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Energy and exergy analyses of hydrogen production process with aluminum and water chemical reaction

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  • Bolt, Andre
  • Dincer, Ibrahim
  • Agelin-Chaab, Martin

Abstract

Hydrogen is recognized as an energy carrier and has substantial potential to fulfill future energy demands. This paper conducted energy and exergy analyses on a hydrogen production process that utilized the chemical reaction between aluminum and water. Various aspects of the system’s performance, such as energetic efficiency, exergetic efficiency, sustainability index, and other methods to evaluate the system’s performance were examined. The factors such as the lower heating value (LHV) of hydrogen, the reactant molecules’ enthalpy of formation, and their respective chemical exergy were considered. The energy input from the heater was substantial enough to be taken into consideration; however, the energy input from the pump was considered negligible in the overall process efficiency. The standard reaction efficiency equation displayed the most favourable results at the higher water temperatures. Therefore, the variation in the water medium and NaOH concentration experiments used 70 °C as its water temperature. The variation in water medium test identified tap water as an effective water medium due to its higher energy efficiency, and its ability to achieve the maximum theoretical yield. However, seawater was identified as a viable option for future testing, as it was able to achieve standard energetic and exergetic efficiencies up to 32.40% and 54.35% for the 3-g samples. Additional parametric studies were conducted and compared throughout this study to provide a comprehensive analysis of the system’s performance.

Suggested Citation

  • Bolt, Andre & Dincer, Ibrahim & Agelin-Chaab, Martin, 2020. "Energy and exergy analyses of hydrogen production process with aluminum and water chemical reaction," Energy, Elsevier, vol. 205(C).
    • Handle: RePEc:eee:energy:v:205:y:2020:i:c:s0360544220310859
    DOI: 10.1016/j.energy.2020.117978
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    References listed on IDEAS

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    1. Gai, Wei-Zhuo & Wang, Le-Yao & Lu, Meng-Yao & Deng, Zhen-Yan, 2023. "Effect of low concentration hydroxides on Al hydrolysis for hydrogen production," Energy, Elsevier, vol. 268(C).
    2. Gai, Wei-Zhuo & Deng, Zhen-Yan, 2024. "Enhanced hydrogen production from Al-water reaction: Strategies, performances, mechanisms and applications," Renewable Energy, Elsevier, vol. 226(C).
    3. Xinyue Gao & Chang’an Wang & Wengang Bai & Yujie Hou & Defu Che, 2022. "Aluminum-Based Fuels as Energy Carriers for Controllable Power and Hydrogen Generation—A Review," Energies, MDPI, vol. 16(1), pages 1-22, December.
    4. Azarpour, Abbas & Mohamadi-Baghmolaei, Mohamad & Hajizadeh, Abdollah & Zendehboudi, Sohrab, 2022. "Systematic energy and exergy assessment of a hydropurification process: Theoretical and practical insights," Energy, Elsevier, vol. 239(PC).
    5. Guo, Junyan & Gao, Ruihong & Tong, Zhaoming & Zhang, Haijun & Duan, Hongjuan & Huang, Liang & Lu, Lilin & Jia, Quanli & Zhang, Shaowei, 2023. "Three eagles with one arrow: Simultaneous production of hydrogen, aluminum ethoxide, and supported metal catalysts via efficient and facile reaction between aluminum and ethanol," Energy, Elsevier, vol. 263(PD).

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