IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v301y2024ics0360544224014890.html
   My bibliography  Save this article

Experimental and chemical kinetics study on the flammability limit of CO2/C3H6 mixture working fluid at variable initial temperature

Author

Listed:
  • Wang, Xueyan
  • Tian, Hua
  • Shu, Gequn
  • Yang, Zhao

Abstract

CO2/C3H6 mixture has a wide range of applications in refrigeration systems, heat pumps and Organic Rankine Cycle (ORC) systems, but its flammability safety needs to be considered. An experimental and computational investigation has been conducted on the determination of the flammability limits of CO2/C3H6 and on the understanding of associated limit phenomena in general. We tested the flammable zone of CO2/C3H6 at variable initial temperature. The accuracy of the prediction model of calculation adiabatic flame temperature were verified based on the experimental data. Meanwhile, a high-speed camera was used to record the process of CO2 suppression of flame propagation near flammability limit. Furthermore, based on kinetic numerical calculation, the effect of CO2 chemical and thermal on the flammability limit of C3H6 were analyzed. The results show that the thermal effect of CO2 is greater than that of chemical effect near the flammability limit. The theory of chemical reactivity inhibition reduces the yield and molar ratio of key radicals. The addition of CO2 can inhibit the activity of the dominant chain and increase the activity of the dominant chain termination reaction in the global combustion kinetics. Results of this study provide theoretical guidance for the safe application of CO2/C3H6 mixture.

