumption in rocking and stirred cells," Energy, Elsevier, vol. 218(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:270:y:2023:i:c:s0360544223002967. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.