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Three eagles with one arrow: Simultaneous production of hydrogen, aluminum ethoxide, and supported metal catalysts via efficient and facile reaction between aluminum and ethanol

Author

Listed:
  • Guo, Junyan
  • Gao, Ruihong
  • Tong, Zhaoming
  • Zhang, Haijun
  • Duan, Hongjuan
  • Huang, Liang
  • Lu, Lilin
  • Jia, Quanli
  • Zhang, Shaowei

Abstract

Complex preparation, risky storage, and expensive transportation are hindering the application of hydrogen (H2) energy. To overcome these, a simple, cost-effective, and zero CO2-emission method is urgently needed. This study for the first time showed that the aluminum-ethanol (Al-ethanol) reaction without the need of complex pre-treatment can produce simultaneously hydrogen, aluminum ethoxide [Al(EtO)3], and supported metallic nanoparticle (NP) catalyst. Fe (3.6 nm), Co (3.5 nm), Ni (2.9 nm), and Cu (3.5 nm) NPs, in-situ generated by the galvanic replacement reaction between aluminum and metal ions, provided the catalytically active sites for the Al-ethanol reaction, effectively enhancing H2 and Al(EtO)3 formation. Consequently, the Al-ethanol reaction catalyzed by the Ni NPs with the smallest average size at 50 °C led to the formation of hydrogen at a high rate of 109 mL-H2·min−1·g-Al−1. Density functional theory (DFT) calculations suggested that the in-situ generated Ni NPs had charge transfer with ethanol and aluminum, which significantly enhanced the ethanol adsorbing capability onto the aluminum. Moreover, recovery of high value-added Al(EtO)3 and utilization of supported metallic catalyst could additionally benefit the practical application of the Al-ethanol reaction. With the proposed “three eagles with one arrow” strategy, simultaneous generation of H2, Al(EtO)3 and supported metallic catalyst could be readily realized in a more straightforward, scalable and economical way.

Suggested Citation

  • Guo, Junyan & Gao, Ruihong & Tong, Zhaoming & Zhang, Haijun & Duan, Hongjuan & Huang, Liang & Lu, Lilin & Jia, Quanli & Zhang, Shaowei, 2023. "Three eagles with one arrow: Simultaneous production of hydrogen, aluminum ethoxide, and supported metal catalysts via efficient and facile reaction between aluminum and ethanol," Energy, Elsevier, vol. 263(PD).
    • Handle: RePEc:eee:energy:v:263:y:2023:i:pd:s0360544222027475
    DOI: 10.1016/j.energy.2022.125861
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