Suggested Citation

  • Wang, Xueyan & Tian, Hua & Shu, Gequn & Yang, Zhao, 2024. "Experimental and chemical kinetics study on the flammability limit of CO2/C3H6 mixture working fluid at variable initial temperature," Energy, Elsevier, vol. 301(C).
    • Handle: RePEc:eee:energy:v:301:y:2024:i:c:s0360544224014890
    DOI: 10.1016/j.energy.2024.131716
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544224014890
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2024.131716?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Wu, Xi & Yang, Zhao & Wang, Xiaoming & Lin, Yulong, 2013. "Experimental and theoretical study on the influence of temperature and humidity on the flammability limits of ethylene (R1150)," Energy, Elsevier, vol. 52(C), pages 185-191.
    2. Li, Pengliang & Liu, Zhenyi & Li, Mingzhi & Zhao, Yao & Qian, Xinming & Ren, Yuan, 2023. "Investigation on the reaction mechanism of methane combustion near flammability limits at elevated pressures and temperaturaes," Energy, Elsevier, vol. 269(C).
    3. Shu, Gequn & Li, Xiaoning & Tian, Hua & Liang, Xingyu & Wei, Haiqiao & Wang, Xu, 2014. "Alkanes as working fluids for high-temperature exhaust heat recovery of diesel engine using organic Rankine cycle," Applied Energy, Elsevier, vol. 119(C), pages 204-217.
    4. Zhao, Zhen & Luo, Jielin & Zou, Dexin & Yang, Kaiyin & Wang, Qin & Chen, Guangming, 2023. "Experimental investigation on the inhibition of flame retardants on the flammability of R1234ze(E)," Energy, Elsevier, vol. 263(PE).
    5. Li, Fangzhou & Qian, Xinming & Li, Pengliang & Liu, Zhenyi & Yuan, Mengqi & Chen, Jian, 2023. "Investigation on the flammability limit and limiting oxygen concentration of propane/propylene mixture at elevated temperature and pressure," Energy, Elsevier, vol. 285(C).
    6. Hu, Xianzhong & Yu, Qingbo & Sun, Yasong, 2020. "Effects of carbon dioxide on the upper flammability limits of methane in O2/CO2 atmosphere," Energy, Elsevier, vol. 208(C).
    7. Tian, Hua & Liu, Yuewei & Shu, Gequn & Li, Linqing & Huo, Xu, 2019. "Theoretical and experimental research on the influence of initial temperature on the flammability of hydrocarbon-CO2 mixture using in organic Rankine cycle," Energy, Elsevier, vol. 167(C), pages 939-949.
    8. Shu, Gequn & Gao, Yuanyuan & Tian, Hua & Wei, Haiqiao & Liang, Xingyu, 2014. "Study of mixtures based on hydrocarbons used in ORC (Organic Rankine Cycle) for engine waste heat recovery," Energy, Elsevier, vol. 74(C), pages 428-438.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Scaccabarozzi, Roberto & Tavano, Michele & Invernizzi, Costante Mario & Martelli, Emanuele, 2018. "Comparison of working fluids and cycle optimization for heat recovery ORCs from large internal combustion engines," Energy, Elsevier, vol. 158(C), pages 396-416.
    2. Qi, Chang & Ding, Jianfei & Wang, Yue & Ning, Ye & Wang, Yalei & Liang, He & Yan, Xingqing & Yu, Jianliang, 2023. "Investigation of the upper flammability limit of ethylene/propane mixtures in air at high temperatures and pressures," Energy, Elsevier, vol. 281(C).
    3. Panesar, Angad Singh, 2017. "An innovative Organic Rankine Cycle system for integrated cooling and heat recovery," Applied Energy, Elsevier, vol. 186(P3), pages 396-407.
    4. Hoang, Anh Tuan, 2018. "Waste heat recovery from diesel engines based on Organic Rankine Cycle," Applied Energy, Elsevier, vol. 231(C), pages 138-166.
    5. Lion, Simone & Michos, Constantine N. & Vlaskos, Ioannis & Rouaud, Cedric & Taccani, Rodolfo, 2017. "A review of waste heat recovery and Organic Rankine Cycles (ORC) in on-off highway vehicle Heavy Duty Diesel Engine applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 691-708.
    6. Zhang, Jianan & Qin, Kan & Li, Daijin & Luo, Kai & Dang, Jianjun, 2020. "Potential of Organic Rankine Cycles for Unmanned Underwater Vehicles," Energy, Elsevier, vol. 192(C).
    7. Bamorovat Abadi, Gholamreza & Kim, Kyung Chun, 2017. "Investigation of organic Rankine cycles with zeotropic mixtures as a working fluid: Advantages and issues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1000-1013.
    8. Yang, Min-Hsiung & Yeh, Rong-Hua, 2015. "Thermo-economic optimization of an organic Rankine cycle system for large marine diesel engine waste heat recovery," Energy, Elsevier, vol. 82(C), pages 256-268.
    9. Yu, Xiaoli & Li, Zhi & Lu, Yiji & Huang, Rui & Roskilly, Anthony Paul, 2019. "Investigation of organic Rankine cycle integrated with double latent thermal energy storage for engine waste heat recovery," Energy, Elsevier, vol. 170(C), pages 1098-1112.
    10. Feng, Biao & Yang, Zhao & Zhai, Rui, 2017. "Experimental research on the concentration characteristics of R32 and R161′ combustion product HF," Energy, Elsevier, vol. 125(C), pages 671-680.
    11. Li, Jing & Li, Pengcheng & Pei, Gang & Alvi, Jahan Zeb & Ji, Jie, 2016. "Analysis of a novel solar electricity generation system using cascade Rankine cycle and steam screw expander," Applied Energy, Elsevier, vol. 165(C), pages 627-638.
    12. Kumma, Nagarjuna & Kruthiventi, S.S Harish, 2024. "Current status of refrigerants used in domestic applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PB).
    13. Lecompte, S. & Huisseune, H. & van den Broek, M. & De Paepe, M., 2015. "Methodical thermodynamic analysis and regression models of organic Rankine cycle architectures for waste heat recovery," Energy, Elsevier, vol. 87(C), pages 60-76.
    14. Shu, Gequn & Shi, Lingfeng & Tian, Hua & Deng, Shuai & Li, Xiaoya & Chang, Liwen, 2017. "Configurations selection maps of CO2-based transcritical Rankine cycle (CTRC) for thermal energy management of engine waste heat," Applied Energy, Elsevier, vol. 186(P3), pages 423-435.
    15. Magdalena Santos-Rodriguez, M. & Flores-Tlacuahuac, Antonio & Zavala, Victor M., 2017. "A stochastic optimization approach for the design of organic fluid mixtures for low-temperature heat recovery," Applied Energy, Elsevier, vol. 198(C), pages 145-159.
    16. Li, Jing & Li, Pengcheng & Gao, Guangtao & Pei, Gang & Su, Yuehong & Ji, Jie, 2017. "Thermodynamic and economic investigation of a screw expander-based direct steam generation solar cascade Rankine cycle system using water as thermal storage fluid," Applied Energy, Elsevier, vol. 195(C), pages 137-151.
    17. Yang, Zhao & Wu, Xi, 2013. "Retrofits and options for the alternatives to HCFC-22," Energy, Elsevier, vol. 59(C), pages 1-21.
    18. Yang, Fubin & Cho, Heejin & Zhang, Hongguang & Zhang, Jian, 2017. "Thermoeconomic multi-objective optimization of a dual loop organic Rankine cycle (ORC) for CNG engine waste heat recovery," Applied Energy, Elsevier, vol. 205(C), pages 1100-1118.
    19. Li, Jing & Alvi, Jahan Zeb & Pei, Gang & Su, Yuehong & Li, Pengcheng & Gao, Guangtao & Ji, Jie, 2016. "Modelling of organic Rankine cycle efficiency with respect to the equivalent hot side temperature," Energy, Elsevier, vol. 115(P1), pages 668-683.
    20. Galindo Noguera, Ana Lisbeth & Mendoza Castellanos, Luis Sebastian & Silva Lora, Electo Eduardo & Melian Cobas, Vladimir Rafael, 2018. "Optimum design of a hybrid diesel-ORC / photovoltaic system using PSO: Case study for the city of Cujubim, Brazil," Energy, Elsevier, vol. 142(C), pages 33-45.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:301:y:2024:i:c:s0360544224014890. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.